Synthesis of 12-epi -Protopanaxadiol and Formal Synthesis of Ginsenoside Chikusetsusaponin-LT8
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[1] Yi Zhang,et al. Plant Resources, 13C-NMR Spectral Characteristic and Pharmacological Activities of Dammarane-Type Triterpenoids , 2016, Molecules.
[2] Xiao-nian Li,et al. Synthesis of hupehenols A, B, and E from protopanaxadiol , 2016 .
[3] A. Osbourn,et al. Triterpene biosynthesis in plants. , 2014, Annual review of plant biology.
[4] X. Xia,et al. Asperterpenols A and B, new sesterterpenoids isolated from a mangrove endophytic fungus Aspergillus sp. 085242. , 2013, Organic letters.
[5] Yong-Eui Choi,et al. Cytochrome P450 CYP716A53v2 catalyzes the formation of protopanaxatriol from protopanaxadiol during ginsenoside biosynthesis in Panax ginseng. , 2012, Plant & cell physiology.
[6] A. D. Boer,et al. Fusicoccanes: diterpenes with surprising biological functions , 2012 .
[7] V. Denisenko,et al. Synthesis of diglycosides of 3β,20S-dihydroxydammar-24-en-12-one , 2012, Chemistry of Natural Compounds.
[8] J. F. Arteaga,et al. Total synthesis of (+)-seco-C-oleanane via stepwise controlled radical cascade cyclization. , 2012, The Journal of organic chemistry.
[9] A. D. de Boer,et al. Fusicoccanes: diterpenes with surprising biological functions. , 2012, Trends in plant science.
[10] Yong-Eui Choi,et al. The Cyt P450 enzyme CYP716A47 catalyzes the formation of protopanaxadiol from dammarenediol-II during ginsenoside biosynthesis in Panax ginseng. , 2011, Plant & cell physiology.
[11] Biao Yu,et al. Synthesis of ginsenoside Rh2 and chikusetsusaponin-LT8 via gold(I)-catalyzed glycosylation with a glycosyl ortho-alkynylbenzoate as donor , 2011 .
[12] A. Srikrishna,et al. Enantiospecific total synthesis of aciphyllene , 2010 .
[13] Xiaoyan Chen,et al. Synthesis of [3- 3 H]20( S )-protopanaxadiol , 2009 .
[14] Y. Liang,et al. Progress in understanding of ginsenoside biosynthesis. , 2008, Plant biology.
[15] A. Alexakis,et al. Copper-catalyzed asymmetric conjugate addition of trialkylaluminium reagents to trisubstituted enones: construction of chiral quaternary centers. , 2007, Chemistry.
[16] G. Mazza,et al. Saponins: Properties, Applications and Processing , 2007, Critical reviews in food science and nutrition.
[17] J. Vincken,et al. Saponins, classification and occurrence in the plant kingdom. , 2007, Phytochemistry.
[18] R. Tharanathan,et al. Fruit Ripening Phenomena–An Overview , 2007, Critical reviews in food science and nutrition.
[19] Y. Ebizuka,et al. Dammarenediol‐II synthase, the first dedicated enzyme for ginsenoside biosynthesis, in Panax ginseng , 2006, FEBS letters.
[20] M. Jung,et al. Synthetic approach to analogues of betulinic acid , 2006 .
[21] V. Denisenko,et al. Synthesis of 20S-protopanaxadiol 20-O-β-D-glucopyranoside, a metabolite of Panax ginseng glycosides, and compounds related to it , 2006, Chemistry of Natural Compounds.
[22] M. Sasaki,et al. Synthesis and absolute configuration of brevione B, an allelochemical isolated from Penicillium sp. , 2006 .
[23] V. Denisenko,et al. Synthesis of 3β,20S-dihydroxydammar-24-en-12-one 3,20-di-O-β-D-glucopyranoside (chikusetsusaponin-LT8), a glycoside from Panax japonicus , 2006, Chemistry of Natural Compounds.
