A fully integrated microbattery for an implantable microelectromechanical system

Abstract The Wireless Integrated Microsystems Engineering Research Center’s Intraocular Sensor (WIMS-ERC IOS) was studied as a model system for an integrated, autonomous implantable device. In the present study, we had four objectives: (1) select and designing an optimized power supply for the WIMS-IOS; (2) develop a fabrication technique allowing small scale, low-cost, and integrable fabrication for CMOS systems, and experimentally demonstrate a microscopic power source; (3) map capacity and lifetime of several fabricated microbatteries; (4) determine the effects of miniaturization on capacity, lifetime and device architecture. Physical vapor deposition (PVD) was used to deposit thin layers (≤1 μm) of metal sequentially onto glass substrates (SiO 2 , as used in the device). To map the influence of size over cell capacity and cycle life, we fabricated and tested five stand-alone cells using a Solartron ® 1470E battery tester and a Maccor ® 4000 series tester. A sixth battery was fabricated to investigate the effects of system integration, variable discharge rate and size reduction simultaneously. The highest experimental capacity among the larger cells O(cm 2 ) was 100 μAh, achieved by IOS-C-1 at 250 μA (1.4 C) discharge. Among O(mm 2 ) cells, IOS-M-1 achieved the highest capacity (2.75 μAh, ∼76% of theoretical) at 2.5 μA discharge (0.7 C rate).

[1]  J. Bates,et al.  Lithium silicon tin oxynitride (LiySiTON): high-performance anode in thin-film lithium-ion batteries for microelectronics , 1999 .

[2]  Liwei Lin,et al.  Electrolyte-based on-demand and disposable microbattery , 2003 .

[3]  A. P. Karpinski,et al.  Silver based batteries for high power applications , 2000 .

[4]  P. Mohseni,et al.  Wireless multichannel biopotential recording using an integrated FM telemetry circuit , 2005, IEEE Transactions on Neural Systems and Rehabilitation Engineering.

[5]  K. Striebel,et al.  Electrochemical Behavior of LiMn2 O 4 and LiCoO2 Thin Films Produced with Pulsed Laser Deposition , 1996 .

[6]  J. Bates Thin-Film Lithium and Lithium-Ion Batteries , 2000 .

[7]  A. Cardenas-Valencia,et al.  Aluminum-anode, silicon-based micro-cells for powering expendable MEMS and lab-on-a-chip devices , 2007 .

[8]  Daeyeon Kim,et al.  The Phoenix Processor: A 30pW platform for sensor applications , 2008, 2008 IEEE Symposium on VLSI Circuits.

[9]  Lei Wang,et al.  Implementation of multichannel sensors for remote biomedical measurements in a microsystems format , 2004, IEEE Transactions on Biomedical Engineering.

[10]  A. Shukla,et al.  Galvanostatic non-destructive characterization of alkaline silver–zinc cells , 2003 .

[11]  M. Humayun,et al.  REVERSIBLE THERMOSENSITIVE GLUE FOR RETINAL IMPLANTS , 2007, Retina.

[12]  Ann Marie Sastry,et al.  An algorithm for selection and design of hybrid power supplies for MEMS with a case study of a micro-gas chromatograph system , 2005 .

[13]  P. Krulevitch,et al.  Vertical-actuated electrostatic comb drive with in situ capacitive position correction for application in phase shifting diffraction interferometry , 2003 .

[14]  C. W. Berry,et al.  A cyborg beetle: Insect flight control through an implantable, tetherless microsystem , 2008, 2008 IEEE 21st International Conference on Micro Electro Mechanical Systems.

[15]  Ann Marie Sastry,et al.  POWER (power optimization for wireless energy requirements): A MATLAB based algorithm for design of hybrid energy systems , 2006 .

[16]  B. S. Kwak,et al.  Thin-film rechargeable lithium batteries , 1994 .

[17]  Patrick D Wolf,et al.  A multichannel telemetry system for single unit neural recordings , 2004, Journal of Neuroscience Methods.

[18]  Kensall D. Wise,et al.  Chip-Scale Integration of Data-Gathering Microsystems , 2006, Proceedings of the IEEE.

[19]  Wei Shyy,et al.  Erratum: Numerical Simulation of Intercalation-Induced Stress in Li-Ion Battery Electrode Particles [ J. Electrochem. Soc. , 154 , A910 (2007) ] , 2007 .

[20]  Nancy J. Dudney,et al.  Preferred Orientation of Polycrystalline LiCoO2 Films , 2000 .

[21]  J. Pereira‐Ramos,et al.  High-Capacity Crystalline V2O5 Thick Films Prepared by RF Sputtering as Positive Electrodes for Rechargeable Lithium Microbatteries , 2006 .

[22]  N. Dudney,et al.  “Lithium‐Free” Thin‐Film Battery with In Situ Plated Li Anode , 2000 .

[23]  A. Sastry,et al.  Particle Compression and Conductivity in Li-Ion Anodes with Graphite Additives , 2004 .

[24]  M. Venkatraman,et al.  A model for the silver–zinc battery during high rates of discharge , 2007 .

[25]  K. Striebel,et al.  Electrochemical Studies of Substituted Spinel Thin Films , 1999 .

[26]  Larry L. Howell,et al.  Microbatteries for self-sustained hybrid micropower supplies , 2002 .

[27]  Bruce Dunn,et al.  Three-dimensional battery architectures. , 2004, Chemical reviews.

[28]  K. Zaghib,et al.  Extraction of Layerwise Conductivities in Carbon-Enhanced, Multilayered LiFePO4 Cathodes , 2005 .

[29]  Fabio Albano,et al.  Design of an implantable power supply for an intraocular sensor, using POWER (power optimization for wireless energy requirements) , 2007 .

[30]  David Blaauw,et al.  Low-voltage circuit design for widespread sensing applications , 2008, 2008 IEEE International Symposium on Circuits and Systems.

[31]  Andreas Nieder,et al.  Miniature stereo radio transmitter for simultaneous recording of multiple single-neuron signals from behaving owls , 2000, Journal of Neuroscience Methods.

[32]  J. Harb,et al.  Microscopic Nickel-Zinc Batteries for Use in Autonomous Microsystems , 2001 .

[33]  T. Richardson,et al.  Characterization of pulsed laser-deposited LiMn2O4 thin films for rechargeable lithium batteries , 1998 .

[34]  Hundred-micron-sized all-solid-state Li secondary battery arrays embedded in a Si substrate , 2002 .

[35]  Kathryn A. Striebel,et al.  Cu2Sb thin film electrodes prepared by pulsed laser deposition f or lithium batteries , 2003 .

[36]  N. Dudney,et al.  Solid state thin-film lithium battery systems , 1999 .

[37]  D. Linden Handbook Of Batteries , 2001 .

[38]  S. D. Jones,et al.  Development and performance of a rechargeable thin-film solid-state microbattery , 1995 .