Diffuse interface simulation of ternary fluids in contact with solid

In this article we developed a geometrical wetting condition for diffuse-interface simulation of ternary fluid flows with moving contact lines. The wettability of the substrate in the presence of ternary fluid flows is represented by multiple contact angles, corresponding to the different material properties between the respective fluid and the substrate. Displacement of ternary fluid flows on the substrate leads to the occurrence of moving contact point, at which three moving contact lines meet. We proposed a weighted contact angle model, to replace the jump in contact angle at the contact point by a relatively smooth transition of contact angle over a region of 'diffuse contact point' of finite size. Based on this model, we extended the geometrical formulation of wetting condition for two-phase flows with moving contact lines to ternary flows with moving contact lines. Combining this wetting condition, a Navier-Stokes solver and a ternary-fluid model, we simulated two-dimensional spreading of a compound droplet on a substrate, and validated the numerical results of the drop shape at equilibrium by comparing against the analytical solution. We also checked the convergence rate of the simulation by investigating the axisymmetric drop spreading in a capillary tube. Finally, we applied the model to a variety of applications of practical importance, including impact of a circular cylinder into a pool of two layers of different fluids and sliding of a three-dimensional compound droplet in shear flows.

[1]  Junseok Kim,et al.  Phase field computations for ternary fluid flows , 2007 .

[2]  Harald Garcke,et al.  A phase-field approach for wetting phenomena of multiphase droplets on solid surfaces. , 2014, Langmuir : the ACS journal of surfaces and colloids.

[3]  C. Clanet,et al.  Making a splash with water repellency , 2007, cond-mat/0701093.

[4]  David Jacqmin,et al.  Contact-line dynamics of a diffuse fluid interface , 2000, Journal of Fluid Mechanics.

[5]  L. Scriven,et al.  Hydrodynamic Model of Steady Movement of a Solid / Liquid / Fluid Contact Line , 1971 .

[6]  Mehmet Yildiz,et al.  Numerical simulation of single droplet dynamics in three-phase flows using ISPH , 2013, Comput. Math. Appl..

[7]  H. Ding,et al.  Sliding, pinch-off and detachment of a droplet on a wall in shear flow , 2008, Journal of Fluid Mechanics.

[8]  Hang Ding,et al.  Inertial effects in droplet spreading: a comparison between diffuse-interface and level-set simulations , 2007, Journal of Fluid Mechanics.

[9]  Xiaoping Wang,et al.  Modeling and simulation of dynamics of three-component flows on solid surface , 2014 .

[10]  L. Marino,et al.  The sharp-interface limit of the Cahn–Hilliard/Navier–Stokes model for binary fluids , 2013, Journal of Fluid Mechanics.

[11]  J. C. Joud,et al.  Physico-chemical and dynamic study of oil-drop removal from bare and coated stainless-steel surfaces , 2006 .

[12]  P. Gennes Wetting: statics and dynamics , 1985 .

[13]  A. Techet,et al.  A spin on cavity formation during water entry of hydrophobic and hydrophilic spheres , 2009 .

[14]  Hao-Ran Liu,et al.  A diffuse-interface immersed-boundary method for two-dimensional simulation of flows with moving contact lines on curved substrates , 2015, J. Comput. Phys..

[15]  P. Spelt,et al.  Propagation of capillary waves and ejection of small droplets in rapid droplet spreading , 2012, Journal of Fluid Mechanics.

[16]  L. Limat,et al.  Shape and motion of drops sliding down an inclined plane , 2005, Journal of Fluid Mechanics.

[17]  R. Craster,et al.  Dynamics and stability of thin liquid films , 2009 .

[18]  Yves Pomeau,et al.  Recent progress in the moving contact line problem: a review , 2002 .

[19]  D. Lohse,et al.  High-speed jet formation after solid object impact. , 2008, Physical review letters.

[20]  H. Ding,et al.  Pumping through porous hydrophobic/oleophilic materials: an alternative technology for oil spill remediation. , 2014, Angewandte Chemie.

[21]  Hang Ding,et al.  Wetting condition in diffuse interface simulations of contact line motion. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[22]  Franck Boyer,et al.  Numerical schemes for a three component Cahn-Hilliard model , 2011 .

[23]  Pierre Seppecher,et al.  Moving contact lines in the Cahn-Hilliard theory , 1996 .

[24]  J. Nouri,et al.  Dynamics of water droplets detached from porous surfaces of relevance to PEM fuel cells. , 2006, Journal of colloid and interface science.

[25]  D. Chopp,et al.  A projection method for motion of triple junctions by level sets , 2002 .

[26]  Hang Ding,et al.  Numerical Simulations of Flows with Moving Contact Lines , 2014 .

[27]  Hang Ding,et al.  Onset of motion of a three-dimensional droplet on a wall in shear flow at moderate Reynolds numbers , 2008, Journal of Fluid Mechanics.

[28]  Ronald Fedkiw,et al.  Multiple interacting liquids , 2006, SIGGRAPH 2006.

[29]  E. B. Dussan,et al.  LIQUIDS ON SOLID SURFACES: STATIC AND DYNAMIC CONTACT LINES , 1979 .

[30]  Laura Schaefer,et al.  Lattice Boltzmann equation model for multi-component multi-phase flow with high density ratios , 2013 .

[31]  Chang Shu,et al.  Diffuse interface model for incompressible two-phase flows with large density ratios , 2007, J. Comput. Phys..

[32]  Philip L. Roe,et al.  A new level set model for multimaterial flows , 2014, J. Comput. Phys..