Recent advancements in natural dye applications: a review

A vast array of colorants obtained from natural sources such as plants, insects/animals and microbes have been scrutinized in recent past for their use in different kinds of applications. Research into new natural dyes sources along with eco-friendly, robust and cost-effective technologies for their processing and application have greatly aided in widening the scope of natural dyes in various traditional and advanced application disciplines. This review encompasses a summary of research performed in last 15 years (1998–2013) in different arenas of applications of natural dyes, with specific reference to technological development in natural textile dyeing and use of natural dyes in functional finishing of textiles, food coloration and dye-sensitized solar cells. In addition, some newly discovered applications of natural dyes have also been discussed.

[1]  Seigo Ito,et al.  Fabrication of dye-sensitized solar cells using natural dye for food pigment: Monascus yellow , 2010 .

[2]  Thomas Bechtold,et al.  Natural dyeing of wool and hair with indigo carmine (C.I. Natural Blue 2), a renewable resource based blue dye , 2009 .

[3]  Elena Vigil,et al.  Nanocrystalline TiO2 photosensitized with natural polymers with enhanced efficiency from 400 to 600 nm , 2005 .

[4]  Weibao Kong,et al.  Optimization of ultrasound-assisted extraction parameters of chlorophyll from Chlorella vulgaris residue after lipid separation using response surface methodology , 2014, Journal of Food Science and Technology.

[5]  Hea-In Kim,et al.  Effects of introduced chemical groups on the dyeability of cotton fabrics with Phellodendron amurense Rupr. , 2007 .

[6]  Evangelia A. Varella,et al.  Revival of traditional European dyeing techniques yellow and red colorants , 2009 .

[7]  Daniel Dupont,et al.  Dyeing plants screening: an approach to combine past heritage and present development , 2006 .

[8]  Mohammad Khaja Nazeeruddin,et al.  Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells , 2012 .

[9]  Henriette M.C. Azeredo,et al.  Study on efficiency of betacyanin extraction from red beetroots , 2009 .

[10]  Nizar Meksi,et al.  Olive mill wastewater: A potential source of natural dyes for textile dyeing , 2012 .

[11]  Rattanaphol Mongkholrattanasit,et al.  Dyeing and fastness properties of natural dyes extracted from eucalyptus leaves using padding techniques , 2010 .

[12]  S. Karthick,et al.  Performance of Kerria japonica and Rosa chinensis flower dyes as sensitizers for dye-sensitized solar cells. , 2012, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[13]  Ho Chang,et al.  Dye-sensitized solar cell using natural dyes extracted from spinach and ipomoea , 2010 .

[14]  J. D. Adam Burrows,et al.  Palette of Our Palates: A Brief History of Food Coloring and Its Regulation , 2009 .

[15]  S. Bhattacharya,et al.  Colouration of wool and silk with Rheum emodi , 2008 .

[16]  Shruti A. Agarkar,et al.  Isobutrin from butea monosperma (flame of the forest): a promising new natural sensitizer belonging to chalcone class. , 2011, ACS applied materials & interfaces.

[17]  Yunus Doθan,et al.  Plants used as natural dye sources in Turkey , 2003, Economic Botany.

[18]  Nikhat Manzoor,et al.  Antimicrobial activity of wool yarn dyed with Rheum emodi L. (Indian Rhubarb) , 2012 .

[19]  Anthony B. Cunningham,et al.  Di Ambang Kepunahan: proses mordan dengan menggunakan logam dari tumbuhan dalam pembuatan kain tradisional di Indonesia , 2011 .

[20]  David Frick,et al.  The coloration of food , 2008 .

[21]  Alison Downham,et al.  Colouring our foods in the last and next millennium , 2000 .

[22]  Venkatasubramanian Sivakumar,et al.  Ultrasound assisted enhancement in natural dye extraction from beetroot for industrial applications and natural dyeing of leather. , 2009, Ultrasonics sonochemistry.

[23]  Kamran Ahmed,et al.  Study the effect of metal ion on wool fabric dyeing with tea as natural dye , 2010 .

[24]  Ali Shams-Nateri,et al.  Reusing wastewater of madder natural dye for wool dyeing , 2011 .

[25]  Padma S. Vankar,et al.  Ecofriendly sonicator dyeing of cotton with Rubia cordifolia Linn. using biomordant , 2008 .

[26]  Ertan Özen,et al.  Determination of the color stability of an environmentally friendly wood stain derived from laurel (Laurus nobilis L.) leaf extracts under UV exposure , 2008 .

[27]  G. Calogero,et al.  Red Sicilian orange and purple eggplant fruits as natural sensitizers for dye-sensitized solar cells , 2008 .

[28]  Madan Dubey,et al.  Lithium storage mechanisms in purpurin based organic lithium ion battery electrodes , 2012, Scientific Reports.

[29]  T. L. Dawson,et al.  Biosynthesis and synthesis of natural colours , 2009 .

[30]  Christian Graziani Garcia,et al.  Fruit extracts and ruthenium polypyridinic dyes for sensitization of TiO2 in photoelectrochemical solar cells , 2003 .

[31]  Xinxing Feng,et al.  New insights into solar UV-protective properties of natural dye , 2007 .

[32]  Susanne Geissler,et al.  Efficient processing of raw material defines the ecological position of natural dyes in textile production , 2008 .

[33]  Y. Shin,et al.  Development of natural dyed textiles with thermo-regulating properties , 2010 .

[34]  Tae Young Kim,et al.  Photochemical properties of dye-sensitized solar cell using mixed natural dyes extracted from Gardenia Jasminoide Ellis , 2013 .

