Carbon Nanotubes and Graphene for Flexible Electrochemical Energy Storage: from Materials to Devices

Flexible electrochemical energy storage (FEES) devices have received great attention as a promising power source for the emerging field of flexible and wearable electronic devices. Carbon nanotubes (CNTs) and graphene have many excellent properties that make them ideally suited for use in FEES devices. A brief definition of FEES devices is provided, followed by a detailed overview of various structural models for achieving different FEES devices. The latest research developments on the use of CNTs and graphene in FEES devices are summarized. Finally, future prospects and important research directions in the areas of CNT- and graphene-based flexible electrode synthesis and device integration are discussed.

[1]  Y. Bando,et al.  Cable‐Type Supercapacitors of Three‐Dimensional Cotton Thread Based Multi‐Grade Nanostructures for Wearable Energy Storage , 2013, Advanced materials.

[2]  Farouk Fardoun,et al.  Review and comparative study of analytical modeling for the elastic properties of textile composites , 2013 .

[3]  E. Xie,et al.  An overview of carbon materials for flexible electrochemical capacitors. , 2013, Nanoscale.

[4]  Yi Cui,et al.  Energy and environmental nanotechnology in conductive paper and textiles , 2012 .

[5]  K. Hata,et al.  Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes , 2004, Science.

[6]  Woo Y. Lee,et al.  Graphene supercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide , 2011 .

[7]  Lele Peng,et al.  Chemically integrated two-dimensional hybrid zinc manganate/graphene nanosheets with enhanced lithium storage capability. , 2014, ACS nano.

[8]  M. Shanahan,et al.  Elastic behaviour of a stretched woven cloth , 2008 .

[9]  Myung Jong Kim,et al.  Macroscopic, Neat, Single-Walled Carbon Nanotube Fibers , 2002, Science.

[10]  Zhiqian Wang,et al.  Development of flexible secondary alkaline battery with carbon nanotube enhanced electrodes , 2014 .

[11]  Ping Zhang,et al.  Flexible free-standing TiO2/graphene/PVdF films as anode materials for lithium-ion batteries , 2012 .

[12]  Jian Chang,et al.  Coaxial fiber supercapacitor using all-carbon material electrodes. , 2013, ACS nano.

[13]  Feng Li,et al.  Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates , 2012, Proceedings of the National Academy of Sciences.

[14]  Markku Rouvala,et al.  Nanomaterial-enhanced all-solid flexible zinc--carbon batteries. , 2010, ACS nano.

[15]  Feng Li,et al.  Carbon nanotubes/activated carbon hybrid with ultrahigh surface area for electrochemical capacitors , 2015 .

[16]  Yi Xie,et al.  Surface chemical-modification for engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials. , 2015, Chemical Society reviews.

[17]  G. Whitesides,et al.  Solvent compatibility of poly(dimethylsiloxane)-based microfluidic devices. , 2003, Analytical chemistry.

[18]  Chunmei Ban,et al.  Nanostructured Fe3O4/SWNT Electrode: Binder‐Free and High‐Rate Li‐Ion Anode , 2010, Advanced materials.

[19]  Hui‐Ming Cheng,et al.  Efficient growth of high-quality graphene films on Cu foils by ambient pressure chemical vapor deposition , 2010 .

[20]  M. El‐Kady,et al.  Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors , 2012, Science.

[21]  Zhixin Chen,et al.  Silicon/Single-Walled Carbon Nanotube Composite Paper as a Flexible Anode Material for Lithium Ion Batteries , 2010 .

[22]  P. Poulin,et al.  Macroscopic fibers and ribbons of oriented carbon nanotubes. , 2000, Science.

[23]  David T. Gethin,et al.  Ultra-thin flexible screen printed rechargeable polymer battery for wearable electronic applications , 2015 .

[24]  Lai-Peng Ma,et al.  25th Anniversary Article: Carbon Nanotube‐ and Graphene‐Based Transparent Conductive Films for Optoelectronic Devices , 2014, Advanced materials.

[25]  Menghe Miao,et al.  High‐Performance Two‐Ply Yarn Supercapacitors Based on Carbon Nanotubes and Polyaniline Nanowire Arrays , 2013, Advanced materials.

[26]  Synergistic toughening of composite fibres by self-alignment of reduced graphene oxide and carbon nanotubes , 2012, Nature communications.

[27]  Wei Zhou,et al.  True solutions of single-walled carbon nanotubes for assembly into macroscopic materials , 2009, Nature Nanotechnology.

[28]  Guangmin Zhou,et al.  Graphene-based integrated electrodes for flexible lithium ion batteries , 2015 .

[29]  G. Wallace,et al.  Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper , 2008 .

