Challenges, uncertainties and issues facing gas production from gas hydrate deposits

Challenges, Uncertainties and Issues Facing Gas Production From Gas Hydrate Deposits G.J. Moridis, SPE, Lawrence Berkeley National Laboratory; T.S. Collett, SPE, US Geological Survey; M. Pooladi- Darvish, SPE, University of Calgary and Fekete; S. Hancock, SPE, RPS Group; C. Santamarina, Georgia Institute of Technology; R. Boswell, US Department of Energy; T. Kneafsey, J. Rutqvist and M. B. Kowalsky, Lawrence Berkeley National Laboratory; M.T. Reagan, SPE, Lawrence Berkeley National Laboratory; E.D. Sloan, SPE, Colorado School of Mines; A.K. Sum and C. A. Koh, Colorado School of Mines Abstract The current paper complements the Moridis et al. (2009) review of the status of the effort toward commercial gas production from hydrates. We aim to describe the concept of the gas hydrate petroleum system, to discuss advances, requirement and suggested practices in gas hydrate (GH) prospecting and GH deposit characterization, and to review the associated technical, economic and environmental challenges and uncertainties, including: the accurate assessment of producible fractions of the GH resource, the development of methodologies for identifying suitable production targets, the sampling of hydrate-bearing sediments and sample analysis, the analysis and interpretation of geophysical surveys of GH reservoirs, well testing methods and interpretation of the results, geomechanical and reservoir/well stability concerns, well design, operation and installation, field operations and extending production beyond sand-dominated GH reservoirs, monitoring production and geomechanical stability, laboratory investigations, fundamental knowledge of hydrate behavior, the economics of commercial gas production from hydrates, and the associated environmental concerns. Introduction Background. Gas hydrates (GH) are solid crystalline compounds of water and gaseous substances described by the general chemical formula G•N H H 2 O, in which the molecules of gas G (referred to as guests) occupy voids within the lattices of ice- like crystal structures. Gas hydrate deposits occur in two distinctly different geographic settings where the necessary conditions of low temperature T and high pressure P exist for their formation and stability: in the Arctic (typically in association with permafrost) and in deep ocean sediments (Kvenvolden, 1988). The majority of naturally occurring hydrocarbon gas hydrates contain CH 4 in overwhelming abundance. Simple CH 4 - hydrates concentrate methane volumetrically by a factor of ~164 when compared to standard P and T conditions (STP). Natural CH 4 -hydrates crystallize mostly in the structure I form, which has a hydration number N H ranging from 5.77 to 7.4, with N H = 6 being the average hydration number and N H = 5.75 corresponding to complete hydration (Sloan and Koh, 2008). Natural GH can also contain other hydrocarbons (alkanes C  H 2+2 ,  = 2 to 4), but may also contain trace amounts of other gases (mainly CO 2 , H 2 S or N 2 ). Although there has been no systematic effort to map and evaluate this resource on a global scale, and current estimates of in-place volumes vary widely (ranging between 10 15 to 10 18 m 3 at standard conditions), the consensus is that the worldwide quantity of hydrocarbon within GH is vast (Milkov, 2004; Boswell and Collett, 2010). Given the sheer magnitude of the resource, ever increasing global energy demand, and the finite volume of conventional fossil fuel resources, GH are emerging as a potential energy source for a growing number of nations. The attractiveness of GH is further enhanced by the environmental desirability of natural gas, as it has the lowest carbon intensity of all fossil fuels. Thus, the appeal of GH accumulations as future hydrocarbon gas sources is rapidly increasing and their production potential clearly demands technical and economic evaluation. The past decade has seen a marked acceleration in gas hydrate R&D, including both a proliferation of basic scientific endeavors as well as the strong emergence of focused field studies of GH occurrence and resource potential, primarily within national GH programs (Paul et al., 2010). Together, these efforts have helped to clarify the dominant issues and challenges facing the extraction of methane from gas hydrates. A review paper by Moridis et al. (2009) summarized the status of the effort for production from gas hydrates. The authors discussed the distribution of natural gas hydrate accumulations, the status of the primary international research and development R&D programs (including current policies, focus and priorities), and the remaining science and technological challenges facing commercialization of production. After a brief examination of GH accumulations that are well characterized and appear to be models for future development and gas production, they analyzed the role of numerical simulation in the assessment of the hydrate production potential, identified the data needs for reliable predictions, evaluated the status of knowledge with regard to these needs, discussed knowledge gaps and their impact, and reached the conclusion that the numerical simulation capabilities are quite advanced and that the related gaps are either not significant or are being addressed. Furthermore, Moridis et al. (2009) reviewed the current body of literature relevant to potential productivity from different types of GH deposits, and determined that there are consistent indications of a large production potential at high rates over long periods from a wide variety of GH deposits. Finally, they identified (a) features, conditions, geology and techniques that are desirable in the selection of potential production targets, (b) methods to maximize production, and (c) some of the conditions and characteristics that render certain GH deposits undesirable for production.

