Dynamic model of a PEMFC stack suitable for component level modeling of a fuel cell based generator

Dynamic fuel cell stack models offering a good trade-off between computation time and realistic transient behavior are required for the optimized control of fuel cell based generators. This paper describes a model which dynamically considers the membrane dehydration by computing its hydration level and the flooding/mass transport phenomena caused by the gradual accumulation of liquid water in the cathode “gas diffusion layer”. The model’s output is shown to better fit the experimental stack central cell voltage than the averaged stack voltage, the error being less than 2%. Additional experimental results are required to properly validate the model water management behavior. Part of the voltage difference between the stack central cells and top/bottom cells has been attributed to the temperature variation along the stack. A threedimensional stack thermal model is being developed to take this temperature distribution into account.

[1]  Anna G. Stefanopoulou,et al.  Control of Fuel Cell Power Systems: Principles, Modeling, Analysis and Feedback Design , 2004 .

[2]  Brandon Michael Eaton,et al.  One-Dimensional, Transient Model of Heat, Mass, and Charge Transfer in a Proton Exchange Membrane , 2001, Advanced Energy Systems.

[3]  T. Springer,et al.  Polymer Electrolyte Fuel Cell Model , 1991 .

[4]  J. C. Amphlett,et al.  Performance modeling of the Ballard Mark IV solid polymer electrolyte fuel cell. II: Empirical model development , 1995 .

[5]  Chia-Jung Hsu Numerical Heat Transfer and Fluid Flow , 1981 .

[6]  Kodjo Agbossou,et al.  Fuel Cell Operation with Oxygen Enrichment , 2002 .

[7]  Warren E. Stewart,et al.  Selected topics in transport phenomena , 1965 .

[8]  Ned Djilali,et al.  Computational model of a PEM fuel cell with serpentine gas flow channels , 2004 .

[9]  Mohammad Tariq Iqbal,et al.  Dynamic Modelling and Simulation of a Fuel Cell Generator , 2005 .

[10]  J. Hinatsu,et al.  Water Uptake of Perfluorosulfonic Acid Membranes from Liquid Water and Water Vapor , 1994 .

[11]  C. Chamberlin,et al.  Modeling of Proton Exchange Membrane Fuel Cell Performance with an Empirical Equation , 1995 .

[12]  S. Dutta,et al.  NUMERICAL PREDICTION OF TEMPERATURE DISTRIBUTION IN PEM FUEL CELLS , 2000 .

[13]  J. C. Amphlett,et al.  A model predicting transient responses of proton exchange membrane fuel cells , 1996 .

[14]  Anna G. Stefanopoulou,et al.  Control of Fuel Cell Power Systems , 2004 .

[15]  Wei-Mon Yan,et al.  Transient analysis of reactant gas transport and performance of PEM fuel cells , 2005 .

[16]  Maher A.R. Sadiq Al-Baghdadi,et al.  Modelling of proton exchange membrane fuel cell performance based on semi-empirical equations , 2005 .