[30]  Huisheng Peng,et al.  Winding aligned carbon nanotube composite yarns into coaxial fiber full batteries with high performances. , 2014, Nano letters.

[31]  Hongwei Zhu,et al.  Synthesis of layered birnessite-type manganese oxide thin films on plastic substrates by chemical bath deposition for flexible transparent supercapacitors , 2011 .

[32]  Guangyuan Zheng,et al.  Silicon-conductive nanopaper for Li-ion batteries , 2013 .

[33]  J. Lee,et al.  One-step, confined growth of bimetallic tin-antimony nanorods in carbon nanotubes grown in situ for reversible Li+ ion storage. , 2006, Angewandte Chemie.

[34]  Hui-Ming Cheng,et al.  Recent advances in graphene-based planar micro-supercapacitors for on-chip energy storage , 2014 .

[35]  G. Shi,et al.  Graphene based new energy materials , 2011 .

[36]  K. Cho,et al.  Graphite/Silicon Hybrid Electrodes using a 3D Current Collector for Flexible Batteries , 2014, Advanced materials.

[37]  Qiang Zhang,et al.  Hierarchical carbon nanotube membrane with high packing density and tunable porous structure for high voltage supercapacitors , 2012 .

[38]  Hui Dou,et al.  Polypyrrole/carbon nanotube nanocomposite enhanced the electrochemical capacitance of flexible graphene film for supercapacitors , 2012 .

[39]  Jens Tübke,et al.  Development and costs calculation of lithium–sulfur cells with high sulfur load and binder free electrodes , 2013 .

[40]  Jiho Lee,et al.  Stretchable carbon nanotube/ion-gel supercapacitors with high durability realized through interfacial microroughness. , 2014, ACS applied materials & interfaces.

[41]  T. Chou,et al.  Laminated ultrathin chemical vapor deposition graphene films based stretchable and transparent high-rate supercapacitor. , 2014, ACS nano.

[42]  Teng Zhai,et al.  Conductive membranes of EVA filled with carbon black and carbon nanotubes for flexible energy-storage devices , 2013 .

[43]  Jianjun Li,et al.  Graphene-coated plastic film as current collector for lithium/sulfur batteries , 2013 .

[44]  Yi Cui,et al.  Stretchable, porous, and conductive energy textiles. , 2010, Nano letters.

[45]  John A. Rogers,et al.  Buckling of a stiff thin film on a compliant substrate in large deformation , 2008 .

[46]  Carter S. Haines,et al.  Biscrolling Nanotube Sheets and Functional Guests into Yarns , 2011, Science.

[47]  Chongwu Zhou,et al.  Hierarchical three-dimensional ZnCo₂O₄ nanowire arrays/carbon cloth anodes for a novel class of high-performance flexible lithium-ion batteries. , 2012, Nano letters.

[48]  Dingshan Yu,et al.  Scalable synthesis of hierarchically structured carbon nanotube–graphene fibres for capacitive energy storage , 2014, Nature Nanotechnology.

[49]  Yang-Kook Sun,et al.  Challenges facing lithium batteries and electrical double-layer capacitors. , 2012, Angewandte Chemie.

[50]  Feng Hou,et al.  Continuous Multilayered Carbon Nanotube Yarns , 2010, Advanced materials.

[51]  Won Jun Lee,et al.  Tailored Assembly of Carbon Nanotubes and Graphene , 2011 .

[52]  J. Kong,et al.  Reversibly Compressible, Highly Elastic, and Durable Graphene Aerogels for Energy Storage Devices under Limiting Conditions , 2015 .

[53]  Jun Wei,et al.  Emergence of fiber supercapacitors. , 2015, Chemical Society reviews.

[54]  Feng Li,et al.  A flexible nanostructured sulphur–carbon nanotube cathode with high rate performance for Li-S batteries , 2012 .

[55]  Xin Cai,et al.  Integrated power fiber for energy conversion and storage , 2013 .

[56]  Pulickel M. Ajayan,et al.  Transparent, flexible supercapacitors from nano-engineered carbon films , 2012, Scientific Reports.

[57]  Wei Lv,et al.  Vertically Aligned Carbon Nanotubes Grown on Graphene Paper as Electrodes in Lithium‐Ion Batteries and Dye‐Sensitized Solar Cells , 2011 .

[58]  D. Su,et al.  Nanostructured carbon and carbon nanocomposites for electrochemical energy storage applications. , 2010, ChemSusChem.

[59]  T. Someya,et al.  Bending experiment on pentacene field-effect transistors on plastic films , 2005 .

[60]  Jianfeng Zang,et al.  Stretchable and High-Performance Supercapacitors with Crumpled Graphene Papers , 2014, Scientific Reports.

