Efficiency of Hybrid Nano Particles of Tio2/Sio2 in Removal of Lead from Paint Industry Effluents

Background and purpose: Lead is a toxic compound which causes variety of health problems in water environments. This study investigated the efficiency of Tio2/Sio2 hybrid nanoparticles in removal of lead from paint industry effluents. Materials and methods: This experimental study was done in samples of synthetic and real wastewater from Binalood paint factory within six months. The chemical quality of crude sample and its lead was determined and then the influence of PH, absorbent amount and time on the removal of lead was evaluated. Then, the optimal conditions for each of these parameters were determined. The same experiments were done for samples of real wastewater. In order to understand the process of adsorption, kinetics of absorption isotherms equilibrium was also studied. SPSS ver.16 was used to analyze the data. Results: The highest percentage of lead absorption was observed at pH=9, Retention time of 120 minutes, absorbent amount of 0.5g for synthetic solution with removal efficiency of 99.99% and for synthetic solution with the efficiency of 95.56%.The findings revealed that the removal of lead followed the freundlich isotherm (R=9822%) and the second order synthetic model (R=9994%). Conclusion: Hybrid nanoparticles had a remarkable effect on the removal of lead (99.99%), so it could be used as an efficient method in removal of lead from industrial effluents.

[1]  A. E. Greenberg,et al.  Standard Methods for the Examination of Water and Wastewater seventh edition , 2013 .

[2]  Jie Cai,et al.  Structure and properties of starch/PVA/nano-SiO2 hybrid films , 2011 .

[3]  Neama A. Reiad,et al.  A study of the removal characteristics of heavy metals from wastewater by low-cost adsorbents , 2011 .

[4]  M. Najafi,et al.  Synthesis and characterization of thiol-functionalized silica nano hollow sphere as a novel adsorbent for removal of poisonous heavy metal ions from water: Kinetics, isotherms and error analysis , 2011 .

[5]  D. O’Carroll,et al.  Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. , 2011, Journal of hazardous materials.

[6]  N. Jaafarzadeh,et al.  Efficiency of perlite as a low cost adsorbent applied to removal of Pb and Cd from paint industry effluent , 2011 .

[7]  Marta Otero,et al.  Silica coated magnetite particles for magnetic removal of Hg2+ from water. , 2010, Journal of colloid and interface science.

[8]  S. Shaheen Sorption and lability of cadmium and lead in different soils from Egypt and Greece , 2009 .

[9]  J. Nouri,et al.  Removal of heavy metals from paint industry’s wastewater using Leca as an available adsorbent , 2009 .

[10]  A. Ozcan,et al.  Adsorption of lead(II) ions onto 8-hydroxy quinoline-immobilized bentonite. , 2009, Journal of hazardous materials.

[11]  W. Ngah,et al.  Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. , 2008, Bioresource technology.

[12]  W. Ngah,et al.  Adsorption of copper on rubber (Hevea brasiliensis) leaf powder: Kinetic, equilibrium and thermodynamic studies , 2008 .

[13]  Y. Bulut,et al.  Removal of copper (II) from aqueous solution by adsorption onto low-cost adsorbents. , 2008, Journal of environmental management.

[14]  A. Almasi,et al.  Pb and Co removal from paint industries effluent using wood ash , 2008 .

[15]  L. O’Dell,et al.  STRUCTURAL CHARACTERIZATION OF SIO2 AND AL2O3 ZENER-PINNED NANOCRYSTALLINE TIO2 BY NMR, XRD AND ELECTRON MICROSCOPY , 2007 .

[16]  T. Moriguchi,et al.  Adsorbability and photocatalytic degradability of humic substances in water on Ti-modified silica. , 2006, Journal of colloid and interface science.

[17]  Yangyang Sun,et al.  Study on mono-dispersed nano-size silica by surface modification for underfill applications. , 2005, Journal of colloid and interface science.

[18]  C. Rajagopal,et al.  Removal of heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent. , 2005, Journal of hazardous materials.

[19]  Afshin Maleki,et al.  Potential of Rice Husk and Rice Husk Ash for Phenol Removal in Aqueous Systems , 2004 .

[20]  W. Qiu,et al.  Morphology and size control of inorganic particles in polyimide hybrids by using SiO2–TiO2 mixed oxide , 2003 .

[21]  K. Abou-El-Sherbini,et al.  Separation and preconcentration in a batch mode of Cd(II), Cr(III, VI), Cu(II), Mn(II, VII) and Pb(II) by solid-phase extraction by using of silica modified with N-propylsalicylaldimine. , 2002, Talanta.

[22]  Bingqing Wei,et al.  Lead adsorption on carbon nanotubes , 2002 .

[23]  D. Hinton,et al.  Diazinon and chlorpyrifos in urban waterways in Northern California, USA , 2000 .

[24]  Acol,et al.  Polarography and Other Voltammetric Methods , 1987 .

[25]  A. Bond Modern Polarographic Methods in Analytical Chemistry , 1980 .

[26]  Mohammad Malakootian,et al.  A STUDY OF KINETICS AND BIOSORPTION ISOTHERMS OF HEAVY METALS BY ALGAE ULOTHRIX ZONATA FROM INDUSTRIAL WASTEWATER , 2012 .

[27]  R. Venckatesh,et al.  SYNTHESIS OF NANO TIO2-SIO2 COMPOSITE USING SOL–GEL METHOD: EFFECT ON SIZE, SURFACE MORPHOLOGY AND THERMAL STABILITY , 2010 .

[28]  M. Rabani,et al.  DETERMINATION OF HEAVY METALS (NICKEL, LEAD AND MERCURY) IN PERSIAN GULF WATER AND SEDIMENT, ASALOOYEH ZONE , 2007 .

[29]  Awwa,et al.  Standard Methods for the examination of water and wastewater , 1999 .

[30]  S. Martin,et al.  Environmental Applications of Semiconductor Photocatalysis , 1995 .

[31]  J. Rivera-Utrilla,et al.  Adsorption of zinc, cadmium, and copper on activated carbons obtained from agricultural by-products , 1988 .

[32]  Raymond Reeves,et al.  Modern polarographic methods in analytical chemistry , 1980 .