[35]  Padma S. Vankar,et al.  Sonicator dyeing of modified cotton, wool and silk with Mahonia napaulensis DC. and identification of the colorant in Mahonia , 2008 .

[36]  Rajesh Kumar,et al.  Anthraquinone derivatives based natural dye from Rheum emodi as a probe for thermal stability of proteins: spectroscopic and chromatographic studies. , 2012, Journal of pharmaceutical and biomedical analysis.

[37]  Laurent Dufossé,et al.  Microorganisms and microalgae as sources of pigments for food use: a scientific oddity or an industrial reality? , 2005 .

[38]  Heba F. Mansour,et al.  Environmental aspects on dyeing silk fabric with sticta coronata lichen using ultrasonic energy and mild mordants , 2011 .

[39]  Laura Bacci,et al.  Laboratory and Outdoor Assessment of UV Protection Offered by Flax and Hemp Fabrics Dyed with Natural Dyes , 2009, Photochemistry and photobiology.

[40]  Faouzi Sakli,et al.  Isolation, identification and dyeing studies of betanin on modified acrylic fabrics , 2012 .

[41]  Nabil A. Ibrahim,et al.  A new approach for natural dyeing and functional finishing of cotton cellulose , 2010 .

[42]  Anna M. Bakowska-Barczak,et al.  Acylated anthocyanins as stable, natural food colorants - a review. , 2005 .

[43]  Elena Ibáñez,et al.  Natural dyes extraction from cochineal (Dactylopius coccus). New extraction methods , 2012 .

[44]  Ehab Tousson,et al.  Black mulberries (Morus nigra) as a natural dye for animal tissues staining , 2011 .

[45]  Faouzi Sakli,et al.  Dyeing properties and colour fastness of wool dyed with indicaxanthin natural dye , 2012 .

[46]  Gerko Oskam,et al.  Dye-sensitized solar cells with natural dyes extracted from achiote seeds , 2010 .

[47]  Mazahar Farooqui,et al.  Analytical Applications of Plant Extract as Natural pH Indicator: A Review , 2011 .

[48]  Laurent Dufossé,et al.  Microbial Production of Food Grade Pigments , 2006 .

[49]  Y. Son,et al.  Effect of reactive anionic agent on dyeing of cellulosic fibers with a Berberine colorant , 2004 .

[50]  John T. Sheridan,et al.  Characterising dye-sensitised solar cells , 2011 .

[51]  Byung-Taek Oh,et al.  Water‐soluble red pigments from Isaria farinosa and structural characterization of the main colored component , 2010, Journal of Basic Microbiology.

[52]  Weidong Yu,et al.  Color evaluation of wool fabric dyed with Rhizoma coptidis extract , 2006 .

[53]  Yiqi Yang,et al.  Antimicrobial activity of wool fabric treated with curcumin , 2005 .

[54]  Lu Wang,et al.  Research on Dyeing and Ultraviolet Protection of Silk Fabric Using Vegetable Dyes Extracted from Flos Sophorae , 2009 .

[55]  D. Cooke,et al.  Dyes from plants: Past usage, present understanding and potential , 2001, Plant Growth Regulation.

[56]  Susanne Geissler,et al.  Extraction of natural dyes for textile dyeing from coloured plant wastes released from the food and beverage industry , 2006 .

[57]  H. Oda,et al.  Improving light fastness of natural dye: photostabilisation of gardenia blue , 2012 .

[58]  Majid Montazer,et al.  Treatment of Wool with Laccase and Dyeing with Madder , 2009, Applied biochemistry and biotechnology.

[59]  L. Bacci,et al.  The role of natural dyes in the UV protection of fabrics made of vegetable fibres , 2011 .

[60]  C. Saikia,et al.  Isolation of colour components from native dye-bearing plants in northeastern India. , 2005, Bioresource technology.

[61]  Masashi Shibata,et al.  Photostability enhancement of anionic natural dye by intercalation into hydrotalcite. , 2009, Journal of colloid and interface science.

[62]  Jeanne L. McHale,et al.  Betalain pigments for dye-sensitized solar cells , 2007 .

[63]  Mohammad Mirjalili,et al.  Eco-friendly dyeing of wool using natural dye from weld as co-partner with synthetic dye , 2011 .

[64]  Faouzi Sakli,et al.  Sonicator dyeing of modified acrylic fabrics with indicaxanthin natural dye , 2013 .

[65]  Guang Hong Zheng,et al.  Application of rare earth as mordant for the dyeing of ramie fabrics with natural dyes , 2011 .

[66]  N. Ahmed,et al.  Ultrasonic dyeing of cationized cotton fabric with natural dye. Part 2: Cationization of cotton using Quat 188 , 2011 .

[67]  Padma S. Vankar,et al.  Chemical characterisation of extract derived from Daphne papyraceae and sonicator dyeing of cotton, silk and wool with the extract , 2009 .

[68]  Susanne Geissler,et al.  Natural dyes in modern textile dyehouses — how to combine experiences of two centuries to meet the demands of the future? , 2003 .

[69]  A. Sarkar,et al.  On the relationship between fabric processing and ultraviolet radiation transmission , 2007, Photodermatology, photoimmunology & photomedicine.

[70]  Shu-Mei Lin,et al.  Structural identification and bioactivities of red-violet pigments present in Basella alba fruits. , 2010, Journal of agricultural and food chemistry.

[71]  Thomas Bechtold,et al.  Natural Colorants in Textile Dyeing , 2009 .