[61]  Lan Jiang,et al.  Highly Compression‐Tolerant Supercapacitor Based on Polypyrrole‐mediated Graphene Foam Electrodes , 2013, Advanced materials.

[62]  Yi Xie,et al.  Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors , 2013, Nature Communications.

[63]  J. Coleman,et al.  Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites , 2006 .

[64]  Lele Peng,et al.  Two-dimensional nanosheets based Li-ion full batteries with high rate capability and flexibility , 2015 .

[65]  K. Hata,et al.  A stretchable carbon nanotube strain sensor for human-motion detection. , 2011, Nature nanotechnology.

[66]  Peng-Cheng Ma,et al.  Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: A review , 2012 .

[67]  Xiaodong Chen,et al.  Highly Stretchable, Integrated Supercapacitors Based on Single‐Walled Carbon Nanotube Films with Continuous Reticulate Architecture , 2013, Advanced materials.

[68]  Zhigao Huang,et al.  Multi-responsive actuators based on a graphene oxide composite: intelligent robot and bioinspired applications. , 2017, Nanoscale.

[69]  Yuhai Hu,et al.  Flexible rechargeable lithium ion batteries: advances and challenges in materials and process technologies , 2014 .

[70]  Tao Chen,et al.  Transparent and stretchable high-performance supercapacitors based on wrinkled graphene electrodes. , 2014, ACS nano.

[71]  Yi Cui,et al.  Thin, flexible secondary Li-ion paper batteries. , 2010, ACS nano.

[72]  John A. Rogers,et al.  Mechanics of stretchable batteries and supercapacitors , 2015 .

[73]  Satish Kumar,et al.  Properties and Structure of Nitric Acid Oxidized Single Wall Carbon Nanotube Films , 2004 .

[74]  Lei Zhang,et al.  A review of electrode materials for electrochemical supercapacitors. , 2012, Chemical Society reviews.

[75]  Young-Il Jang,et al.  TEM Study of Electrochemical Cycling‐Induced Damage and Disorder in LiCoO2 Cathodes for Rechargeable Lithium Batteries , 1999 .

[76]  Huisheng Peng,et al.  A highly stretchable, fiber-shaped supercapacitor. , 2013, Angewandte Chemie.

[77]  Jiaoyang Li,et al.  Flexible Hybrid Paper Made of Monolayer Co3O4 Microsphere Arrays on rGO/CNTs and Their Application in Electrochemical Capacitors , 2012 .

[78]  Bin Wang,et al.  Preparation of Nanowire Arrays of Amorphous Carbon Nanotube-Coated Single Crystal SnO2 , 2008 .

[79]  Candace K. Chan,et al.  Printable thin film supercapacitors using single-walled carbon nanotubes. , 2009, Nano letters.

[80]  Shoushan Fan,et al.  Nanotechnology: Spinning continuous carbon nanotube yarns , 2002, Nature.

[81]  Hui-Ming Cheng,et al.  A nanosized Fe2O3 decorated single-walled carbon nanotube membrane as a high-performance flexible anode for lithium ion batteries , 2012 .

[82]  G. R. Rideal,et al.  Flexible inorganic films and coatings , 1983 .

[83]  I. Kinloch,et al.  Macroscopic fibers of well-aligned carbon nanotubes by wet spinning. , 2008, Small.

[84]  John A Rogers,et al.  Imprintable, Bendable, and Shape‐Conformable Polymer Electrolytes for Versatile‐Shaped Lithium‐Ion Batteries , 2013, Advanced materials.

[85]  Hui‐Ming Cheng,et al.  Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. , 2011, Nature materials.

[86]  L. Qu,et al.  MnO 2 -modified hierarchical graphene fiber electrochemical supercapacitor , 2014 .

[87]  Sindy K. Y. Tang,et al.  Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity , 2011, Nature.

[88]  Bowen Zhu,et al.  A Mechanically and Electrically Self‐Healing Supercapacitor , 2014, Advanced materials.

[89]  Po-Chiang Chen,et al.  Inkjet printing of single-walled carbon nanotube/RuO2 nanowire supercapacitors on cloth fabrics and flexible substrates , 2010 .

[90]  Lili Liu,et al.  Nanostructured Graphene Composite Papers for Highly Flexible and Foldable Supercapacitors , 2014, Advanced materials.

[91]  Sang-Young Lee,et al.  Progress in flexible energy storage and conversion systems, with a focus on cable-type lithium-ion batteries , 2013 .

[92]  C. V. Singh,et al.  A Foldable Lithium-Sulfur Battery. , 2015, ACS nano.

[93]  Zhenxing Zhang,et al.  Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes. , 2013, ACS nano.