[1]  Philip E. Long,et al.  Methane hydrate formation in turbidite sediments of northern Cascadia, IODP Expedition 311 , 2008 .

[2]  George J. Moridis,et al.  Methane hydrate formation and dissociation in a partially saturated sand , 2004 .

[3]  R. N. Edwards On the resource evaluation of marine gas hydrate deposits using sea‐floor transient electric dipole‐dipole methods , 1997 .

[4]  George J. Moridis,et al.  Methane hydrate formation and dissociation in a partially saturated core-scale sand sample , 2005 .

[5]  George J. Moridis,et al.  Preliminary report on the commercial viability of gas production from natural gas hydrates , 2009 .

[6]  Johannes Kulenkampff,et al.  Influence of methane hydrate content on electrical sediment properties , 2006 .

[7]  Amos Nur,et al.  Elastic‐wave velocity in marine sediments with gas hydrates: Effective medium modeling , 1999 .

[8]  Scott J. Wilson,et al.  PRELIMINARY REPORT ON THE ECONOMICS OF GAS PRODUCTION FROM NATURAL GAS HYDRATES , 2008 .

[9]  Mark D. White,et al.  Numerical Simulation of Methane Hydrate Production from Geologic Formations via Carbon Dioxide Injection , 2008 .

[10]  M. Reagan,et al.  Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico , 2009 .

[11]  Tae Sup Yun,et al.  Physical characterization of core samples recovered from Gulf of Mexico , 2006 .

[12]  Mehran Pooladi-Darvish,et al.  Use of formation pressure test results over a hydrate interval for long-term production forecasting at the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Implications of uncertainties , 2011 .

[13]  A. Singer,et al.  Detection and Estimation of , 1999 .

[14]  J. Rutqvist,et al.  Numerical Studies on the Geomechanical Stability of Hydrate-Bearing Sediments , 2009 .

[15]  E. D. Sloan,et al.  Microsecond Simulations of Spontaneous Methane Hydrate Nucleation and Growth , 2009, Science.

[16]  J. Rutqvist,et al.  Geomechanical response of permafrost-associated hydrate deposits to depressurization-induced gas production , 2009 .

[17]  Shuanshi Fan,et al.  Measuring and modeling thermal conductivity of gas hydrate‐bearing sand , 2005 .

[18]  William F. Waite,et al.  Estimating pore‐space gas hydrate saturations from well log acoustic data , 2008 .

[19]  Nicolas Kalogerakis,et al.  Multiphase equilibrium flash calculations for systems containing gas hydrates , 1989 .

[20]  Tae Sup Yun,et al.  Compressional and shear wave velocities in uncemented sediment containing gas hydrate , 2005 .

[21]  Bob A. Hardage,et al.  Multicomponent Seismic Technology Assessment of Fluid-gas Expulsion Geology and Gas-hydrate Systems: Gulf of Mexico , 2009 .

[22]  C. Ruppel Thermal State of the Gas Hydrate Reservoir , 2000 .

[23]  Sanjay Srinivasan,et al.  Experimental determination of permeability in the presence of hydrates and its effect on the dissociation characteristics of gas hydrates in porous media , 2010 .

[24]  K. Kvenvolden Methane hydrate — A major reservoir of carbon in the shallow geosphere? , 1988 .

[25]  G. Narsilio,et al.  Instrumented pressure testing chamber for characterizing sediment cores recovered at in situ hydrostatic pressure , 2006 .

[26]  Jonny Rutqvist,et al.  Coupled Hydrologic, Thermal and Geomechanical Analysis of Well Bore Stability in Hydrate-Bearing Sediments , 2008 .

[27]  W. Landman Climate change 2007: the physical science basis , 2010 .

[28]  Mehran Pooladi-Darvish,et al.  Behavior of gas production from Type III hydrate reservoirs , 2011 .

[29]  Kelly Rose,et al.  Korean national Program expedition confirms rich gas hydrate deposit in the Ulleung Basin, East Sea , 2008 .

[30]  T. Collett Natural Gas Hydrates of the Prudhoe Bay and Kuparuk River Area, North Slope, Alaska , 1993 .

[31]  C. Berndt,et al.  Escape of methane gas from the seabed along the West Spitsbergen continental margin , 2009 .

[32]  T. Sowers Late Quaternary Atmospheric CH4 Isotope Record Suggests Marine Clathrates Are Stable , 2006, Science.

[33]  Bahman Tohidi Kalorazi,et al.  Application of high pressure glass micromodels to gas hydrates studies , 2002 .

[34]  Jaewon Jang,et al.  Gas production from hydrate-bearing sediments , 2011 .

