HIGHLY EFFICIENT AND SELECTIVE DISPLACEMENT OF ALKYLTHIO GROUP ON ACYLKETENE O,S-ACETALS BY ORGANOCOPPER REAGENTS : A NOVEL ROUTE TO 2-ALKOXY/ARYLOXY- 1-ALKENYLKETONES

[1]  Yoshinori Yamamoto Selective Synthesis by Use of Lewis Acids in the Presence of Organocopper and Related Reagents. New Synthetic Methods (61) , 1986 .

[2]  L. A. Silks,et al.  Control of chemo- and stereoselectivity in the reactions of organocuprates with .alpha.-oxoketene dithioacetals , 1985 .

[3]  L. A. Silks,et al.  Stereoselectivity in the addition of organocuprates to .beta.-(alkylthio)-.alpha.,.beta.-enones , 1983 .

[4]  E. Piers,et al.  .beta.-Acylvinyl anion equivalents: preparation of 1-lithio-3-(tert-butyldimethylsiloxy)-1,3-cyclohexadiene and its reaction with electrophiles , 1979 .

[5]  F. Sum,et al.  Stereoselective synthesis of β-substituted α,β-unsaturated esters by dialkylcuprate coupling to the enol phosphate of β-keto esters , 1979 .

[6]  H. Williams,et al.  A NEW PREPARATION OF ACETYLENIC KETONES AND APPLICATION TO THE SYNTHESIS OF EXO-BREVICOMIN, THE PHEROMONE FROM DENDROCTONUS BREVICOMIS , 1977 .

[7]  C. Heathcock,et al.  Preparation and reactions of .beta.-chloro-.alpha.,.beta.-unsaturated ketones , 1976 .

[8]  A. Pohland,et al.  β-Chlorovinyl Ketones , 1966 .

[9]  Robert M. Williams,et al.  Mechanism of the Reaction of Acetylacetone with Diazomethane , 1962 .

[10]  B. Eistert,et al.  Die Enolmethyläther des Benzoylacetons , 1953 .

[11]  R. Wilhelm,et al.  The chemistry of higher order organocuprates , 1984 .

[12]  R. Coates,et al.  Conjugate-addition alkylation of .alpha., .beta.-unsaturated ketones , 1974 .

[13]  C. Harris,et al.  Condensations of enol ethers of .beta.-dicarbonyl compounds with dimethylsulfonium methylide and dimethyloxosulfonium methylide , 1974 .

[14]  C. Casey,et al.  A New General Synthesis of Isoprenoid Chains Employing the Reaction of Dialkylcuprates with β-Acetoxy α,β-Unsaturated Esters , 1973 .