[94]  Bo Pei,et al.  Highly porous graphene on carbon cloth as advanced electrodes for flexible all-solid-state supercapacitors , 2013 .

[95]  Li Li,et al.  Flexible, weavable and efficient microsupercapacitor wires based on polyaniline composite fibers incorporated with aligned carbon nanotubes , 2013 .

[96]  Jun Chen,et al.  Flexible, aligned carbon nanotube/conducting polymer electrodes for a lithium-ion battery , 2007 .

[97]  Kwang Man Kim,et al.  Low Resistance Flexible Current Collector for Lithium Secondary Battery , 2011 .

[98]  Guangyuan Zheng,et al.  Nanostructured sulfur cathodes. , 2013, Chemical Society reviews.

[99]  N. Lu,et al.  Mechanics for stretchable sensors , 2015 .

[100]  Xiaohong Liu,et al.  Flexible graphene/MnO2 composite papers for supercapacitor electrodes , 2011 .

[101]  Shoushan Fan,et al.  Superaligned Carbon Nanotube Arrays, Films, and Yarns: A Road to Applications , 2011, Advanced materials.

[102]  Zhiqian Wang,et al.  Fabrication of High‐Performance Flexible Alkaline Batteries by Implementing Multiwalled Carbon Nanotubes and Copolymer Separator , 2014, Advanced materials.

[103]  Changsheng Liu,et al.  Flexible pillared graphene-paper electrodes for high-performance electrochemical supercapacitors. , 2012, Small.

[104]  L. Qu,et al.  All‐Graphene Core‐Sheath Microfibers for All‐Solid‐State, Stretchable Fibriform Supercapacitors and Wearable Electronic Textiles , 2013, Advanced materials.

[105]  Ying Tian,et al.  Aerosol-synthesized SWCNT networks with tunable conductivity and transparency by a dry transfer technique. , 2010, Nano letters.

[106]  Qingwen Li,et al.  Graphene-patched CNT/MnO2 nanocomposite papers for the electrode of high-performance flexible asymmetric supercapacitors. , 2013, ACS applied materials & interfaces.

[107]  Sungmee Park,et al.  Smart Textiles: Wearable Electronic Systems , 2003 .

[108]  Benjamin C. K. Tee,et al.  Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes. , 2011, Nature nanotechnology.

[109]  Shaogang Wang,et al.  Rapid communicationA graphene foam electrode with high sulfur loading for flexible and high energy Li-S batteries , 2015 .

[110]  Yongsheng Hu,et al.  A repeated halving approach to fabricate ultrathin single-walled carbon nanotube films for transparent supercapacitors. , 2013, Small.

[111]  P. Ajayan,et al.  Flexible carbon nanotube--Cu2O hybrid electrodes for li-ion batteries. , 2011, Small.

[112]  Xinyu Xue,et al.  An integrated power pack of dye-sensitized solar cell and Li battery based on double-sided TiO2 nanotube arrays. , 2012, Nano letters.

[113]  Yu Huang,et al.  Functionalized Graphene Hydrogel‐Based High‐Performance Supercapacitors , 2013, Advanced materials.

[114]  Mary B Chan-Park,et al.  Advances in carbon-nanotube assembly. , 2007, Small.

[115]  Feng Li,et al.  Carbon materials for Li–S batteries: Functional evolution and performance improvement , 2016 .

[116]  C. R. Becer,et al.  Self-healing and self-mendable polymers , 2010 .

[117]  Pooi See Lee,et al.  Highly Stretchable Piezoresistive Graphene–Nanocellulose Nanopaper for Strain Sensors , 2014, Advanced materials.

[118]  G. Whitesides,et al.  Fabrication of microfluidic systems in poly(dimethylsiloxane) , 2000, Electrophoresis.

[119]  L. Qu,et al.  Dimension-tailored functional graphene structures for energy conversion and storage. , 2013, Nanoscale.

[120]  Husam N. Alshareef,et al.  Conducting polymer micro-supercapacitors for flexible energy storage and Ac line-filtering , 2015 .

[121]  Mohammad F. Islam,et al.  Ultracompressible, high-rate supercapacitors from graphene-coated carbon nanotube aerogels. , 2015, ACS applied materials & interfaces.

[122]  Yi Cui,et al.  Nanostructured paper for flexible energy and electronic devices , 2013 .

[123]  Huisheng Peng,et al.  Flexible and Weaveable Capacitor Wire Based on a Carbon Nanocomposite Fiber , 2013, Advanced materials.

[124]  Lele Peng,et al.  Two dimensional nanomaterials for flexible supercapacitors. , 2014, Chemical Society reviews.

[125]  K. R. Atkinson,et al.  Multifunctional Carbon Nanotube Yarns by Downsizing an Ancient Technology , 2004, Science.