[72]  John B. Bremner,et al.  Dyeing of cotton yarn with the aqueous extract of the leaves of Eupatorium odoratum L. in Thailand and associated extract toxicity studies , 2011 .

[73]  A. M. Humphrey,et al.  Chlorophyll as a Color and Functional Ingredient , 2006 .

[74]  Deepti Gupta,et al.  Antimicrobial activity of cotton fabric treated with Quercus infectoria extract , 2007 .

[75]  M. D. Teli,et al.  Eco-dyeing using Tamarindus indica L. seed coat tannin as a natural mordant for textiles with antibacterial activity , 2014 .

[76]  Majid Montazer,et al.  Effect of Ammonia on Madder-Dyed Natural Protein Fiber , 2004 .

[77]  Muhammad Safdar,et al.  Influence of gamma radiation on the colour strength and fastness properties of fabric using turmeric (Curcuma longa L.) as natural dye , 2010 .

[78]  Sara Kadolph,et al.  Natural Dyes: A Traditional Craft Experiencing New Attention , 2008 .

[79]  Aldo Di Carlo,et al.  Efficient Dye-Sensitized Solar Cells Using Red Turnip and Purple Wild Sicilian Prickly Pear Fruits , 2010, International journal of molecular sciences.

[80]  P. Griffiths,et al.  Enhancement of lac dye adsorption on cotton fibres by poly(ethyleneimine) , 2004 .

[81]  Jeanne L. McHale,et al.  Improved efficiency of betanin-based dye-sensitized solar cells , 2011 .

[82]  Anne Perwuelz,et al.  Dyeing of woven polyester fabric with curcumin: effect of dye concentrations and surface pre‐activation using air atmospheric plasma and ultraviolet excimer treatment , 2012 .

[83]  O. Paredes-López,et al.  Natural Pigments: Carotenoids, Anthocyanins, and Betalains — Characteristics, Biosynthesis, Processing, and Stability , 2000, Critical reviews in food science and nutrition.

[84]  P. K. D. D. P. Pitigala,et al.  Utilization of natural pigment extracted from pomegranate fruits as sensitizer in solid-state solar cells , 2006 .

[85]  Deepti Gupta,et al.  Antimicrobial properties of natural dyes against Gram‐negative bacteria , 2004 .

[86]  Tanveer Hussain,et al.  Optimization of alkaline extraction of natural dye from Henna leaves and its dyeing on cotton by exhaust method , 2009 .

[87]  H. Katırcıoğlu,et al.  Antimicrobial effect of natural dyes on some pathogenic bacteria , 2009 .

[88]  J. Fernández-López,et al.  Fermentation of Opuntia stricta (Haw.) fruits for betalains concentration. , 2008, Journal of agricultural and food chemistry.

[89]  M. D. Gholami,et al.  An Investigation of the Dyeability of Acrylic Fiber Via Microwave Irradiation , 2008 .

[90]  Hansgeorg Ernst,et al.  Quantitative assessment of antioxidant properties of natural colorants and phytochemicals: carotenoids, flavonoids, phenols and indigoids. The role of β‐carotene in antioxidant functions , 2001 .

[91]  Rıza Atav,et al.  Effects of Alkali Proteases on Dyeing Properties of Various Proteinous Materials with Natural Dyes , 2009 .

[92]  Heba F. Mansour,et al.  Environment and energy efficient dyeing of woollen fabric with sticta coronata , 2010 .

[93]  Vittaya Amornkitbamrung,et al.  Density functional theory study on the electronic structure of Monascus dyes as photosensitizer for dye-sensitized solar cells , 2012 .

[94]  Qing Wang,et al.  Highly Efficient Porphyrin Sensitizers for Dye-Sensitized Solar Cells , 2007 .

[95]  Y. Son,et al.  Effect of reactive anionic agent on dyeing of cellulosic fibers with a Berberine colorant—part 2: anionic agent treatment and antimicrobial activity of a Berberine dyeing , 2005 .

[96]  Nizar Meksi,et al.  Extraction, identification and dyeing studies of Isosalipurposide, a natural chalcone dye from Acacia cyanophylla flowers on wool , 2012 .

[97]  Cyrus Macfoy,et al.  Ethonobotany and sustainable utilization of natural dye plants in Sierra Leone , 2004, Economic Botany.

[98]  Shally Khanna,et al.  Natural dyes versus lysochrome dyes in cheiloscopy: A comparative evaluation , 2010, Journal of forensic dental sciences.

[99]  Thomas Bechtold,et al.  Anthocyanin dyes extracted from grape pomace for the purpose of textile dyeing. , 2007, The Journal of the Science of Food and Agriculture.

[100]  Yunfang Huang,et al.  Natural dyes as photosensitizers for dye-sensitized solar cell , 2006 .

[101]  Shahid Adeel,et al.  Influence of UV radiations on the extraction and dyeing of cotton fabric with Curcuma longa L , 2012 .

[102]  Eun-Kyung Hwang,et al.  Colorimetric Assay and Antibacterial Activity of Cotton, Silk, and Wool Fabrics Dyed with Peony, Pomegranate, Clove, Coptis chinenis and Gallnut Extracts , 2009, Materials.

[103]  Soundarapandian Sekar,et al.  Phycobiliproteins as a commodity: trends in applied research, patents and commercialization , 2008, Journal of Applied Phycology.

[104]  Deepti Gupta,et al.  Anti-UV and anti-microbial properties of some natural dyes on cotton , 2005 .

