Particle size distributions from heavy-duty diesel engine operated on low-sulfur marine fuel

Abstract Particulate matter (PM) emission characteristics of a four-stroke diesel engine were investigated while operating on low-sulfur marine gas oil. PM size distributions appeared to be unimodal (accumulation mode) with fairly constant count median diameter (CMD) of 55–65 nm for all test modes at maximum engine speed. The slightly bigger CMD of around 76 nm for unimodal particle size distributions at 1080 rpm at medium- and high-load conditions was observed. The bimodal size distribution was registered only at very low load with nuclei CMD being below 15 nm, accumulation CMD of around 82 nm and percentage of nanoparticles of around 65%. The study of primary dilution air temperature (PDT) effect revealed a significant reduction in total particle number for all operating conditions when PDT was increased from 30 °C to 400 °C. This also had an effect on particle CMD values and is believed to be due to evaporation of sulfuric acid with bound water and certain organic fractions that were formed during dilution process (at PDT = 30 °C). At very low load intermediate speed conditions, the heating of dilution air had a very little effect on the nucleation mode, which could suggest that it primarily consists of heavy hydrocarbons associated with lubrication oil.

[1]  A. Nel,et al.  Ultrafine particulate pollutants induce oxidative stress and mitochondrial damage. , 2002, Environmental health perspectives.

[2]  K. T. Whitby,et al.  Aerosol classification by electric mobility: apparatus, theory, and applications , 1975 .

[3]  Richard E. Chase,et al.  Size Distributions of Motor Vehicle Exhaust PM: A Comparison Between ELPI and SMPS Measurements , 2000 .

[4]  Hans-Erik Ångström,et al.  Evaluation of Techniques for Transient PM-Measurements , 2008 .

[5]  Carl-Johan Fogelholm,et al.  Emissions from large-scale medium-speed diesel engines: 2. Influence of fuel type and operating mode , 2008 .

[6]  David B. Kittelson,et al.  Variability in Particle Emission Measurements in the Heavy Duty Transient Test , 1991 .

[7]  J. Warren HEALTH EFFECTS OF DIESEL EXHAUST: AN HEI PERSPECTIVE , 2000 .

[8]  Jyrki Ristimäki,et al.  Chemical and physical characterization of exhaust particulate matter from a marine medium speed diesel engine , 2010 .

[9]  K. Chun,et al.  Calculation of mass-weighted distribution of diesel particulate matters using primary particle density , 2011 .

[10]  Arto Sarvi,et al.  Emissions from large-scale medium-speed diesel engines: 1. Influence of engine operation mode and turbocharger , 2008 .

[11]  C. rd,et al.  Epidemiology of fine particulate air pollution and human health: biologic mechanisms and who's at risk? , 2000 .

[12]  David B. Kittelson,et al.  On-line measurements of diesel nanoparticle composition and volatility , 2003 .

[13]  A. De Filippo,et al.  Diesel nucleation mode particles: semivolatile or solid? , 2008, Environmental science & technology.

[14]  David B. Kittelson,et al.  Further studies of electrostatic collection and agglomeration of diesel particles , 1991 .

[15]  John H. Johnson,et al.  The Effect of Fuel and Engine Design on Diesel Exhaust Particle Size Distributions , 1996 .

[16]  Jian Wang,et al.  Studies of Diesel Engine Particle Emissions During Transient Operations Using an Engine Exhaust Particle Sizer , 2006 .

[17]  Imad A. Khalek,et al.  Nanoparticle growth during dilution and cooling of diesel exhaust: Experimental investigation and theoretical assessment , 2000 .

[18]  Klaus Willeke,et al.  Aerosol Measurement: Principles, Techniques, and Applications , 2001 .

[19]  David B. Kittelson,et al.  Diesel Trap Performance: Particle Size Measurements and Trends , 1998 .

[20]  Michael P. Walsh,et al.  Global Trends in Diesel Emissions Regulation - A 2001 Update , 2001 .

[21]  Zhi Ning,et al.  Experimental investigation of the effect of exhaust gas cooling on diesel particulate , 2004 .

[22]  Dan Haupt,et al.  Particulate Emissions From an Ethanol Fueled Heavy-Duty Diesel Engine Equipped With EGR, Catalyst and DPF , 2004 .

[23]  Topi Rönkkö,et al.  Dependence between nonvolatile nucleation mode particle and soot number concentrations in an EGR equipped heavy-duty Diesel engine exhaust. , 2010, Environmental science & technology.

[24]  Y. Ibuki,et al.  Simple and easy method to evaluate uptake potential of nanoparticles in mammalian cells using a flow cytometric light scatter analysis. , 2007, Environmental science & technology.