[126]  Phaedon Avouris,et al.  Deformation of carbon nanotubes by surface van der Waals forces , 1998 .

[127]  Jinlong Yang,et al.  Metallic few-layered VS2 ultrathin nanosheets: high two-dimensional conductivity for in-plane supercapacitors. , 2011, Journal of the American Chemical Society.

[128]  R. Ruoff,et al.  Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage , 2015, Science.

[129]  Bin Liu,et al.  Spray-painted binder-free SnSe electrodes for high-performance energy-storage devices. , 2014, ChemSusChem.

[130]  Goangseup Zi,et al.  Biaxially stretchable, integrated array of high performance microsupercapacitors. , 2014, ACS nano.

[131]  Husam N. Alshareef,et al.  Symmetrical MnO2-carbon nanotube-textile nanostructures for wearable pseudocapacitors with high mass loading. , 2011, ACS nano.

[132]  Z. Suo,et al.  Mechanics of rollable and foldable film-on-foil electronics , 1999 .

[133]  Nan Zhang,et al.  Highly stretchable pseudocapacitors based on buckled reticulate hybrid electrodes , 2014, Nano Research.

[134]  Xuemei Sun,et al.  Electrochromic Fiber‐Shaped Supercapacitors , 2014, Advanced materials.

[135]  Guangmin Zhou,et al.  Graphene/metal oxide composite electrode materials for energy storage , 2012 .

[136]  Dong-Hwa Seo,et al.  Flexible energy storage devices based on graphene paper , 2011 .

[137]  Keon Jae Lee,et al.  Bendable inorganic thin-film battery for fully flexible electronic systems. , 2012, Nano letters.

[138]  John A Rogers,et al.  Controlled buckling of semiconductor nanoribbons for stretchable electronics , 2006, Nature nanotechnology.

[139]  Changsoon Choi,et al.  Flexible Supercapacitor Made of Carbon Nanotube Yarn with Internal Pores , 2014, Advanced materials.

[140]  W Gregory Sawyer,et al.  Super-Compressible Foamlike Carbon Nanotube Films , 2005, Science.

[141]  Huaihe Song,et al.  Enhanced Lithium Ion Storage Property of Sn Nanoparticles: The Confinement Effect of Few-Walled Carbon Nanotubes , 2012 .

[142]  Chaohe Xu,et al.  Synthesis of Multiwalled Carbon Nanotubes That Are Both Filled and Coated by SnO2 Nanoparticles and Their High Performance in Lithium-Ion Batteries , 2009 .

[143]  Haitao Huang,et al.  Stretchable all-solid-state supercapacitor with wavy shaped polyaniline/graphene electrode , 2014 .

[144]  J. Yin,et al.  Fabric-based flexible electrode with multi-walled carbon nanotubes@Ni network structure as a novel anode for hydrogen peroxide electrooxidation , 2014 .

[145]  Bin Sun,et al.  Scalable non-liquid-crystal spinning of locally aligned graphene fibers for high-performance wearable supercapacitors , 2015 .

[146]  Huisheng Peng,et al.  Integrated Polymer Solar Cell and Electrochemical Supercapacitor in a Flexible and Stable Fiber Format , 2014, Advanced materials.

[147]  Ann Marie Sastry,et al.  Mechanical properties of nanotube sheets: Alterations in joint morphology and achievable moduli in manufacturable materials , 2004 .

[148]  Hyo-Jeong Ha,et al.  UV-curable semi-interpenetrating polymer network-integrated, highly bendable plastic crystal composite electrolytes for shape-conformable all-solid-state lithium ion batteries , 2012 .

[149]  J. L. Jackson The tensile fracture strain of graphite determined during neutron irradiation , 1965 .

[150]  G. Lu,et al.  Fabrication of Graphene/Polyaniline Composite Paper via In Situ Anodic Electropolymerization for High-Performance Flexible Electrode. , 2009, ACS nano.

[151]  Chao Gao,et al.  Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics , 2014, Nature Communications.

[152]  S. Stankovich,et al.  Preparation and characterization of graphene oxide paper , 2007, Nature.

[153]  Huisheng Peng,et al.  Twisted Aligned Carbon Nanotube/Silicon Composite Fiber Anode for Flexible Wire‐Shaped Lithium‐Ion Battery , 2014, Advanced materials.

[154]  N. Lu,et al.  Stretchability and compliance of freestanding serpentine-shaped ribbons , 2014 .

[155]  Pengwan Chen,et al.  Edge-to-edge assembled graphene oxide aerogels with outstanding mechanical performance and superhigh chemical activity. , 2013, Small.

[156]  J. Rogers,et al.  Finite deformation mechanics in buckled thin films on compliant supports , 2007, Proceedings of the National Academy of Sciences.