[105]  Ulf Thrane,et al.  Identification of potentially safe promising fungal cell factories for the production of polyketide natural food colorants using chemotaxonomic rationale , 2009, Microbial cell factories.

[106]  María José Amores,et al.  Environmental assessment of urban water cycle on Mediterranean conditions by LCA approach , 2013 .

[107]  Siddhartha Datta,et al.  Dyeing of jute fabric with tesu extract: Part 1 — Effects of different mordants and dyeing process variables , 2011 .

[108]  J. Rodríguez,et al.  Chemical studies of anthocyanins: A review , 2009 .

[109]  Mazeyar Parvinzadeh,et al.  Effect of proteolytic enzyme on dyeing of wool with madder , 2007 .

[110]  Ezgi Akar,et al.  Ecological dyeing with some plant pulps on woolen yarn and cationized cotton fabric , 2012 .

[111]  Milin Zhang,et al.  From salmon pink to blue natural sensitizers for solar cells: Canna indica L., Salvia splendens, cowberry and Solanum nigrum L. , 2009, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[112]  Nikhat Manzoor,et al.  Assessment of colorimetric, antibacterial and antifungal properties of woollen yarn dyed with the extract of the leaves of henna (Lawsonia inermis) , 2012 .

[113]  Zaisheng Cai,et al.  Study on the natural dyeing of wool modified with enzyme , 2011 .

[114]  Barbara Simončič,et al.  Structures of Novel Antimicrobial Agents for Textiles - A Review , 2010 .

[115]  Hyunmi Lee,et al.  UV absorber aftertreatment to improve lightfastness of natural dyes on protein fibres , 2001 .

[116]  R. El-Shishtawy,et al.  Ultrasonic assisted dyeing. III. Dyeing of wool with lac as a natural dye , 2005 .

[117]  A. Sinha,et al.  Resurgence of natural colourants: a holistic view , 2004, Natural product research.

[118]  Greg P. Smestad,et al.  Education and solar conversion:: Demonstrating electron transfer , 1998 .

[119]  Masaki Murayama,et al.  Utilization of natural carotenoids as photosensitizers for dye-sensitized solar cells , 2007 .

[120]  M. S. Shekhawat Studies on the Use of In vitro Synthesized Red Dye of Arnebia hispidissima L. in Textile Industries , 2012 .

[121]  Sara J. Kadolph,et al.  In the Bag: Contact Natural Dyes , 2004 .

[122]  M I Savvidou,et al.  Colour gamut produced by applying mixtures of natural dyes on de‐inked mechanical pulp , 2007 .

[123]  Homa Maleki,et al.  Plasma and Ultrasonic Process in Dyeing of Wool Fibers with Madder in Presence of Lecithin , 2011 .

[124]  Jixun Zhan,et al.  A kind of potential food additive produced by Streptomyces coelicolor: Characteristics of blue pigment and identification of a novel compound, λ-actinorhodin , 2006 .

[125]  G. Zanin,et al.  Interaction of curcumin and bixin with β-cyclodextrin: complexation methods, stability, and applications in food. , 2011, Journal of agricultural and food chemistry.

[126]  Padma S. Vankar,et al.  Sonicator dyeing of natural polymers with Symplocos spicata by metal chelation , 2008 .

[127]  Mahmood Ghoranneviss,et al.  Influence of plasma sputtering treatment on natural dyeing and antibacterial activity of wool fabrics , 2011 .

[128]  M. Kumar,et al.  Effect of chitosan treatment on the properties of turmeric dyed cotton yarn , 2007 .

[129]  Subbiyan Rajendran,et al.  Ecofriendly antimicrobial finishing of textiles using bioactive agents based on natural products , 2009 .

[130]  M. Hossein . Bazargan,et al.  PERFORMANCE OF NANO STRUCTURED DYE-SENSITIZED SOLAR CELL UTILIZING NATURAL SENSITIZER OPERATED WITH PLATINUM AND CARBON COATED COUNTER ELECTRODES , 2009 .

[131]  Nikolaos Nikolaidis,et al.  Digital and conventional printing and dyeing with the natural dye annatto: optimisation and standardisation processes to meet future demands , 2013 .

[132]  Aurora E. Clark,et al.  DFT characterization of the optical and redox properties of natural pigments relevant to dye-sensitized solar cells , 2007 .

[133]  Padma S. Vankar,et al.  An assessment and characterization for biosorption efficiency of natural dye waste , 2013 .

[134]  Shayeda,et al.  Formulation and evaluation of commonly used natural hair colorants , 2008 .

[135]  H. Oda,et al.  Improvement of light fastness of natural dye: effect of ultraviolet absorbers containing benzotriazolyl moiety on the photofading of red carthamin , 2012 .

[136]  J. A. Campo,et al.  Outdoor cultivation of microalgae for carotenoid production: current state and perspectives , 2007, Applied Microbiology and Biotechnology.

[137]  Rattanaphol Mongkholrattanasit,et al.  Dyeing, Fastness, and UV Protection Properties of Silk and Wool Fabrics Dyed with Eucalyptus Leaf Extract by the Exhaustion Process , 2011 .

[138]  Mónica González,et al.  Optimizing conditions for the extraction of pigments in cochineals (Dactylopius coccus Costa) using response surface methodology. , 2002, Journal of agricultural and food chemistry.

[139]  Ramamoorthy Siva,et al.  Status of natural dyes and dye-yielding plants in India , 2007 .

[140]  Carmen G. Boeriu,et al.  Colorants based on renewable resources and food‐grade colorants for application in thermoplastics , 2004 .