[35]  Bob A. Hardage,et al.  Multicomponent Seismic Technology , 2011 .

[36]  George J. Moridis,et al.  COMPARISON OF KINETIC AND EQUILIBRIUM REACTION MODELS IN SIMULATING THE BEHAVIOR OF GAS HYDRATES IN POROUS MEDIA , 2006 .

[37]  F. R. S. Geological Survey of Canada , 1906, Nature.

[38]  E. D. Sloan,et al.  A New Technique for Hydrate Thermal Diffusivity Measurements , 2005 .

[39]  T. Collett Energy resource potential of natural gas hydrates , 2002 .

[40]  Timothy S. Collett,et al.  Seismic-attribute Analysis for Gas-hydrate and Free-gas Prospects on the North Slope of Alaska , 2009 .

[41]  Tsutomu Uchida,et al.  Effects of Pore Sizes on Dissociation Temperatures and Pressures of Methane, Carbon Dioxide, and Propane Hydrates in Porous Media , 2002 .

[42]  J. Santamarina,et al.  Electrical Conductivity in Soils: Underlying Phenomena , 2003 .

[43]  Barry Freifeld,et al.  X-ray Computed Tomography Observation of Methane Hydrate Dissociation , 2002 .

[44]  Roger M. Butler,et al.  The Gravity Drainage of Steam-heated Heavy Oil to Parallel Horizontal Wells , 1981 .

[45]  M. Reagan,et al.  Large‐scale simulation of methane hydrate dissociation along the West Spitsbergen Margin , 2009 .

[46]  George J. Moridis,et al.  Studies of Reaction Kinetics of Methane Hydrate Dissocation in Porous Media , 2005 .

[47]  Timothy J. Kneafsey,et al.  Analysis of core samples from the BPXA-DOE-USGS Mount Elbert gas hydrate stratigraphic test well: Insights into core disturbance and handling , 2010 .

[48]  George J. Moridis,et al.  Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential , 2008 .

[49]  Shahab Gerami,et al.  Predicting gas generation by depressurization of gas hydrates where the sharp-interface assumption is not valid , 2007 .

[50]  William F. Waite,et al.  Methane gas hydrate effect on sediment acoustic and strength properties , 2007 .

[51]  Tae Sup Yun,et al.  Mechanical properties of sand, silt, and clay containing tetrahydrofuran hydrate , 2007 .

[52]  Tae Sup Yun,et al.  Geotechnical characterization of marine sediments in the Ulleung Basin, East Sea , 2011 .

[53]  Carolyn A. Koh,et al.  Clathrate hydrates of natural gases , 1990 .

[54]  C.R.I. Clayton,et al.  Influence of gas hydrate morphology on the seismic velocities of sands , 2009 .

[55]  B. Anderson,et al.  Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Overview of scientific and technical program , 2011 .

[56]  Mehran Pooladi-Darvish,et al.  Effect of Conductive and Convective Heat Flow on Gas Production from Natural Hydrates by Depressurization , 2004 .

[57]  George J. Moridis,et al.  Gas Production From Oceanic Class 2 Hydrate Accumulations , 2007 .

[58]  Ray Boswell,et al.  Gulf of Mexico Gas Hydrate Joint Industry Project Leg II: Results From the Alaminos Canyon 21 Site , 2010 .

[59]  Timothy J. Kneafsey,et al.  Permeability of Laboratory-Formed Hydrate-Bearing Sand , 2008 .

[60]  K. Kvenvolden,et al.  A primer on gas hydrates , 1993 .

[61]  Divison on Earth Realizing the Energy Potential of Methane Hydrate for the United States: Committee on Assessment of the Department of Energy's Methane Hydrate Research and Development Program: Evaluating Methane Hydrate as a Future Energy Resource , 2010 .

[62]  Timothy S. Collett,et al.  Overview of pressure-drawdown production-test results for the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[63]  Thomas Bohlen,et al.  Multi-offset vertical seismic profiling - an experiment to assess petrophysical scale parameters at the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[64]  P. Bollavaram,et al.  Hydrate plug dissociation , 2006 .

[65]  Bjørn Kvamme,et al.  MRI Visualization of Spontaneous Methane Production From Hydrates in Sandstone Core Plugs When Exposed to CO2 , 2008 .

[66]  R. N. Edwards,et al.  RESOLVING RESISTIVE ANOMALIES DUE TO GAS HYDRATE USING ELECTROMAGNETIC IMAGING METHODS , 2008 .

[67]  Toshi-aki Kobayashi,et al.  Resource Assessment of Methane Hydrate in the Eastern Nankai Trough, Japan , 2007 .

[68]  K. H. Coats,et al.  Cyclic Gas/Steam Stimulation of Heavy-Oil Wells , 1981 .

[69]  William F. Waite,et al.  Simultaneous determination of thermal conductivity, thermal diffusivity and specific heat in sI methane hydrate , 2007 .

