Use of Renewable Raw Materials in the Chemical Industry – Beyond Sugar and Starch

Classical energy sources such as petroleum oil and natural gas make up the fundamental materials on which modern industrial chemical parks are based. According to the finite availability of these consuetudinary resources and due to the increasing demand for energy from developing countries and the related rise in prices of oil and natural gas, renewable resources must be considered as valuable alternatives. Discussions about climate change with regard to alternatives in energy production are preceded very fervidly but alternatives have to be examined from a matter-of-fact based economic and scientific point of view. Therefore, this review is focussed on alternative sources such as wood and other agricultural residues with respect to their potential as future energy resources as well as building blocks for chemical synthesis processes.

[1]  Matsumoto Shinji,et al.  Biomethanol Production and CO2 Emission Reduction from Forage Grasses, Trees, and Crop Residues , 2007 .

[2]  T. Ghose,et al.  Methanol biosynthesis by covalently immobilized cells of Methylosinus trichosporium: Batch and continuous studies , 1991, Biotechnology and bioengineering.

[3]  George A. Olah,et al.  Beyond Oil and Gas: The Methanol Economy , 2005 .

[4]  L. Harvey,et al.  Heterologous protein production using the Pichia pastoris expression system , 2005, Yeast.

[5]  J. Cregg,et al.  Applications of yeast in biotechnology: protein production and genetic analysis. , 1999, Current opinion in biotechnology.

[6]  A. Stams,et al.  Microbiology of synthesis gas fermentation for biofuel production. , 2007, Current opinion in biotechnology.

[7]  Ying-xin Zhang,et al.  Methanol production from CO2 by resting cells of the methanotrophic bacterium Methylosinus trichosporium IMV 3011 , 2007, Journal of basic microbiology.

[8]  Otto Pulz,et al.  The utilization of renewable resources in German industrial production , 2006, Biotechnology journal.

[9]  Gatze Lettinga,et al.  Anaerobic-aerobic treatment of toxic pulping black liquor with upfront effluent recirculation , 1998 .

[10]  J. Benemann,et al.  Look Back at the U.S. Department of Energy's Aquatic Species Program: Biodiesel from Algae; Close-Out Report , 1998 .

[11]  T. H. Hsiung,et al.  Deactivation of methanol synthesis catalysts , 1993 .

[12]  P. Spolaore,et al.  Commercial applications of microalgae. , 2006, Journal of bioscience and bioengineering.

[13]  Andrzej Cybulski,et al.  Liquid-Phase Methanol Synthesis: Catalysts, Mechanism, Kinetics, Chemical Equilibria, Vapor-Liquid Equilibria, and Modeling—A Review , 1994 .

[14]  Martyn V. Twigg,et al.  Deactivation of Copper Metal Catalysts for Methanol Decomposition, Methanol Steam Reforming and Methanol Synthesis , 2003 .

[15]  Robbert Kleerebezem,et al.  Treating industrial wastewater: anaerobic digestion comes of age: anaerobic treatment systems offer important advantages over conventionally applied aerobic processes for removing organic pollutants from water-based streams. (Cover Story) , 2003 .

[16]  G Lettinga,et al.  Stability and activity of anaerobic sludge from UASB reactors treating sewage in subtropical regions. , 2006, Water science and technology : a journal of the International Association on Water Pollution Research.

[17]  Peter Weiland,et al.  Biomethane for future mobility. , 2007 .

[18]  B. Dave,et al.  Enzymatic Conversion of Carbon Dioxide to Methanol: Enhanced Methanol Production in Silica Sol−Gel Matrices , 1999 .

[19]  Li-Min Zhu,et al.  Production of methanol from methane by methanotrophic bacteria , 2004 .

[20]  Y. Chisti.  Biodiesel from microalgae. , 2007, Biotechnology advances.

[21]  Li-Min Zhu,et al.  Particulate methane monooxygenase from Methylosinus trichosporium is a copper-containing enzyme. , 2002, Biochemical and biophysical research communications.

[22]  J. Liao,et al.  Non-fermentative pathways for synthesis of branched-chain higher alcohols as biofuels , 2008, Nature.

[23]  J. Cregg,et al.  Recombinant protein expression in Pichia pastoris , 2000, Molecular biotechnology.

[24]  Friedrich Asinger.  Methanol — Chemie und Energierohstoff , 1986 .

[25]  Francisco Valero,et al.  Operational strategies, monitoring and control of heterologous protein production in the methylotrophic yeast Pichia pastoris under different promoters: A review , 2006, Microbial cell factories.

[26]  D. Ballerini,et al.  Production of vitamin B12 by gram-variable methanol-utilizing bacteria , 2005, Biotechnology Letters.

[27]  J. Cregg,et al.  Heterologous protein expression in the methylotrophic yeast Pichia pastoris. , 2000, FEMS microbiology reviews.

[28]  Ayhan Demirbas,et al.  Progress and recent trends in biofuels , 2007 .

[29]  William C. Raschke,et al.  Recent Advances in the Expression of Foreign Genes in Pichia pastoris , 1993, Bio/Technology.

[30]  F. Wagner,et al.  Methanol: A fermentation substrate , 1977, Experientia.

[31]  Ichiro Okura,et al.  Semicontinuous methanol biosynthesis by Methylosinus trichosporium OB3b , 1999 .

[32]  M. Lidstrom,et al.  Methylotrophs: genetics and commercial applications. , 1990, Annual review of microbiology.

[33]  C. J. Campbell,et al.  The Rimini Protocol an oil depletion protocol: Heading off economic chaos and political conflict during the second half of the age of oil , 2006 .

[34]  Rolf Froböse.  Green Chemistry-Schlagwort oder Synonym für Innovation? , 2004 .

[35]  F B Metting,et al.  Biodiversity and application of microalgae , 1996, Journal of Industrial Microbiology.