[141]  Sin-hee Kim,et al.  Dyeing characteristics and UV protection property of green tea dyed cotton fabrics , 2006 .

[142]  John B. Bremner,et al.  Dyeing of cotton and silk yarn with the extracted dye from the fruit hulls of mangosteen,Garcinia mangostana linn , 2007 .

[143]  Christian Graziani Garcia,et al.  Efficient and low cost devices for solar energy conversion: Efficiency and stability of some natural-dye-sensitized solar cells , 2009 .

[144]  Rattanaphol Mongkholrattanasit,et al.  UV protection properties of silk fabric dyed with eucalyptus leaf extract , 2011 .

[145]  Hiroshi Kato,et al.  Potentialities of Natural Dyestuffs as Antifeedants against Varied Carpet Beetle, Anthrenus verbasci , 2004 .

[146]  K. W. Waldron,et al.  Sustainable Dyes from Agri-Food Chain Co-Products , 2009 .

[147]  Shoji Furukawa,et al.  Characteristics of dye-sensitized solar cells using natural dye , 2009 .

[148]  Tim L Dawson,et al.  Progress towards a greener textile industry , 2012 .

[149]  Venkatasubramanian Sivakumar,et al.  Effective natural dye extraction from different plant materials using ultrasound , 2011 .

[150]  V P Kapoor,et al.  Herbal Cosmetics for Skin and Hair care , 2005 .

[151]  S. H. Nassar,et al.  Technological evaluation of reactive cyclodextrin in cotton printing with reactive and natural dyes , 2006 .

[152]  Nikhat Manzoor,et al.  Assessment of antimicrobial activity of Catechu and its dyed substrate , 2011 .

[153]  A. Dash,et al.  Evaluation of red cabbage dye as a potential natural color for pharmaceutical use. , 2002, International journal of pharmaceutics.

[154]  N. Muthukumarasamy,et al.  Dye-sensitized ZnO nanorod based photoelectrochemical solar cells with natural dyes extracted from Ixora coccinea, Mulberry and Beetroot , 2011 .

[155]  Guy Campet,et al.  Alternative natural dyes in water purification: Anthocyanin as TiO2-sensitizer in methyl orange photo-degradation , 2011 .

[156]  M. M. Kamel,et al.  Dyeing of modified acrylic fibers with curcumin and madder natural dyes , 2009 .

[157]  Padma S. Vankar,et al.  Sonicator dyeing of cotton fabric and chemical characterization of the colorant from Melastoma malabathricum , 2009 .

[158]  Nelson Durán,et al.  Enzyme applications in the textile industry , 2008 .

[159]  Peter Gies,et al.  Photoprotection by clothing , 2007, Photodermatology, photoimmunology & photomedicine.

[160]  E. Kaxiras,et al.  Natural dyes adsorbed on TiO2 nanowire for photovoltaic applications: enhanced light absorption and ultrafast electron injection. , 2008, Nano letters.

[161]  Thomas Bechtold,et al.  Reuse of ash‐tree (Fraxinus excelsior L.) bark as natural dyes for textile dyeing: process conditions and process stability , 2007 .

[162]  Jungmin Lee,et al.  Tracking color and pigment changes in anthocyanin products , 2005 .

[163]  Eun-Kyung Hwang,et al.  Dyeing and deodorizing properties of cotton, silk, wool fabrics dyed with Amur Corktree, Dryopteris crassirhizoma, Chrysanthemum boreale, Artemisia extracts , 2010 .

[164]  Santosh K. Upadhyay,et al.  Natural dye–surfactant interactions: thermodynamic and surface parameters , 2012 .

[165]  A. K. Panda,et al.  Exploring sustainable technique on natural dye extraction from native plants for textile: identification of colourants, colourimetric analysis of dyed yarns and their antimicrobial evaluation , 2012 .

[166]  Padma S. Vankar,et al.  Eco‐friendly pretreatment of silk fabric for dyeing with Delonix regia extract , 2009 .

[167]  Lijing Wang,et al.  Application of acacia natural dyes on cotton by pad dyeing , 2012, Fibers and Polymers.

[168]  Changhai Xu,et al.  Extraction of natural dyes from Alpinia blepharocalyx K. Schum. for dyeing of silk fabric , 2013 .

[169]  Atul K. Raturi,et al.  Photosynthesis in a test tube- dye sensitized solar cells as a teaching tool , 2010 .

[170]  P. Griffiths,et al.  Comparative study of lac dye adsorption on cotton fibre surface modified by synthetic and natural polymers , 2006 .

[171]  D. Hill,et al.  Is there a future for natural dyes , 2008 .

[172]  J. Rabani,et al.  Photosensitization of nanocrystalline TiO2 films by pomegranate pigments with unusually high efficiency in aqueous medium. , 2001, Chemical communications.

[173]  M. Kamel,et al.  SOME STUDIES ON DYEING PROPERTIES OF COTTON FABRICS WITH CROCUS SATIVUS (SAFFRON) (FLOWERS) USING AN ULTRASONIC METHOD , 2009, AUTEX Research Journal.

[174]  Ulf Thrane,et al.  Colorimetric characterization for comparative analysis of fungal pigments and natural food colorants. , 2006, Journal of agricultural and food chemistry.

[175]  Adrian Georgescu,et al.  A combined experimental and theoretical study of natural betalain pigments used in dye-sensitized solar cells , 2012 .

[176]  Mihai Irimia-Vladu,et al.  Indigo ‐ A Natural Pigment for High Performance Ambipolar Organic Field Effect Transistors and Circuits , 2012, Advanced materials.