[25]  Güunter Oberdürster Toxicology of ultrafine particles: in vivo studies , 2000, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.

[26]  D. Kittelson Engines and nanoparticles: a review , 1998 .

[27]  Martin Mohr,et al.  Comprehensive particle characterization of modern gasoline and diesel passenger cars at low ambient temperatures , 2005 .

[28]  Liisa Pirjola,et al.  Nucleation mode particles with a nonvolatile core in the exhaust of a heavy duty diesel vehicle. , 2007, Environmental science & technology.

[29]  E. R. Jayaratne,et al.  Influence of diesel fuel sulfur on nanoparticle emissions from city buses. , 2006, Environmental science & technology.

[30]  R. Harrison,et al.  Particle size distribution from a modern heavy duty diesel engine , 1999 .

[31]  S. Schürch,et al.  Interaction of fine particles and nanoparticles with red blood cells visualized with advanced microscopic techniques. , 2006, Environmental science & technology.

[32]  J. Jokiniemi,et al.  Particulate emissions from large-scale medium-speed diesel engines: 2. Chemical composition , 2011 .

[33]  Jon Andersson,et al.  Particle measurement programme (PMP) light-duty inter-laboratory exercise: comparison of different particle number measurement systems , 2008 .

[34]  G. Martini,et al.  Evaluation of the particle measurement programme (PMP) protocol to remove the vehicles' exhaust aerosol volatile phase. , 2010, The Science of the total environment.

[35]  David B. Kittelson,et al.  On-road and laboratory evaluation of combustion aerosols-Part1: Summary of diesel engine results , 2006 .

[36]  H. Lüders,et al.  The Role of Sampling Conditions in Particle Size Distribution Measurements , 1998 .

[37]  M. Kasper Nanoparticle Exhaust Gas Measurement: On-Line Response, High Sensitivity, Low Cost , 2003 .

[38]  W. Kreyling,et al.  Translocation of Inhaled Ultrafine Particles to the Brain , 2004, Inhalation toxicology.

[39]  Kebin He,et al.  Influence of fuel sulfur on the characterization of PM10 from a diesel engine , 2009 .

[40]  David B. Kittelson,et al.  REVIEW OF DIESEL PARTICULATE MATTER SAMPLING METHODS , 1999 .

[41]  D. Kittelson,et al.  The influence of dilution conditions on diesel exhaust particle size distribution measurements , 1999 .

[42]  R. W. Waytulonis,et al.  Chemical analysis of diesel engine nanoparticles using a nano-DMA/thermal desorption particle beam mass spectrometer. , 2001, Environmental science & technology.

[43]  Leonidas Ntziachristos,et al.  Sampling Conditions for the Measurement of Nucleation Mode Particles in the Exhaust of a Diesel Vehicle , 2004 .

[44]  H. Burtscher Physical characterization of particulate emissions from diesel engines: a review , 2005 .

[45]  M. Maricq,et al.  Vehicle Exhaust Particle Size Distributions: A Comparison of Tailpipe and Dilution Tunnel Measurements , 1999 .

[46]  Roy M. Harrison,et al.  INVESTIGATION OF ULTRAFINE PARTICLE FORMATION DURING DIESEL EXHAUST DILUTION , 1999 .

[47]  B. Holmén,et al.  Ultrafine PM emissions from natural gas, oxidation-catalyst diesel, and particle-trap diesel heavy-duty transit buses. , 2002, Environmental science & technology.

[48]  D. Jagadish,et al.  Performance and emission characteristics of diesel engine run on biofuels based on experimental and semi analytical methods. , 2011 .

[49]  D. Dockery,et al.  An association between air pollution and mortality in six U.S. cities. , 1993, The New England journal of medicine.

[50]  Gyu-Baek Cho,et al.  MEASUREMENT OF SIZE DISTRIBUTION OF DIESEL PARTICLES: EFFECTS OF INSTRUMENTS, DILUTION METHODS, AND MEASURING POSITIONS , 2005 .

[51]  Jorma Keskinen,et al.  Electrical low pressure impactor , 1992 .

[52]  Nigel N Clark,et al.  Factors Affecting Heavy-Duty Diesel Vehicle Emissions , 2002, Journal of the Air & Waste Management Association.

[53]  J H Hong,et al.  Particle number and size distribution characteristics from diesel- and liquefied-natural-gas-fuelled buses for various emission certification modes in the Republic of Korea , 2010 .

[54]  J. Jokiniemi,et al.  Particulate emissions from large-scale medium-speed diesel engines: 1. Particle size distribution , 2011 .