[70]  Doroteya K. Staykova,et al.  Formation of Porous Gas Hydrates from Ice Powders: Diffraction Experiments and Multistage Model , 2003 .

[71]  K. Rose,et al.  HIGH CONCENTRATION HYDRATE IN DISSEMINATED FORMS OBTAINED IN SHENHU AREA, NORTH SLOPE OF SOUTH CHINA SEA , 2008 .

[72]  R. Kleinberg,et al.  Magnetic resonance log of JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well: gas hydrate saturation, growth habit, and relative permeability , 2005 .

[73]  Gas Production Potential , .

[74]  George J. Moridis,et al.  Numerical Studies of Gas Production From Methane Hydrates , 2003 .

[75]  Bob A. Hardage,et al.  Rock-physics Models for Gas-hydrate Systems Associated with Unconsolidated Marine Sediments , 2009 .

[76]  George J. Moridis,et al.  Strategies for gas production from hydrate accumulations under various geologic conditions , 2003 .

[77]  Tae Sup Yun,et al.  Hydrate-Bearing Sediments from the Krishna-Godavari Basin: Physical Characterization, Pressure Core Testing, and Scaled Production Monitoring , 2010 .

[78]  Tae Sup Yun,et al.  Geophysical and geotechnical properties of near-seafloor sediments in the northern Gulf of Mexico gas hydrate province , 2005 .

[79]  C. Ruppel,et al.  Thermal Conductivity Measurements in Porous Mixtures of Methane Hydrate and Quartz Sand , 2002 .

[80]  Yoshihiro Masuda,et al.  ANALYSIS OF THE JOGMEC/NRCAN/AURORA MALLIK GAS HYDRATE PRODUCTION TEST THROUGH NUMERICAL SIMULATION , 2008 .

[81]  Satinder Chopra,et al.  Geophysical Characterization of Gas Hydrates , 2010 .

[82]  Tsutomu Uchida,et al.  Decomposition of methane hydrates in sand, sandstone, clays, and glass beads , 2004 .

[83]  M. Reagan,et al.  Strategies for gas production from oceanic Class 3 hydrate accumulations , 2007 .

[84]  Irene Gullapalli,et al.  DESIGNING A RESERVOIR FLOW RATE EXPERIMENT FOR THE GOM HYDRATE JIP LEG II LWD DRILLING , 2008 .

[85]  Shahab Gerami,et al.  Effect of Hydrates on Sustaining Reservoir Pressure in a Hydrate-Capped Gas Reservoir , 2007 .

[86]  J. C. Santamarina,et al.  Parametric study of the physical properties of hydrate‐bearing sand, silt, and clay sediments: 2. Small‐strain mechanical properties , 2010 .

[87]  George J. Moridis,et al.  Numerical Studies of Gas Production From Class 2 and Class 3 Hydrate Accumulations at the Mallik Site, Mackenzie Delta, Canada , 2004 .

[88]  Jack Dvorkin,et al.  Elasticity of marine sediments: Rock physics modeling , 1999 .

[89]  Y. P. Handa,et al.  Thermodynamic properties and dissociation characteristics of methane and propane hydrates in 70-.ANG.-radius silica gel pores , 1992 .

[90]  E. Rosenbaum,et al.  Thermal conductivity of methane hydrate from experiment and molecular simulation. , 2007, The journal of physical chemistry. B.

[91]  George J. Moridis,et al.  Production-test planning for the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[92]  Walter S Borowski,et al.  Methane-rich plumes on the Carolina continental rise: Associations with gas hydrates , 1995 .

[93]  J. C. Santamarina,et al.  Parametric study of the physical properties of hydrate-bearing sand, silt, and clay sediments: 1. Electromagnetic properties , 2010 .

[94]  Timothy J. Kneafsey,et al.  Examination of core samples from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Effects of retrieval and preservation , 2011 .

[95]  T. Plona,et al.  Anisotropic stress analysis from downhole acoustic logs in the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[96]  Scott J. Wilson,et al.  Formation pressure testing at the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Operational summary, history matching, and interpretations , 2011 .

[97]  Timothy J. Kneafsey,et al.  X-ray computed-tomography observations of water flow through anisotropic methane hydrate-bearing sand , 2009 .

[98]  K. Yamamoto,et al.  Environmental risks of the gas hydrate field development in the Eastern Nankai Trough , 2009 .

[99]  V. Bondarenko,et al.  Development of gas hydrates in the Black sea , 2011 .

[100]  T S Collett,et al.  Electrical-resistivity well-log analysis of gas hydrate saturations in the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[101]  William F. Waite,et al.  Physical property changes in hydrate-bearing sediment due to depressurization and subsequent repressurization , 2008 .

[102]  M. O’Hara,et al.  Summary and Implications , 1995 .