[177]  Taekyeong Kim,et al.  Berberine finishing for developing antimicrobial nylon 66 fibers: % exhaustion, colorimetric analysis, antimicrobial study, and empirical modeling , 2007 .

[178]  P. R. China,et al.  Extraction of coloring matter from Sargentodoxa cuneata by ultrasonic technique and its application on wool fabric , 2008 .

[179]  S. Rajanarayanan,et al.  Evaluation of antibacterial, antifungal, and antioxidant properties of some food dyes , 2011 .

[180]  N. Muthukumarasamy,et al.  Natural dye (cyanidin 3-O-glucoside) sensitized nanocrystalline TiO2 solar cell fabricated using liquid electrolyte/quasi-solid-state polymer electrolyte , 2011 .

[181]  Kiran Sachan,et al.  Optimization of extraction and dyeing conditions for traditional turmeric dye , 2007 .

[182]  Balaraman Madhan,et al.  Studies on the application of natural dye extract from Bixa orellana seeds for dyeing and finishing of leather , 2013 .

[183]  Runu Chakraborty,et al.  The use of a natural colorant based on betalain in the manufacture of sweet products in India , 2004 .

[184]  Mahmood Ghoranneviss,et al.  Investigation on dye ability and antibacterial activity of nanolayer platinum coated polyester fabric using DC magnetron sputtering , 2011 .

[185]  Barbara M. Gatewood,et al.  Naturally occurring quinones and flavonoid dyes for wool: Insect feeding deterrents , 2005 .

[186]  M. Casal,et al.  Application of enzymes for textile fibres processing , 2008 .

[187]  Craig J. Hawker,et al.  A renaissance of color: New structures and building blocks for organic electronics , 2013 .

[188]  Mihai Irimia-Vladu,et al.  Indigo and Tyrian Purple – From Ancient Natural Dyes to Modern Organic Semiconductors , 2012 .

[189]  J. Frisvad,et al.  Exploring fungal biodiversity for the production of water-soluble pigments as potential natural food colorants. , 2005, Current opinion in biotechnology.

[190]  Aminah Abdullah,et al.  Real-Time Monitoring of Shrimp Spoilage Using On-Package Sticker Sensor Based on Natural Dye of Curcumin , 2012, Food Analytical Methods.

[191]  N. M. Iha,et al.  Photoelectrochemical solar cell using extract of Eugenia jambolana Lam as a natural sensitizer. , 2003, Anais da Academia Brasileira de Ciencias.

[192]  A C Dweck,et al.  Natural ingredients for colouring and styling. , 2002, International journal of cosmetic science.

[193]  Somes Bhaumik,et al.  Antimicrobial treatments for textiles , 2007 .

[194]  Stephen M. Burkinshaw,et al.  The mordant dyeing of wool using tannic acid and FeSO4, Part 1: Initial findings , 2009 .

[195]  Xiaopeng Zhao,et al.  The synergistic effect of two photosynthetic pigments in dye-sensitized mesoporous TiO2 solar cells , 2008 .

[196]  Yuxin Cheng,et al.  Dyeing and UV-protection properties of water extracts from orange peel , 2013 .

[197]  Bingqing Wei,et al.  Anthocyanin-sensitized solar cells using carbon nanotube films as counter electrodes , 2008, Nanotechnology.

[198]  F Nawaz Khan,et al.  Characterisation of novel pH indicator of natural dye Oldenlandia umbellata L. , 2009, Natural product research.

[199]  Ho Chang,et al.  Pomegranate leaves and mulberry fruit as natural sensitizers for dye-sensitized solar cells , 2010 .

[200]  Liqiong Wu,et al.  Dye-sensitized solar cells using 20 natural dyes as sensitizers , 2011 .

[201]  Deevya L. Narayanan,et al.  Review: Ultraviolet radiation and skin cancer , 2010, International journal of dermatology.

[202]  Florian C. Stintzing,et al.  Betalain stability and degradation--structural and chromatic aspects , 2006 .

[203]  Florian C. Stintzing,et al.  Betalains – emerging prospects for food scientists , 2007 .

[204]  Ahmet Sarı,et al.  Ellagic acid from gallnut ( Quercus infectoria ): Extraction and determination of its dyeing conditions for natural fibres , 2005 .

[205]  Ian Holme,et al.  Sir William Henry Perkin: a review of his life, work and legacy , 2006 .

[206]  Anuradha Mishra,et al.  Curcumin, a natural colorant as initiator for photopolymerization of styrene: kinetics and mechanism , 2007 .

[207]  S M'Garrech,et al.  Colorimetric study of effect of gamma-radiation on the color of cotton fabric colored by "henna" dye. , 2009, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[208]  A. Mortensen Carotenoids and other pigments as natural colorants , 2006 .

[209]  Maria Caridi,et al.  Environmental sustainability in fashion supply chains: An exploratory case based research , 2012 .

[210]  Lay Gaik Teoh,et al.  Commercial and natural dyes as photosensitizers for a water-based dye-sensitized solar cell loaded with gold nanoparticles , 2008 .

[211]  Javed Iqbal,et al.  Effect of UV radiation on dyeing of cotton fabric with extracts of henna leaves , 2008 .

[212]  Byung-Taek Oh,et al.  Assessment of the dyeing properties of pigments from five fungi and anti‐bacterial activity of dyed cotton fabric and leather , 2009 .

[213]  Cheng Yang,et al.  Adsorption Isotherms and Mordant Dyeing Properties of Tea Polyphenols on Wool, Silk, and Nylon , 2010 .

