Water Reducers/Retarders

Publisher Summary This chapter examines water reducers/retarders admixtures. A water reducer can be defined as an admixture that reduces the amount of mixing water for concrete for a given workability. It improves the properties of hardened concrete and, in particular, increases strength and durability. Usually, according to standards the reduction of mixing water by the use of these admixtures must be at least 5%. However, commercial water reducers can reduce mixing water up to 10 to 15%.There is another mode of use of these admixtures, involving reduction of both water and cement, so that workability and strength of concrete containing admixtures are similar to those of the control concrete. Admixtures could thus act as cement reducers. Besides allowing cement saving, these admixtures are capable of reducing the heat of hydration, a property that is useful for concreting in hot climates or massive structures. If water reducers are added without modifying mix proportions, concrete workability improves; in this case they act as plasticizers. This is particularly useful for placing concrete in areas of high steel content thatrequire a more workable concrete.

[1]  H. Taylor,et al.  Crystal Structure of Ettringite , 1968, Nature.

[2]  E. G. Swenson,et al.  Morphology and microstructure of hydrating portland cement and its constituents V. Changes in hydration of portland cement with and without the presence of triethanolamine and calcium lignosulphonate , 1971 .

[3]  R. L. Berger,et al.  Influence of admixtures on the morphology of calcium hydroxide formed during tricalcium silicate hydration , 1972 .

[4]  H. Taylor Hydraulic cement pastes: Their structure and properties: Cement and concrete Association, Slough, England, 1976. Paperback, 334 pages, £9. , 1976 .

[5]  J. F. Young Discussion: Hydration of tricalcium aluminate with lignosulphonate additives* , 1964 .

[6]  S. Diamond Interactions Between Cement Minerals and Hydroxycarboxylic‐Acid Retarders: III, Infrared Spectral Identification of the Aluminosalicylate Complex , 1972 .

[7]  D. R. Rossington,et al.  Adsorption of Admixtures on Portland Cement , 1963 .

[8]  N. B. Milestone,et al.  The effect of glucose and some glucose oxidation products on the hydration of tricalcium aluminate , 1977 .

[9]  M. Daimon,et al.  Early Hydration of Tricalcium Silicate: A Solid Reaction with Induction and Acceleration Periods , 1969 .

[10]  G. M. Bruere Importance of Mixing Sequence when using Set-Retarding Agents with Portland Cement , 1963, Nature.

[11]  M. Collepardi,et al.  Penetration of Chloride Ions into Cement Pastes and Concretes , 1972 .

[12]  N. B. Milestone The effect of lignosulphonate fractions on the hydration of tricalcium aluminate , 1976 .

[13]  N. B. Milestone Hydration of Tricalcium Silicate in the Presence of Lignosulfonates, Glucose, and Sodium Gluconate , 1979 .

[14]  Adsorption of Admixtures on Portland Cement Hydration Products , 1968 .

[15]  N. L. Thomas,et al.  The effect of lead nitrate on the early hydration of portland cement , 1981 .

[16]  G. M. Bruere Set-retarding Effects of Sugars in Portland Cement Pastes , 1966, Nature.

[17]  A. Glasnović,et al.  The grinding equation in the investigation of the coarse dispersing system of cement , 1982 .

[18]  G. Moriconi,et al.  Combined effect of lignosulfonate and carbonate on pure portland clinker compounds hydration. III. Hydration of tricalcium silicate alone and in the presence of tricalcium aluminate , 1982 .

[19]  V. S. Ramachandran Elucidation of the role of chemical admixtures in hydrating cements by DTA technique , 1972 .

[20]  Bayard M. Call Slump Loss with Type “K” Shrinkage Compensating Cement Concretes and Admixtures , 1979 .

[21]  N. Greening,et al.  STUDIES OF EARLY HYDRATION REACTIONS OF PORTLAND CEMENT BY X -RAY DIFFRACTION , 1964 .

[22]  V. S. Ramachandran Interaction of calcium lignosulfonate with tricalcium silicate, hydrated tricalcium silicate, and calcium hydroxide , 1972 .

[23]  Dan Ravina,et al.  Retempering of Prolonged-Mixed Concrete with Admixtures in Hot Weather , 1975 .

[24]  D. R. Rossington,et al.  Early hydration of cement constituents with organic admixtures , 1981 .

[25]  M. Pauri,et al.  Combined effect of lignosulfonate and carbonate on pure portland clinker compounds hydration. IV. Hydration of tricalcium aluminate-sodium oxide solid solution , 1983 .

[26]  J. Hodge,et al.  Complexes of carbohydrates with aluminate ion. Chromatography of carbohydrates on columns of anion-exchange resin (aluminate form)☆ , 1975 .

[27]  V. S. Ramachandran,et al.  The role of phosphonates in the hydration of Portland cement , 1993 .

[28]  Sidney Diamond,et al.  Consistency, setting, and strength gain characteristics of a “low porosity” Portland cement paste , 1978 .

[29]  M. Pauri,et al.  Tricalcium aluminate hydration in the presence of lime, gypsum or sodium sulfate , 1978 .

[30]  F. Massazza,et al.  Interaction Between Superplasticizers and Calcium Aluminate Hydrates , 1982 .

