Five sesquiterpene polyol esters with ss-dihydroagarofuran including 1ss-acetoxy-8ss,9α-dibenzoyloxy-6α-hydroxy-2ss(α-methylbutanoyloxy)-ss-dihydroa garofuran(1), 1ss-acetoxy-8ss,9α-dibenzoyloxy-4α,6α-dihydroxy-2ss(α-methyl-butanoyloxy)-ss-dihydroagarofuran (2), 1ss-acetoxy-2ss, 8ss, 9α-tribenzoyloxy-6α-hydroxy-ss-dihydroagarofuran (3), 1ss-acetoxy-2ss,8ss,9α-tribenzoyloxy-4,6α-dihydroxy-ss-dihydroagarofuran (4) and celahin-D (5), as well as five triterpenes including friedelin (6), lupeol (7), lupenone (8), betulin (9) and lup-20(29)-en-3ss,30-diol (10) were isolated from the EtOH extract of the stems of Celastrus punctatus. The structural determinations of compounds 1 to 10 were established on the basis of spectral analysis. Biological evaluation revealed that these compounds were not highly cytotoxic against KB, Hepa-3B, Hela and COLO-205 cancer cells.