[157]  Yi Cui,et al.  Highly conductive paper for energy-storage devices , 2009, Proceedings of the National Academy of Sciences.

[158]  Zhiqian Wang,et al.  Flexible zinc–carbon batteries with multiwalled carbon nanotube/conductive polymer cathode matrix , 2013 .

[159]  John A. Rogers,et al.  Bendable single crystal silicon thin film transistors formed by printing on plastic substrates , 2005 .

[160]  Huisheng Peng,et al.  Super-stretchy lithium-ion battery based on carbon nanotube fiber , 2014 .

[161]  Yi Cui,et al.  Light-weight free-standing carbon nanotube-silicon films for anodes of lithium ion batteries. , 2010, ACS nano.

[162]  Arumugam Manthiram,et al.  Rechargeable lithium-sulfur batteries. , 2014, Chemical reviews.

[163]  Jizhou Song,et al.  Mechanics of stretchable electronics , 2015 .

[164]  Jonathan A. Fan,et al.  Experimental and Theoretical Studies of Serpentine Microstructures Bonded To Prestrained Elastomers for Stretchable Electronics , 2014 .

[165]  Hyo-Jeong Ha,et al.  A facile approach to fabricate self-standing gel-polymer electrolytes for flexible lithium-ion batteries by exploitation of UV-cured trivalent/monovalent acrylate polymer matrices , 2011 .

[166]  Gunchul Shin,et al.  Fabrication of a stretchable solid-state micro-supercapacitor array. , 2013, ACS nano.

[167]  John A. Rogers,et al.  Mechanics of noncoplanar mesh design for stretchable electronic circuits , 2009 .

[168]  Fei Zhao,et al.  Super‐Aligned Carbon Nanotube Films as Current Collectors for Lightweight and Flexible Lithium Ion Batteries , 2013 .

[169]  Jonathan A. Fan,et al.  Stretchable batteries with self-similar serpentine interconnects and integrated wireless recharging systems , 2013, Nature Communications.

[170]  Hao Sun,et al.  Novel Graphene/Carbon Nanotube Composite Fibers for Efficient Wire‐Shaped Miniature Energy Devices , 2014, Advanced materials.

[171]  Yu-Lun Chueh,et al.  Fiber-based all-solid-state flexible supercapacitors for self-powered systems. , 2012, ACS nano.

[172]  R. Sarpeshkar,et al.  Large-scale complementary integrated circuits based on organic transistors , 2000, Nature.

[173]  Sabu Thomas,et al.  Electrochemical and mechanical properties of nanochitin-incorporated PVDF-HFP-based polymer electrolytes for lithium batteries , 2011 .

[174]  Jun Chen,et al.  A Leavening Strategy to Prepare Reduced Graphene Oxide Foams , 2012, Advanced materials.

[175]  Lianxi Zheng,et al.  Strong carbon-nanotube fibers spun from long carbon-nanotube arrays. , 2007, Small.

[176]  Feijun Wang,et al.  Cellulose nanofiber–graphene all solid-state flexible supercapacitors , 2013 .

[177]  Yanhuai Ding,et al.  Three-dimensional graphene/LiFePO4 nanostructures as cathode materials for flexible lithium-ion batteries , 2013 .

[178]  Yi Xie,et al.  Ultrathin two-dimensional MnO2/graphene hybrid nanostructures for high-performance, flexible planar supercapacitors. , 2013, Nano letters.

[179]  Yi Xie,et al.  Design of vanadium oxide structures with controllable electrical properties for energy applications. , 2013, Chemical Society reviews.

[180]  Yonggang Huang,et al.  Ultrathin conformal devices for precise and continuous thermal characterization of human skin. , 2013, Nature materials.

[181]  B. Wei,et al.  Materials and Structures for Stretchable Energy Storage and Conversion Devices , 2014, Advanced materials.

[182]  Xiaodong Li,et al.  Towards Textile Energy Storage from Cotton T‐Shirts , 2012, Advanced materials.

[183]  Klaus Müllen,et al.  Graphene-based in-plane micro-supercapacitors with high power and energy densities , 2013, Nature Communications.

[184]  Thomas M. Higgins,et al.  Silver Nanowire Networks as Flexible, Transparent, Conducting Films: Extremely High DC to Optical Conductivity Ratios. , 2009, ACS nano.

[185]  Zhuang Xie,et al.  Three‐Dimensional Compressible and Stretchable Conductive Composites , 2014, Advanced materials.

[186]  Chao Gao,et al.  Ultrastrong Fibers Assembled from Giant Graphene Oxide Sheets , 2013, Advanced materials.