[31]  K T Greene A SETTING PROBLEM INVOLVING WHITE CEMENT AND ADMIXTURE , 1976 .

[32]  J. Skalny,et al.  Hydration of Cement‐Lignosulfonate‐Alkali Carbonate System , 1979 .

[33]  L. M. Meyer,et al.  Theory of Concrete Slump Loss as Related to the Use of Chemical Admixtures , 1979 .

[34]  I. Odler,et al.  On the combined effect of water solubles lignosulfonates and carbonates on portland cement and clinker pastes 1. Physical properties , 1978 .

[35]  William A. Cordon,et al.  Properties and Uses of Initially Retarded Concrete , 1955 .

[36]  J. Young Effect of Organic Compounds on the Interconversions of Calcium Aluminate Hydrates: Hydration of Tricalcium Aluminate , 1970 .

[37]  J. F. Young,et al.  A review of the mechanisms of set-retardation in portland cement pastes containing organic admixtures , 1972 .

[38]  Robert W. Previte,et al.  Concrete Slump Loss , 1977 .

[39]  J. F. Young,et al.  Hydration of tricalcium aluminate with lignosulphonate additives , 1962 .

[40]  Early Hydration of Tricalcium Silicate , 1976 .

[41]  S. Diamond Interactions Between Cement Minerals and Hydroxycarboxylic‐Acid Retarders: I, Apparent Adsorption of Salicylic Acid on Cement and Hydrated Cement Compounds , 1971 .

[42]  E. G. Swenson,et al.  Morphology and microstructure of hydrating portland cement and its constituents I. Changes in hydration of tricalcium aluminate alone and in the presence of triethanolamine or calcium lignosulphonate , 1971 .

[43]  S. M. Khalil,et al.  Influence of a lignin based admixture on the hydration of portland cements , 1973 .

[44]  E. G. Swenson,et al.  Morphology and microstructure of hydrating portland cement and its constituents II. Changes in hydration of calcium silicates alone and in the presence of triethanolamine and calcium lignosulphonate, both with and without gypsum , 1971 .

[45]  W. G. France,et al.  Some physical and chemical properties of weight-fractionated lignosulfonic acid, including the dissociation of lignosulfonates. , 1948, The Journal of physical and colloid chemistry.

[46]  N. Alford,et al.  The effect of lead nitrate on the physical properties of cement pastes , 1981 .

[47]  N. B. Singh Influence of calcium gluconate with calcium chloride or glucose on the hydration of cements , 1975 .

[48]  P.F.G. Banfill A discussion of the papers “rheological properties of cement mixes” by M. Daimon and D. M. Roy☆ , 1979 .

[49]  I. Odler,et al.  On the combined effect of water soluble lignosulfonates and carbonates on portland cement and clinker pastes — II. Mode of action and structure of the hydration products , 1978 .

[50]  Jan Skalny,et al.  USE OF ADMIXTURES IN PRODUCTION OF LOW-POROSITY PASTES AND CONCRETES , 1976 .

[51]  M. Pauri,et al.  Combined effect of lignosulfonate and carbonate on pure portland clinker compounds hydration. I. Tetracalcium aluminoferrite hydration , 1980 .

[52]  Jan Skalny,et al.  HARDENED PORTLAND CEMENT PASTES OF LOW POROSITY , 1973 .

[53]  H. Takahashi,et al.  Hardening property of cement mortar adding heavy metal compound and solubility of heavy metal from hardened mortar , 1977 .

[54]  J. Grandet,et al.  Etude de l'effet retardateur du zinc sur l'hydratation de la pate de ciment Portland , 1982 .

[55]  Kenneth E Daugherty,et al.  USE OF ADMIXTURES IN CONCRETE PLACED AT HIGH TEMPERATURES , 1976 .

[56]  R. L. Angstadt,et al.  THE EFFECT OF SOME SOLUBLE INORGANIC ADMIXTURES ON THE EARLY HYDRATION OF PORTLAND CEMENT , 1966 .

[57]  M. R. Rixom,et al.  Role of Lignosulfonates as Superplasticizers , 1981 .

[58]  J. Young REACTION MECHANISM OF ORGANIC ADMIXTURES WITH HYDRATING CEMENT COMPOUNDS , 1976 .

[59]  John Ryell AN UNUSUAL CASE OF SURFACE DETERIORATION ON A CONCRETE BRIDGE DECK , 1965 .

[60]  S. M. Khalil,et al.  Effect of degree of hydration upon creep of mortars containing calcium lignosulphonate , 1977 .

[61]  G. Kalousek,et al.  Composition and physical properties of aqueous extracts from Portland cement clinker pastes containing added materials , 1943 .

[62]  R. H. Rogue,et al.  Hydration of Portland Cement Compounds , 1934 .

[63]  El Howard,et al.  Field Experience Using Water-Reducers in Ready-Mixed Concrete , 1960 .

[64]  W. Hansen Actions of Calcium Sulfate and Admixtures in Portland Cement Pastes , 1960 .

[65]  A. M. Paillère,et al.  Guide for use of admixtures in concrete , 1992 .

[66]  J. Schubert,et al.  Stability of Alkaline Earth—Organic Acid Complexes Measured by Ion Exchange1 , 1952 .