[103]  P. Bishnoi,et al.  Formation and decomposition of gas hydrates , 1996 .

[104]  Timothy J. Kneafsey,et al.  Permeability of Laboratory-Formed Methane-Hydrate-Bearing Sand: Measurements and Observations Using X-Ray Computed Tomography , 2011 .

[105]  Stefan Finsterle,et al.  Estimation of field‐scale soil hydraulic and dielectric parameters through joint inversion of GPR and hydrological data , 2005 .

[106]  Thomas O. Blank,et al.  Summary and Implications , 1992 .

[107]  Stan Tomov,et al.  Direct observations of three dimensional growth of hydrates hosted in porous media , 2009 .

[108]  Koji Yamamoto,et al.  AurorA-JoGMEC-NrCAN MAllik 2006-2008 GAs HydrAtE rEsEArCH , 2008 .

[109]  Pushpendra Kumar,et al.  INDIAN CONTINENTAL MARGIN GAS HYDRATE PROSPECTS: RESULTS OF THE INDIAN NATIONAL GAS HYDRATE PROGRAM (NGHP) EXPEDITION 01 , 2008 .

[110]  Jong Won Jung,et al.  Gas production from hydrate-bearing sediments: Geo-mechanical implications , 2010 .

[111]  R. Boswell Is Gas Hydrate Energy Within Reach? , 2009, Science.

[112]  S. K. Dutta,et al.  Physical properties of gram , 1988 .

[113]  Mehran Pooladi-Darvish,et al.  Simulation of Depressurization for Gas Production From Gas Hydrate Reservoirs , 2005 .

[114]  R. Boswell,et al.  Current perspectives on gas hydrate resources , 2011 .

[115]  Hideo Narita,et al.  Visual observation of dissociation of methane hydrate crystals in a glass micro model: Production and transfer of methane , 2008 .

[116]  George J. Moridis,et al.  Response of oceanic hydrate-bearing sediments to thermal stresses , 2006 .

[117]  G. Dickens Rethinking the global carbon cycle with a large, dynamic and microbially mediated gas hydrate capacitor , 2003 .

[118]  Gilles Guerin,et al.  Sonic attenuation in the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[119]  Timothy S. Collett,et al.  JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well downhole well-log and core montages , 2005 .

[120]  Ray Boswell,et al.  Gulf of Mexico Gas Hydrates Joint Industry Project Leg II: Results from the Walker Ridge 313 Site , 2009 .

[121]  T. Ebinuma,et al.  Methane hydrate crystal growth in a porous medium filled with methane-saturated liquid water , 2007 .

[122]  Toshifumi Matsuoka,et al.  Preliminary assessment of the waveform inversion method for interpretation of cross-well seismic data from the thermal production test, JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[123]  Ray Boswell,et al.  Gulf of Mexico Gas Hydrate Joint Industry Project Leg II: LWD Logging Program Design, Data Acquisition and Evaluation , 2010 .

[124]  兵動 正幸,et al.  BASIC RESEARCH ON THE MECHANICAL BEHAVIOR OF METHANE HYDRATE-SEDIMENTS MIXTURE , 2005 .

[125]  A K Jain,et al.  Culture-based microbial profiling in sediments of the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[126]  S. Aoki,et al.  Magnetic resonance , 2012, International Journal of Computer Assisted Radiology and Surgery.

[127]  M. Lee,et al.  Assessment of Gas Hydrate Resources on the North Slope, Alaska, 2008 , 2008 .

[128]  Werner F. Kuhs,et al.  Microstructure of gas hydrates in porous media , 2007 .

[129]  E. D. Sloan,et al.  Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments , 2006 .

[130]  Quan Hua,et al.  14CH4 Measurements in Greenland Ice: Investigating Last Glacial Termination CH4 Sources , 2009, Science.

[131]  J. Ripmeester,et al.  The coexistence of two different methane hydrate phases under moderate pressure and temperature conditions: kinetic versus thermodynamic products. , 2004, Angewandte Chemie.

[132]  Kazuo Aoki,et al.  Effects of Methane Hydrate Formation On Shear Strength of Synthetic Methane Hydrate Sediments , 2005 .

[133]  Rana Roy,et al.  Special Session - Gas Hydrates: Gulf of Mexico Gas Hydrates Joint Industry Project: Overview of Leg II LWD Results , 2010 .

[134]  George J. Moridis,et al.  Response of oceanic hydrate-bearing sediments to thermal stresses , 2006 .

[135]  Ray Boswell,et al.  Scientific results from Gulf of Mexico Gas Hydrates Joint Industry Project Leg 1 drilling : introduction and overview , 2008 .

[136]  K. Weitemeyer,et al.  Marine Electromagnetic Methods for Gas Hydrate Characterization , 2008 .