[214]  Özlenen Erdem İşmal,et al.  Almond shell as a natural colorant , 2012 .

[215]  Robert U. Ayres,et al.  On the life cycle metaphor: where ecology and economics diverge , 2004 .

[216]  S. N. Chattopadhyay,et al.  Development of natural dyed jute fabric with improved colour yield and UV protection characteristics , 2013 .

[217]  Ramamoorthy Siva,et al.  An alternative tracking dye for gel electrophoresis , 2008 .

[218]  M. Narayan,et al.  Review: Dye sensitized solar cells based on natural photosensitizers , 2011 .

[219]  Padma S. Vankar,et al.  Enzymatic natural dyeing of cotton and silk fabrics without metal mordants , 2007 .

[220]  H. Kim,et al.  Dyeing properties and colour fastness of cotton and silk fabrics dyed withCassia tora L. extract , 2004 .

[221]  R. El-Shishtawy,et al.  Ultrasonic assisted dyeing. IV. Dyeing of cationised cotton with lac natural dye , 2007 .

[222]  Sambandam Anandan,et al.  Performance of dye-sensitized solar cells fabricated with extracts from fruits of ivy gourd and flowers of red frangipani as sensitizers. , 2013, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[223]  A. Raja,et al.  Influence of Enzyme and Mordant Treatments on the Antimicrobial Efficacy of Natural Dyes on Wool Materials , 2011 .

[224]  L. Ammayappan,et al.  Study of antimicrobial activity of aloevera, chitosan, and curcumin on cotton, wool, and rabbit hair , 2009 .

[225]  Greg P. Smestad,et al.  Demonstrating Electron Transfer and Nanotechnology: A Natural Dye-Sensitized Nanocrystalline Energy Converter , 1998 .

[226]  António Candeias,et al.  Enlightening the influence of mordant, dyeing technique and photodegradation on the colour hue of textiles dyed with madder – A chromatographic and spectrometric approach , 2011 .

[227]  Wimonrat Sricharussin,et al.  Effect of enzymatic treatment on the dyeing of pineapple leaf fibres with natural dyes , 2009 .

[228]  Aminoddin Haji,et al.  Functional Dyeing of Wool with Natural Dye Extracted from Berberis vulgaris Wood and Rumex Hymenosepolus Root as Biomordant , 2010 .

[229]  Ashis Kumar Samanta,et al.  Application of natural dyes on textiles , 2009 .

[230]  Susanne Geissler Economic Aspects of Natural Dyes , 2009 .

[231]  R. Wrolstad,et al.  Anthocyanin pigments: Bioactivity and coloring properties , 2006 .

[232]  Andrew J Lamb,et al.  Antimicrobial activity of flavonoids , 2005, International Journal of Antimicrobial Agents.

[233]  Shahid Adeel,et al.  Dyeing properties of cotton fabric using un-irradiated and gamma irradiated extracts of Eucalyptus camaldulensis bark powder , 2011 .

[234]  Sandipan Chatterjee,et al.  Biotechnological potential of natural food grade biocolorants , 2008 .

[235]  Shela Gorinstein,et al.  Extraction and characterization of some natural plant pigments , 2012 .

[236]  T. Das,et al.  Colourimetric analysis and antimicrobial study of natural dyes and dyed silk , 2010 .

[237]  N. Ahmed,et al.  Ultrasonic dyeing of cationized cotton fabric with natural dye. Part 1: cationization of cotton using Solfix E. , 2009, Ultrasonics sonochemistry.

[238]  Darko Ujević,et al.  Analysis of High-Frequency Artificial Leather Welding as a Function of Seam Quality , 2011 .

[239]  Sam-Soo Kim,et al.  Improving the colorfastness of poly(ethylene terephthalate) fabrics with the natural dye of Caesalpinia sappan L. Wood extract and the effect of chitosan and low‐temperature plasma , 2008 .

[240]  Erika Ganglberger Environmental Aspects and Sustainability , 2009 .

[241]  M. Grätzel Dye-sensitized solar cells , 2003 .

[242]  A. Sarkar,et al.  An evaluation of UV protection imparted by cotton fabrics dyed with natural colorants , 2004, BMC dermatology.

[243]  Giuseppe Vasapollo,et al.  Anthocyanins from bay (Laurus nobilis L.) berries. , 2005, Journal of agricultural and food chemistry.

[244]  Maria C. Thiry Staying alive: making textiles sustainable , 2011 .

[245]  Eun-Kyung Hwang,et al.  Dyeing, fastness, and deodorizing properties of cotton, silk, and wool fabrics dyed with gardenia, coffee sludge, Cassia tora. L., and pomegranate extracts , 2008 .

[246]  Majid Montazer,et al.  Colorimetric properties of wool dyed with natural dyes after treatment with ammonia , 2004 .

[247]  Louis Cindrella,et al.  Molecular orbital evaluation of charge flow dynamics in natural pigments based photosensitizers , 2010, Journal of molecular modeling.

[248]  Padma S. Vankar,et al.  Ecofriendly ultrasonic natural dyeing of cotton fabric with enzyme pretreatments , 2008 .

[249]  Pradeep Kumar Mishra,et al.  Extraction of natural dye from Dahlia variabilis using ultrasound , 2012 .

[250]  Ulf Thrane,et al.  Fungal polyketide azaphilone pigments as future natural food colorants? , 2010, Trends in biotechnology.

[251]  Patricia Cox Crews,et al.  TEXTILE TECHNOLOGY The Ultraviolet Protection Factor of Naturally-pigmented Cotton , 2005 .

