Chaotic Advection and Enhanced Groundwater Remediation

The field of groundwater remediation needs cost effective and time efficient technologies. Recent developments in the field of chaotic advection in low Reynolds number flows have led to the belief that a system of wells that oscillate between injection and extraction with time-dependent, randomly constrained flow rates could cause substantial mixing in an aquifer. This could have significant effects when combined with the advection and dispersion and biodegradation aspects of natural attenuation, especially in the context of mixing rate-limiting electron acceptors with contaminants that are serving as substrate for microbes. Chaotic advection enhanced remediation could possibly turn decades into years, while reducing both exposure risk and clean up costs. In this research work, we use flow and transport modeling to study the mixing phenomena created in groundwater by oscillating wells. To quantify mixing, an index is developed using the concept of average interparticle distances and implemented along with the dilution index, presented in the literature before.

[1]  J. Xin,et al.  Stochastic analysis of biodegradation fronts in one-dimensional heterogeneous porous media , 1998 .

[2]  L. Gelhar,et al.  Bimolecular second‐order reactions in spatially varying flows: Segregation induced scale‐dependent transformation rates , 1997 .

[3]  C. S. Simmons,et al.  Stochastic-Convective Transport with Nonlinear Reaction: Biodegradation With Microbial Growth , 1995 .

[4]  Julio M. Ottino,et al.  A case study of chaotic mixing in deterministic flows: The partitioned-pipe mixer , 1987 .

[5]  Olaf A Cirpka,et al.  Measurement of mixing-controlled reactive transport in homogeneous porous media and its prediction from conservative tracer test data. , 2004, Environmental science & technology.

[6]  Jan Frøyland,et al.  Introduction to Chaos and Coherence , 1992 .

[7]  Scott W. Jones,et al.  Enhanced separation of diffusing particles by chaotic advection , 1989 .

[8]  P. Dutta,et al.  Inertial effects in chaotic mixing with diffusion , 1995, Journal of Fluid Mechanics.

[9]  Hassan Aref,et al.  Chaotic advection in pulsed source–sink systems , 1988 .

[10]  R. Colwell,et al.  Microbial degradation of hydrocarbons in the environment. , 1990, Microbiological reviews.

[11]  Vivek Kapoor,et al.  Stochastic analysis of oxygen‐limited biodegradation in three‐dimensionally heterogeneous aquifers , 1997 .

[12]  Julio M. Ottino,et al.  A comparative computational and experimental study of chaotic mixing of viscous fluids , 1990, Journal of Fluid Mechanics.

[13]  J. M. Zalc,et al.  Parallel-competitive reactions in a two-dimensional chaotic flow , 1999 .

[14]  Peter K. Kitanidis,et al.  Concentration fluctuations and dilution in two-dimensionally periodic heterogeneous porous media , 1996 .

[15]  Peter K. Kitanidis,et al.  The concept of the Dilution Index , 1994 .

[16]  A. Roshko Structure of Turbulent Shear Flows: A New Look , 1976 .

[17]  P. Kitanidis,et al.  Impact of Biomass‐Decay Terms on the Simulation of Pulsed Bioremediation , 2000 .

[18]  S. P. Beerens,et al.  An Analytical Study of Chaotic Stirring in Tidal Areas , 1994 .

[19]  Rainer Helmig,et al.  Numerical simulation of biodegradation controlled by transverse mixing , 1999 .

[20]  Peter K. Kitanidis,et al.  Concentration fluctuations and dilution in aquifers , 1998 .

[21]  A. Valocchi,et al.  Transport and biodegradation of solutes in stratified aquifers under enhanced in situ bioremediation conditions , 1998 .

[22]  Garrison Sposito,et al.  Topological groundwater hydrodynamics , 2001 .

[23]  Hassan Aref,et al.  Chaotic advection in a Stokes flow , 1986 .

[24]  Olaf A. Cirpka,et al.  Large‐scale sandbox experiment on longitudinal effective dispersion in heterogeneous porous media , 2004 .

[25]  S.E.A.T.M. van der Zee,et al.  Transport of reactive solute in spatially variable soil systems , 1987 .

[26]  C. Kranenburg Wind-driven chaotic advection in a shallow model lake , 1992 .

[27]  P. Kitanidis,et al.  Characterization of mixing and dilution in heterogeneous aquifers by means of local temporal moments , 2000 .

[28]  H. Aref Stirring by chaotic advection , 1984, Journal of Fluid Mechanics.

[29]  Garrison Sposito,et al.  Mixing and stretching efficiency in steady and unsteady groundwater flows , 1998 .

[30]  George M. Zaslavsky,et al.  Chaotic Dynamics and the Origin of Statistical Laws , 1999 .

[31]  P. Bedient,et al.  Transport of dissolved hydrocarbons influenced by oxygen‐limited biodegradation: 1. Theoretical development , 1986 .