[137]  Earl E. Davis,et al.  A mechanism for the formation of methane hydrate and seafloor bottom‐simulating reflectors by vertical fluid expulsion , 1992 .

[138]  Stephen Lemos,et al.  A New Technique , 2004, The American journal of sports medicine.

[139]  Ray Boswell,et al.  INVESTIGATION OF GAS HYDRATE-BEARING SANDSTONE RESERVOIRS AT THE "MOUNT ELBERT" STRATIGRAPHIC TEST WELL, MILNE POINT, ALASKA , 2008 .

[140]  Haibin Xu,et al.  Detection and estimation of gas hydrates using rock physics and seismic inversion: Examples from the northern deepwater Gulf of Mexico , 2004 .

[141]  Yoshihiro Masuda,et al.  Analysis of formation pressure test results in the Mount Elbert methane hydrate reservoir through numerical simulation , 2011 .

[142]  M. Juul Hvorslev,et al.  Subsurface exploration and sampling of soils for civil engineering purposes : report on a research project of the Committee on Sampling and Testing Soil Mechanics and Foundations Division, American Society of Civil Engineers , 1949 .

[143]  Teamrat A. Ghezzehei,et al.  Measurements of the Capillary Pressure-Saturation Relationship of Methane Hydrate Bearing Sediments , 2010 .

[144]  P. Papantoni-Kazakos,et al.  Detection and Estimation , 1989 .

[145]  Syed S. H. Rizvi,et al.  Kinetics of methane hydrate decomposition , 1987 .

[146]  Timothy S. Collett,et al.  In-situ gas hydrate hydrate saturation estimated from various well logs at the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope , 2011 .

[147]  J. C. Santamarina,et al.  Mechanical and electromagnetic properties of northern Gulf of Mexico sediments with and without THF hydrates , 2008 .

[148]  Bob A. Hardage,et al.  Evaluation of deepwater gas-hydrate systems , 2006 .

[149]  H. Melling,et al.  Origin of pingo‐like features on the Beaufort Sea shelf and their possible relationship to decomposing methane gas hydrates , 2007 .

[150]  W. Kuhs,et al.  Kinetic studies of methane-ethane mixed gas hydrates by neutron diffraction and Raman spectroscopy. , 2009, The journal of physical chemistry. B.

[151]  E. Peltzer,et al.  Deep sea NMR: Methane hydrate growth habit in porous media and its relationship to hydraulic permeability, deposit accumulation, and submarine slope stability , 2003 .

[152]  E. Hammerschmidt Formation of Gas Hydrates in Natural Gas Transmission Lines , 1934 .

[153]  Kazuo Aoki,et al.  Mechanical Properties of Natural Gas Hydrate Bearing Sediments Retrieved from Eastern Nankai Trough , 2008 .

[154]  Julio R. Valdes,et al.  Particle Clogging in Radial Flow: Microscale Mechanisms , 2006 .

[155]  Yongkoo Seol,et al.  Composite thermal conductivity in a large heterogeneous porous methane hydrate sample. , 2006, The journal of physical chemistry. B.

[156]  Ruben Juanes,et al.  Preferential Mode of gas invasion in sediments: Grain‐scale mechanistic model of coupled multiphase fluid flow and sediment mechanics , 2009 .

[157]  M. Lee,et al.  Biot–Gassmann theory for velocities of gas hydrate‐bearing sediments , 2002 .

[158]  Masato Yasuda,et al.  Well-test analysis for gas hydrate reservoirs: examination of parameters suggested by conventional analysis for the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[159]  Yash Paul Handa,et al.  Compositions, enthalpies of dissociation, and heat capacities in the range 85 to 270 K for clathrate hydrates of methane, ethane, and propane, and enthalpy of dissociation of isobutane hydrate, as determined by a heat-flow calorimeter , 1986 .

[160]  Mehran Pooladi-Darvish,et al.  Behavior of Depressurization in Type III Hydrate Reservoirs , 2014 .

[161]  Rana Roy,et al.  Gulf of Mexico Gas Hydrate Joint Industry Project Leg II: Logging-While-Drilling Operations and Challenges , 2010 .

[162]  Yoshihiro Masuda,et al.  Prediction of Gas Productivity From Eastern Nankai Trough Methane Hydrate Reservoirs , 2008 .

[163]  Takashi Uchida,et al.  Gas hydrate saturation analysis using density and nuclear magnetic-resonance logs from the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[164]  Wenyue Xu,et al.  Predicting the occurrence, distribution, and evolution of methane gas hydrate in porous marine sediments , 1999 .

[165]  Bahman Tohidi,et al.  Casing Integrity in Hydrate Bearing Sediments , 2007 .

[166]  Albert C. Reynolds,et al.  Well Testing for Radially Heterogeneous Reservoirs Under Single and Multiphase Flow Conditions , 1997 .

