论文信息 - Coulomb exchange interaction between electrons in the atom and structure of complex configurations

Coulomb exchange interaction between electrons in the atom and structure of complex configurations

The Coulomb exchange interaction operator and its matrix elements are represented in a special form, which enables the investigation of groups of terms, caused by this interaction, and the construction of new wavefunction bases. The existence of distinct upper and lower groups of terms due to exchange interaction in configurations n(l-1)-1nlN and nl4l+2-Nn(l+1) for small numbers of electrons or vacancies N=1, 2 is shown. The separation of groups becomes more pronounced in the two-configuration approximation on taking into account correlations with symmetric exchange of symmetry. In this case a new wavefunction basis is proposed.

S. Kučas | R. Karazija

[1] Z. Rudzikas,et al. Isospin method for complex electronic configurations , 1987 .

[2] J. Bauche,et al. Quenching of transition arrays through configuration mixing , 1987 .

[3] W. Persson,et al. Spectrum of Rb IV , 1985 .

[4] C. Nicolaides,et al. Specific correlation effects in inner-electron photoelectron spectroscopy , 1982 .

[5] J. Connerade. Controlling the collapse of atomic wavefunctions , 1978 .

[6] W. Persson,et al. Spectrum of Trebly-Ionized Strontium (Sr IV) , 1976 .

[7] M. Aymar. Cancellation effects in computed lifetimes of 3s3pn levels for third-row atoms and ions , 1973 .

[8] J. E. Hansen. Hartree-Fock predictions of the 1P term in the p5d configurations of the spectra in the Ar I and Kr I isoelectronic sequences , 1972 .

[9] J. Sugar. Potential-Barrier Effects in Photoabsorption. II. Interpretation of Photoabsorption Resonances in Lanthanide Metals at the 4 d -Electron Threshold , 1972 .