High Sensitivity Polymer Photosensors for Image Sensing Applications

Abstract Conjugated polymers are photosensing materials with high quantum efficiency. Large area photosensors fabricated in the metalpolymer-metal configuration show high photosensitivity, 0.1–0.5 A/Watt in the visible and near UV; i.e., sensitivity comparable to that obtained from inorganic semiconductors. The processibility of these semiconducting polymers enables the fabrication of large area photosensors on substrates (either flexible or rigid) of desire shapes, hybridized or integrated with optical or electronic devices. In addition to single and/or integrated devices for energy conversion or photosensing applications, passive photodiode arrays and matrices were fabricated for large area, full-color, image sensing. These photodiode arrays have high photosensitivity, low dark current, and large dynamic range. Photodetection with desired spectral response or multi-band selection are also demonstrated.

[1]  Jun Gao,et al.  High-sensitivity photodetectors made with charge-transfer polymer blends , 1997, Photonics West.

[2]  E. Lerner Applications drive new detector technologies , 1996 .

[3]  J. Hummelen,et al.  Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions , 1995, Science.

[4]  Alan J. Heeger,et al.  Charge separation and photovoltaic conversion in polymer composites with internal donor/acceptor heterojunctions , 1995 .

[5]  C. A. Walsh,et al.  Efficient photodiodes from interpenetrating polymer networks , 1995, Nature.

[6]  Jie Yao,et al.  Preparation and Characterization of Fulleroid and Methanofullerene Derivatives , 1995 .

[7]  A. J. Heeger,et al.  Semiconducting polymer diodes: Large size, low cost photodetectors with excellent visible‐ultraviolet sensitivity , 1994 .

[8]  Niyazi Serdar Sariciftci,et al.  REVERSIBLE, METASTABLE, ULTRAFAST PHOTOINDUCED ELECTRON TRANSFER FROM SEMICONDUCTING POLYMERS TO BUCKMINSTERFULLERENE AND IN THE CORRESPONDING DONOR/ACCEPTOR HETEROJUNCTIONS , 1994 .

[9]  Moses,et al.  Sensitization of the photoconductivity of conducting polymers by C60: Photoinduced electron transfer. , 1993, Physical review. B, Condensed matter.

[10]  David Braun,et al.  Semiconducting polymer‐buckminsterfullerene heterojunctions: Diodes, photodiodes, and photovoltaic cells , 1993 .

[11]  A. J. Heeger,et al.  Photoinduced Electron Transfer from a Conducting Polymer to Buckminsterfullerene , 1992, Science.