[187]  Yi Cui,et al.  Enhancing the supercapacitor performance of graphene/MnO2 nanostructured electrodes by conductive wrapping. , 2011, Nano letters.

[188]  Gordon G Wallace,et al.  Intrinsically stretchable supercapacitors composed of polypyrrole electrodes and highly stretchable gel electrolyte. , 2013, ACS applied materials & interfaces.

[189]  Chao Gao,et al.  Multifunctional, Ultra‐Flyweight, Synergistically Assembled Carbon Aerogels , 2013, Advanced materials.

[190]  Fei Liu,et al.  Folded Structured Graphene Paper for High Performance Electrode Materials , 2012, Advanced materials.

[191]  Chang Liu,et al.  Preparation and electrochemical property of Fe2O3 nanoparticles-filled carbon nanotubes. , 2010, Chemical communications.

[192]  Huisheng Peng,et al.  Novel Electric Double‐Layer Capacitor with a Coaxial Fiber Structure , 2013, Advanced materials.

[193]  Feng Li,et al.  A smart self-regenerative lithium ion supercapacitor with a real-time safety monitor , 2015 .

[194]  Cunjiang Yu,et al.  Stretchable Supercapacitors Based on Buckled Single‐Walled Carbon‐Nanotube Macrofilms , 2009, Advanced materials.

[195]  Xin Cai,et al.  Fiber Supercapacitors Utilizing Pen Ink for Flexible/Wearable Energy Storage , 2012, Advanced materials.

[196]  B. Liu,et al.  Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources , 2011 .

[197]  L. Wen,et al.  Graphene for flexible lithium-ion batteries: Applications and prospects , 2015 .

[198]  Feng Li,et al.  A Flexible Sulfur‐Graphene‐Polypropylene Separator Integrated Electrode for Advanced Li–S Batteries , 2015, Advanced materials.

[199]  D. Wei,et al.  Transparent, flexible and solid-state supercapacitors based on room temperature ionic liquid gel , 2009 .

[200]  Huisheng Peng,et al.  Weaving Efficient Polymer Solar Cell Wires into Flexible Power Textiles , 2014 .

[201]  Feng Li,et al.  TiO2/graphene sandwich paper as an anisotropic electrode for high rate lithium ion batteries. , 2013, Nanoscale.

[202]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[203]  G. Shi,et al.  A high-performance flexible fibre-shaped electrochemical capacitor based on electrochemically reduced graphene oxide. , 2013, Chemical communications.

[204]  Chen Feng,et al.  Cross‐Stacked Carbon Nanotube Sheets Uniformly Loaded with SnO2 Nanoparticles: A Novel Binder‐Free and High‐Capacity Anode Material for Lithium‐Ion Batteries , 2009 .

[205]  Bo Gao,et al.  A flexible graphene/multiwalled carbon nanotube film as a high performance electrode material for supercapacitors , 2011 .

[206]  John A Rogers,et al.  Stretchable, Curvilinear Electronics Based on Inorganic Materials , 2010, Advanced materials.

[207]  P. Ajayan,et al.  Direct laser writing of micro-supercapacitors on hydrated graphite oxide films. , 2011, Nature nanotechnology.

[208]  Chao Gao,et al.  Highly Electrically Conductive Ag‐Doped Graphene Fibers as Stretchable Conductors , 2013, Advanced materials.

[209]  K. R. Atkinson,et al.  Strong, Transparent, Multifunctional, Carbon Nanotube Sheets , 2005, Science.

[210]  Francisco del Monte,et al.  Three dimensional macroporous architectures and aerogels built of carbon nanotubes and/or graphene: synthesis and applications. , 2013, Chemical Society reviews.

[211]  Songtao Lu,et al.  Synergistic effects from graphene and carbon nanotubes enable flexible and robust electrodes for high-performance supercapacitors. , 2012, Nano letters.

[212]  Q. Xue,et al.  Flexible and conductive nanocomposite electrode based on graphene sheets and cotton cloth for supercapacitor , 2012 .

[213]  Yonggang Huang,et al.  Materials and noncoplanar mesh designs for integrated circuits with linear elastic responses to extreme mechanical deformations , 2008, Proceedings of the National Academy of Sciences.

[214]  Xin Li,et al.  Dynamic and galvanic stability of stretchable supercapacitors. , 2012, Nano letters.

[215]  Kun-Hong Lee,et al.  Flexible micro-supercapacitors , 2006 .

[216]  Stephen R. Forrest,et al.  The path to ubiquitous and low-cost organic electronic appliances on plastic , 2004, Nature.

[217]  J. Goodenough Energy storage materials: A perspective , 2015 .

[218]  Ping Wang,et al.  Wet-spinning assembly of continuous, neat, and macroscopic graphene fibers , 2012, Scientific Reports.