[252]  Qing Dai,et al.  Unusually efficient photosensitization of nanocrystalline TiO2 films by pomegranate pigments in aqueous medium , 2002 .

[253]  N. M. Iha,et al.  Blue sensitizers for solar cells: Natural dyes from Calafate and Jaboticaba , 2006 .

[254]  G. Cuevas-Rodríguez,et al.  Cotton fabric dyeing with cochineal extract: influence of mordant concentration , 2011 .

[255]  P Pushpangadan,et al.  Development of natural dye based sindoor , 2008 .

[256]  Tsutomu Miyasaka,et al.  Chlorin-sensitized High-efficiency Photovoltaic Cells that Mimic Spectral Response of Photosynthesis , 2008 .

[257]  Padma S. Vankar,et al.  Sonicator dyeing of cotton with the leaves extract Acer pectinatum Wallich , 2008 .

[258]  Eunjou Yi,et al.  Color analysis of natural colorant‐dyed fabrics , 2008 .

[259]  Kyung Hwa Hong,et al.  Preparation and properties of multi-functionalized cotton fabrics treated by extracts of gromwell and gallnut , 2012, Cellulose.

[260]  Sumaeth Chavadej,et al.  Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers , 2007 .

[261]  Siddhartha Datta,et al.  Response surface optimization and artificial neural network modeling of microwave assisted natural dye extraction from pomegranate rind , 2012 .

[262]  Navid Nasirizadeh,et al.  Optimization of wool dyeing with rutin as natural dye by central composite design method , 2012 .

[263]  T. Bechtold,et al.  Process balance and product quality in the production of natural indigo from Polygonum tinctorium Ait. applying low-technology methods. , 2002, Bioresource technology.

[264]  A. Salem,et al.  Eco-friendly printing of natural fabrics using natural dyes from alkanet and rhubarb , 2009 .

[265]  N. Lewis,et al.  Powering the planet: Chemical challenges in solar energy utilization , 2006, Proceedings of the National Academy of Sciences.

[266]  N. Durán,et al.  Ecological-Friendly Pigments From Fungi , 2002, Critical reviews in food science and nutrition.

[267]  Masayuki Okuya,et al.  Shiso leaf pigments for dye-sensitized solid-state solar cell , 2006 .

[268]  Yuan Gao,et al.  Recent Advances in Antimicrobial Treatments of Textiles , 2008 .

[269]  T L Dawson,et al.  It must be green: meeting society’s environmental concerns , 2008, Coloration Technology.

[270]  Anna Maria Mercuri,et al.  Surface‐enhanced Raman spectroscopy (SERS) on silver colloids for the identification of ancient textile dyes. Part II: pomegranate and sumac , 2011 .

[271]  Ioannis Eleftheriadis,et al.  Comparative study of dyeing properties of two yellow natural pigments—Effect of enzymes and proteins , 1998 .

[272]  Padma S. Vankar,et al.  Ultrasonic dyeing of cotton fabric with aqueous extract of Eclipta alba , 2007 .

[273]  G.K.R. Senadeera,et al.  Natural anthocyanins as photosensitizers for dye-sensitized solar devices , 2008 .

[274]  Seeram Ramakrishna,et al.  Dyeing and antimicrobial characteristics of chitosan treated wool fabrics with henna dye , 2009 .

[275]  Suk-Chul Choi,et al.  Effect of Low Temperature Plasma Treatment on Color of Wool and Nylon 6 Fabrics Dyed with Natural Dyes , 1998 .

[276]  Roberto Argazzi,et al.  Natural dye senstizers for photoelectrochemical cells , 2009 .

[277]  M P Sathianarayanan,et al.  Antibacterial finish for cotton fabric from herbal products , 2010 .

[278]  Rajasekar Saranya,et al.  Dyeing of silk fabric with phenazine from Pseudomonas species , 2012 .

[279]  N. Laohakunjit,et al.  Natural pigments from six species of Thai plants extracted by water for hair dyeing product application , 2012 .

[280]  M. Liakopoulou-Kyriakides,et al.  Dyeing of cotton and wool fibres with pigments from Crocus Sativus - Effect of enzymatic treatment , 1998 .

[281]  M. D. Teli,et al.  Eco-friendly dyeing using natural mordant extracted from Emblica officinalis G. Fruit on cotton and silk fabrics with antibacterial activity , 2011 .

[282]  Nikhat Manzoor,et al.  Dyeing, fastness and antimicrobial properties of woolen yarns dyed with gallnut (Quercus infectoria Oliv.) extract , 2012 .

[283]  Chonyu Chen,et al.  Antimicrobial activity of cotton fabric pretreated by microwave plasma and dyed with onion skin and onion pulp extractions , 2007 .

[284]  Evangelia A. Varella,et al.  Colour and fastness of natural dyes: revival of traditional dyeing techniques , 2011 .

[285]  R. El-Shishtawy,et al.  The use of new technologies in coloration of textile fibers , 2010 .

[286]  Steven Jansen,et al.  Hanging by a Thread: Natural Metallic Mordant Processes in Traditional Indonesian Textiles1 , 2011, Economic Botany.

[287]  Gérard Vilarem,et al.  Improving light fastness of natural dyes on cotton yarn , 2006 .

[288]  T. Hahn,et al.  Enzymatic conversion of precarthamin to carthamin by a purified enzyme from the yellow petals of safflower. , 2000, Journal of agricultural and food chemistry.

[289]  Deepti Gupta,et al.  Antimicrobial activity of some natural dyes , 2005 .