Label-free detection of sulfide ions based on fluorescence quenching of unmodified core–shell Au@Ag nanoclusters

Based on the principle of fluorescence quenching, by the interaction between S2− ions and the Ag atoms/ions on the surface of the core–shell Au@Ag NCs, we propose a simple label-free method for the detection of S2− ions with high selectivity and sensitivity by using fluorescent core–shell Au@Ag NCs in aqueous media.

[1]  Anil H. Gore,et al.  Direct detection of sulfide ions [S2-] in aqueous media based on fluorescence quenching of functionalized CdS QDs at trace levels: analytical applications to environmental analysis. , 2013, The Analyst.

[2]  Lingwen Zeng,et al.  A simple and sensitive sensor for rapid detection of sulfide anions using DNA-templated copper nanoparticles as fluorescent probes. , 2012, The Analyst.

[3]  C. Yang,et al.  Sonochemical synthesis of highly fluorescent glutathione-stabilized Ag nanoclusters and S2- sensing. , 2012, Nanoscale.

[4]  G. Nienhaus,et al.  Effect of protein adsorption on the fluorescence of ultrasmall gold nanoclusters. , 2012, Small.

[5]  Xiaowen Xu,et al.  Highly specific colorimetric recognition and sensing of sulfide with glutathione-modified gold nanoparticle probe based on an anion-for-molecule ligand exchange reaction. , 2012, The Analyst.

[6]  Daeha Seo,et al.  Full-color tuning of surface plasmon resonance by compositional variation of Au@Ag core-shell nanocubes with sulfides. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[7]  Changqing Zhu,et al.  Gold nanocluster-based fluorescent probes for near-infrared and turn-on sensing of glutathione in living cells. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[8]  Wei-Yu Chen,et al.  Use of fluorescent DNA-templated gold/silver nanoclusters for the detection of sulfide ions. , 2011, Analytical chemistry.

[9]  Xiu‐Ping Yan,et al.  Silica-coated S(2-)-enriched manganese-doped ZnS quantum dots as a photoluminescence probe for imaging intracellular Zn2+ ions. , 2011, Analytical chemistry.

[10]  A. Banerjee,et al.  Fluorescent Au@Ag core-shell nanoparticles with controlled shell thickness and Hg(II) sensing. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[11]  G. Nienhaus,et al.  Ultra-small fluorescent metal nanoclusters: Synthesis and biological applications , 2011 .

[12]  Robin H. A. Ras,et al.  Fluorescent silver nanoclusters. , 2011, Nanoscale.

[13]  Hong-Yan. Yuan,et al.  Sulfide sensor based on the room-temperature phosphorescence of ZnO/SiO2 nanocomposite. , 2010, The Analyst.

[14]  R. Dickson,et al.  DNA Encapsulation of Ten Silver Atoms Produces a Bright, Modulatable, Near Infrared-Emitting Cluster. , 2010, The journal of physical chemistry letters.

[15]  K. Suslick,et al.  Water‐Soluble Fluorescent Silver Nanoclusters , 2010, Advanced materials.

[16]  Hong-Yan. Yuan,et al.  Sulfide sensor based on room-temperature phosphorescence of PbO/SiO2 nanocomposite. , 2010, Analytical chemistry.

[17]  Jianping Xie,et al.  Highly selective and ultrasensitive detection of Hg(2+) based on fluorescence quenching of Au nanoclusters by Hg(2+)-Au(+) interactions. , 2010, Chemical communications.

[18]  Myung Gil Choi,et al.  Sulfide-selective chemosignaling by a Cu2+ complex of dipicolylamine appended fluorescein. , 2009, Chemical communications.

[19]  Jianping Xie,et al.  Protein-directed synthesis of highly fluorescent gold nanoclusters. , 2009, Journal of the American Chemical Society.

[20]  Minglei Zhao,et al.  A fluorescein-based fluorogenic and chromogenic chemodosimeter for the sensitive detection of sulfide anion in aqueous solution. , 2009, Analytica chimica acta.

[21]  R. Dickson,et al.  Shuttle-based fluorogenic silver-cluster biolabels. , 2009, Angewandte Chemie.

[22]  Tom Vosch,et al.  Oligonucleotide-stabilized Ag nanocluster fluorophores. , 2008, Journal of the American Chemical Society.

[23]  Tom Vosch,et al.  Strongly emissive individual DNA-encapsulated Ag nanoclusters as single-molecule fluorophores , 2007, Proceedings of the National Academy of Sciences.

[24]  Robert M Dickson,et al.  Highly fluorescent noble-metal quantum dots. , 2007, Annual review of physical chemistry.

[25]  Pekka Pyykkö,et al.  Theoretical chemistry of gold. , 2004, Angewandte Chemie.

[26]  D. Goia Preparation and formation mechanisms of uniform metallic particles in homogeneous solutions , 2004 .

[27]  N. Lawrence,et al.  Amperometric determination of sulfide at a pre-oxidised nickel electrode in acidic media. , 2003, The Analyst.

[28]  S. Marzouk,et al.  Methylene blue potentiometric sensor for selective determination of sulfide ions , 2002 .

[29]  N. Lawrence,et al.  Analytical strategies for the detection of sulfide: a review. , 2000, Talanta.

[30]  Karayannis,et al.  Electrochemical study of chemically modified and screen-printed graphite electrodes with , 2000, Analytical chemistry.

[31]  P. Santschi,et al.  Sensitive determination of dissolved sulfide in estuarine water by solid-phase extraction and high-performance liquid chromatography of methylene blue. , 2000, Journal of chromatography. A.

[32]  Z. Pawlak,et al.  Modification of iodometric determination of total and reactive sulfide in environmental samples. , 1999, Talanta.

[33]  Pierre R. Bérubé,et al.  Measurement of reduced sulphur compounds contained in aqueous matrices by direct injection into a gas chromatograph with a flame photometric detector , 1999 .

[34]  Martin M. F. Choi Fluorimetric optode membrane for sulfide detection , 1998 .