[219]  Sanjaya D. Perera,et al.  Vanadium oxide nanowire – Graphene binder free nanocomposite paper electrodes for supercapacitors: A facile green approach , 2013 .

[220]  Genevieve Dion,et al.  Carbon coated textiles for flexible energy storage , 2011 .

[221]  J. Choi,et al.  3D macroporous graphene frameworks for supercapacitors with high energy and power densities. , 2012, ACS nano.

[222]  Feng Li,et al.  Graphene–Cellulose Paper Flexible Supercapacitors , 2011 .

[223]  Yi Cui,et al.  Lithium‐Ion Textile Batteries with Large Areal Mass Loading , 2011 .

[224]  F. Fardoun,et al.  Improved analytical model to predict the effective elastic properties of 2.5D interlock woven fabrics composite , 2012 .

[225]  Gang Wang,et al.  Ultrasound-assisted preparation of electrospun carbon nanofiber/graphene composite electrode for supercapacitors , 2013 .

[226]  W. Ma,et al.  Macroscopic carbon nanotube assemblies: preparation, properties, and potential applications. , 2011, Small.

[227]  Klaus Müllen,et al.  Towards free-standing graphene/carbon nanotube composite films via acetylene-assisted thermolysis of organocobalt functionalized graphene sheets. , 2010, Chemical communications.

[228]  Zhiqiang Niu,et al.  All‐Solid‐State Flexible Ultrathin Micro‐Supercapacitors Based on Graphene , 2013, Advanced materials.

[229]  Dong Jin Lee,et al.  Silicon Nanofibrils on a Flexible Current Collector for Bendable Lithium‐Ion Battery Anodes , 2013 .

[230]  Yonggang Huang,et al.  Biaxially stretchable "wavy" silicon nanomembranes. , 2007, Nano letters.

[231]  Lei Wen,et al.  A Self‐Standing and Flexible Electrode of Li4Ti5O12 Nanosheets with a N‐Doped Carbon Coating for High Rate Lithium Ion Batteries , 2013 .

[232]  Qiang Zhang,et al.  Macroporous 'bubble' graphene film via template-directed ordered-assembly for high rate supercapacitors. , 2012, Chemical communications.

[233]  Minbaek Lee,et al.  Single‐Fiber‐Based Hybridization of Energy Converters and Storage Units Using Graphene as Electrodes , 2011, Advanced materials.

[234]  K. Varahramyan,et al.  Paper-Based Lithium-Ion Batteries Using Carbon Nanotube-Coated Wood Microfibers , 2013, IEEE Transactions on Nanotechnology.

[235]  Tammy Y. Olson,et al.  Synthesis of graphene aerogel with high electrical conductivity. , 2010, Journal of the American Chemical Society.

[236]  Wenzhao Jia,et al.  All‐Printed Stretchable Electrochemical Devices , 2015, Advanced materials.

[237]  Shoushan Fan,et al.  Binder‐Free LiCoO2/Carbon Nanotube Cathodes for High‐Performance Lithium Ion Batteries , 2012, Advanced materials.

[238]  Lili Zhang,et al.  Carbon-based materials as supercapacitor electrodes. , 2009, Chemical Society reviews.

[239]  Yonggang Huang,et al.  Materials and Mechanics for Stretchable Electronics , 2010, Science.

[240]  Guangmin Zhou,et al.  Progress in flexible lithium batteries and future prospects , 2014 .

[241]  Chen Chen,et al.  Twisting Carbon Nanotube Fibers for Both Wire‐Shaped Micro‐Supercapacitor and Micro‐Battery , 2013, Advanced materials.

[242]  John B Goodenough,et al.  The Li-ion rechargeable battery: a perspective. , 2013, Journal of the American Chemical Society.

[243]  Min Wei,et al.  Flexible hierarchical nanocomposites based on MnO2 nanowires/CoAl hydrotalcite/carbon fibers for high-performance supercapacitors , 2013 .

[244]  Yi Cui,et al.  Solution-processed graphene/MnO2 nanostructured textiles for high-performance electrochemical capacitors. , 2011, Nano letters.

[245]  Shing‐Jong Huang,et al.  Supplementary Information for , 2013 .

[246]  Bin Liu,et al.  Fiber-based flexible all-solid-state asymmetric supercapacitors for integrated photodetecting system. , 2014, Angewandte Chemie.

[247]  Daniel A. Steingart,et al.  Recent Progress on Printed Flexible Batteries: Mechanical Challenges, Printing Technologies, and Future Prospects , 2015 .

[248]  Z. Suo,et al.  Nonlinear analyses of wrinkles in a film bonded to a compliant substrate , 2005 .