[167]  R. Freij-Ayoub,et al.  A wellbore stability model for hydrate bearing sediments , 2007 .

[168]  R. M. Owen,et al.  Dissociation of oceanic methane hydrate as a cause of the carbon isotope excursion at the end of the Paleocene , 1995 .

[169]  Scott J. Wilson,et al.  AN INTERNATIONAL EFFORT TO COMPARE GAS HYDRATE RESERVOIR SIMULATORS , 2008 .

[170]  Daniel R. McConnell,et al.  Images of the Base of Gas Hydrate Stability, Northwest Walker Ridge, Gulf of Mexico , 2002 .

[171]  S. Belfroid,et al.  Gas Production From Oceanic Class 2 Hydrate Accumulations , 2007 .

[172]  T. Collett GAS HYDRATE RESOURCES OF THE UNITED STATES , 2001 .

[173]  E. Dendy Sloan,et al.  Introductory overview: Hydrate knowledge development , 2004 .

[174]  P. Schultheiss,et al.  Wireline Coring and Analysis under Pressure: Recent Use and Future Developments of the HYACINTH System , 2009 .

[175]  G. J. Moridis Gas Production From a Cold, Stratigraphically Bounded Hydrate Deposit at the Mount Elbert Site, North Slope, Alaska , 2009 .

[176]  M. Juul Hvorslev,et al.  Subsurface exploration and sampling of soil for civil engineering purposes , 1949 .

[177]  Adam L. Ballard,et al.  The Next Generation of Hydrate Prediction: An Overview , 2002 .

[178]  T. Ebinuma,et al.  SS Gas Hydrate: Prediction of Production Test Performances in Eastern Nankai Trough Methane Hydrate Reservoirs Using 3D Reservoir Model , 2010 .

[179]  Yukio Nakata,et al.  Basic research on the mechanical behavior of methane hydrate-sediments mixture , 2005 .

[180]  Joo-yong Lee,et al.  Hydrate-bearing sediments: Formation and geophysical properties , 2007 .

[181]  L. Mattar,et al.  The Primary Pressure Derivative (Ppd) A New Diagnostic Tool In Well Test Interpretation , 1992 .

[182]  Hitoshi Sugiyama,et al.  DEVELOPMENT OF A MONITORING SYSTEM FOR THE JOGMEC/NRCAN/AURORA MALLIK GAS HYDRATE PRODUCTION TEST PROGRAM , 2008 .

[183]  George J. Moridis,et al.  Comparison of kinetic and equilibrium reaction models in simulating gas hydrate behavior in porous media , 2006 .

[184]  Stephen H. Kirby,et al.  Peculiarities of Methane Clathrate Hydrate Formation and Solid-State Deformation, Including Possible Superheating of Water Ice , 1996, Science.

[185]  Johannes Kulenkampff,et al.  Pore space hydrate formation in a glass bead sample from methane dissolved in water , 2005 .

[186]  Richard E. Lewis,et al.  Modelling the response of the Cased Hole Formation Resistivity tool in order to determine the depth of gas hydrate dissociation during the thermal test in the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate production research well , 2005 .

[187]  Richard L. Smith,et al.  Acting Director , 1978 .

[188]  Jack Dvorkin,et al.  The challenge of scale in seismic mapping of hydrate and solutions , 2006 .

[189]  M. Kowalsky,et al.  Depressurization-Induced Gas Production From Class-1 Hydrate Deposits , 2005 .

[190]  R. D. Malone,et al.  Effects of Gas Composition and Geothermal Properties on the Thickness and Depth of Natural-Gas-Hydrate Zones , 1985 .

[191]  Lars Inge Berge,et al.  Measured acoustic wave velocities of R11 (CCl3F) hydrate samples with and without sand as a function of hydrate concentration , 1999 .

[192]  T S Collett,et al.  Assessments of gas hydrate concentrations estimated from sonic logs in the JAPEX/JNOC/GSC et al. Mallik 5L-38 gas hydrate research production well , 2005 .

[193]  Stephen H. Kirby,et al.  Scanning Electron Microscopy investigations of laboratory-grown gas clathrate hydrates formed from melting ice, and comparison to natural hydrates , 2004 .

[194]  E. Spangenberg,et al.  Physical properties of gas hydrate bearing sediments , 2000 .

[195]  D. Archer Methane hydrate stability and anthropogenic climate change , 2007 .

[196]  Scott J. Wilson,et al.  Regional long-term production modeling from a single well test, Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope , 2011 .

[197]  Y F Sun,et al.  Analysis of electromagnetic propagation tool response in gas-hydrate-bearing formations , 2005 .

[198]  M. Kowalsky,et al.  Feasibility of monitoring gas hydrate production with time-lapse VSP , 2009 .

[199]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[200]  M. Lee,et al.  Gas hydrate saturations estimated from fractured reservoir at Site NGHP-01-10, Krishna-Godavari Basin, India , 2009 .

[201]  Mehran Pooladi-Darvish,et al.  Analytical solution for gas production from hydrate reservoirs underlain with free gas , 2009 .

[202]  Tom Lunne,et al.  Effects of sample disturbance and consolidation procedures on measured shear strength of soft marine Norwegian clays , 2006 .

[203]  D. J. Taylor,et al.  Seismic Prospecting for Gas-hydrate and Associated Free-gas Prospects in the Milne Point Area of Northern Alaska , 2009 .

[204]  W. Waite,et al.  Methane hydrate formation in partially water-saturated Ottawa sand , 2004 .

[205]  Robert L. Kleinberg,et al.  Fracture-controlled gas hydrate systems in the northern Gulf of Mexico , 2008 .

[206]  Howard Carter,et al.  A PRELIMINARY INVESTIGATION , 2010 .

[207]  S. Dallimore,et al.  Summary and implications of the Mallik 2002 Gas Hydrate Production Research Well Program , 2005 .

[208]  Namita Jaiswal,et al.  Measurement of gas-water relative permeabilities in hydrate systems , 2004 .

[209]  Shahab Gerami,et al.  An Early-Time Model for Drawdown Testing of a Hydrate-Capped Gas Reservoir , 2009 .

[210]  D. Peters,et al.  Gumusut-Kakap Project: Geohazard Characterisation and Impact on Field Development Plans , 2008 .

[211]  M. Clarke,et al.  Determination of the activation energy and intrinsic rate constant of methane gas hydrate decomposition , 2001 .

[212]  M. Kowalsky,et al.  TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media , 2008 .

[213]  Tae Sup Yun,et al.  Observations related to tetrahydrofuran and methane hydrates for laboratory studies of hydrate‐bearing sediments , 2007 .

[214]  Gilles Bellefleur,et al.  Acoustic impedance inversion and seismic reflection continuity analysis for delineating gas hydrate resources near the Mallik research sites, Mackenzie Delta, Northwest Territories, Canada , 2009 .

[215]  Rajagopal Raghavan,et al.  Well Test Analysis , 2018, Petroleum Engineering.

[216]  Barry Freifeld,et al.  Investigating Methane Hydrate in Sediments using X-Ray Computed Tomography , 2004 .

[217]  J. Wright,et al.  GEOLOGIC AND POROUS MEDIA FACTORS AFFECTING THE 2007 PRODUCTION RESPONSE CHARACTERISTICS OF THE JOGMEC/NRCAN/AURORA MALLIK GAS HYDRATE PRODUCTION RESEARCH WELL , 2008 .

[218]  Tao He,et al.  Gas hydrate on the northern Cascadia margin: regional geophysics and structural framework , 2006 .

[219]  Dianna Shelander,et al.  Predicting saturation of gas hydrates using pre-stack seismic data, Gulf of Mexico , 2010 .

[220]  I︠u︡. F. Makogon Hydrates of Hydrocarbons , 1997 .

[221]  P. Bishnoi,et al.  A kinetic study of methane hydrate formation , 1983 .

[222]  Warren T. Wood,et al.  Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico , 2008 .

[223]  A. C. Bumb,et al.  Gas-well testing in the presence of desorption for coalbed methane and devonian shale , 1988 .

[224]  Ross Anderson,et al.  Visual observation of gas hydrate formation in glass micromodels , 2001 .

[225]  J. Carlos Santamarina,et al.  Volume change associated with formation and dissociation of hydrate in sediment , 2010 .

[226]  Hideo Narita,et al.  Formation, growth and ageing of clathrate hydrate crystals in a porous medium , 2006 .

[227]  W. F. Agena,et al.  Pre- and post-drill comparison of the Mount Elbert gas hydrate prospect at the Milne Point area, Alaska North Slope , 2009 .

[228]  Tae Sup Yun,et al.  Physical properties of hydrate‐bearing sediments , 2009 .

[229]  Tae Sup Yun,et al.  Thermal conductivity of hydrate‐bearing sediments , 2009 .

[230]  Gilles Bellefleur,et al.  Seismic characterization and continuity analysis of gas-hydrate horizons near Mallik research wells, Mackenzie Delta, Canada , 2006 .

[231]  George J. Moridis,et al.  Feasibility of Monitoring Gas-Hydrate Production With Time-Lapse Vertical Seismic Profiling , 2010 .

[232]  J. MoridisG.,et al.  Development of a Numerical Simulator for Analyzing the Geomechanical Performance of Hydrate-Bearing Sediments , 2008 .

[233]  Adam Koesoemadinata,et al.  Exploration for gas hydrates in the deepwater, northern Gulf of Mexico: Part I. A seismic approach based on geologic model, inversion, and rock physics principles , 2008 .