[24] R. Oballa,et al. Total syntheses of the sesquiterpenoids (+)-trans-dracunculifoliol and (+)-4-hydroxyoppositan-7-one , 2005 .
[25] J. E. Oltra,et al. Titanocene-catalyzed cascade cyclization of epoxypolyprenes: straightforward synthesis of terpenoids by free-radical chemistry. , 2004, Chemistry.
[26] M. Sporn,et al. Efficient synthesis of (-)- and (+)-tricyclic compounds with enone functionalities in rings A and C. A novel class of orally active anti-inflammatory and cancer chemopreventive agents. , 2003, Organic & biomolecular chemistry.
[27] M. Sasaki,et al. The first synthesis of (±)-brevione B, an allelopathic agent isolated from Penicillium sp. , 2003 .
[28] K. Becker,et al. The biological action of saponins in animal systems: a review. , 2002, The British journal of nutrition.
[29] J. Nandakumar,et al. Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from (−)-α-pinene , 2002 .
[30] W. S. Chick,et al. The biology of ophiobolins. , 2000, Life sciences.
[31] A. Gautier,et al. The Fluorine Atom as a Cation-Stabilizing Auxiliary in Biomimetic Polyene Cyclizations: Total Synthesis of dl-Dammarenediol1 , 1999 .
[32] M. Demuth,et al. Short Biomimetic Synthesis of a Steroid by Photoinduced Electron Transfer and Remote Asymmetric Induction , 1999 .
[33] G. B. Elyakov,et al. Cytotoxicity of natural ginseng glycosides and semisynthetic analogues. , 1999, Planta medica.
[34] A. J. Blake,et al. Cascade radical cyclisations leading to polycyclic diterpenes. Total synthesis of (±)-spongian-16-one , 1998 .
[35] M. Nukina,et al. Structural Confirmation of Cotylenin A, a Novel Fusicoccane-diterpene Glycoside with Potent Plant Growth-regulating Activity from Cladosporium Fungus sp. 501-7W. , 1998, Bioscience, biotechnology, and biochemistry.
[36] E. and,et al. A Short Enantioselective Total Synthesis of Dammarenediol II , 1996 .
[37] H. Neh,et al. Nickel-Catalysed Conjugate Addition of Trimethylaluminum to Sterically Hindered α,β-Unsaturated Ketones , 1995 .
[38] L. Garlaschelli,et al. Asymmetric dihydroxylation of geranyl, neryl and trans, trans-farnesyl acetates , 1993 .
[39] Jens Hartung,et al. The Osmium-Catalyzed Asymmetric Dihydroxylation: A New Ligand Class and a Process Improvement , 1992 .
[40] T. Hasegawa,et al. The Biogenetic-Type Cyclization of the Unsaturated Monocyclic Alcohol with Formic Acid; Facile Synthesis of the Tricarbocyclic Alcohol, (+)-2-Epi-allo-cedrol , 1992 .
[41] R. Chang,et al. Variecolin, a sesterterpenoid of novel skeleton from Aspergillus variecolor MF138 , 1991 .
[42] S. Darvesh,et al. Synthetic studies towards bruceantin. Part 1. Establishment of the carbon network , 1991 .
[43] E. Ellsworth,et al. The Role of BF3·Et2O in Reactions of Lower Order (Gilman) Organocuprates , 1989 .
[44] Y. Asakawa,et al. New highly oxidized fusicoccane diterpenoids from the liverwort plagiochila acanthophylla subsp. japonica , 1985 .
[45] E. E. Tamelen. The role of organic synthesis in bioorganic chemistry , 1981 .
[46] S. Yahara,et al. Dammarane type saponins of leaves of Panax japonicus C.A. Meyer. (2). Saponins of the specimens collected in Tottori-ken, Kyoto-shi, and Niigata-ken , 1978 .
[47] J. Huffman,et al. REDUCTION OF 12-KETO STEROIDS. 2 , 1977 .
[48] O. Tanaka,et al. Syntheses of betulafolienetriol and the ginseng sapogenin, 20(S)-protopanaxadiol. , 1976, Chemical & pharmaceutical bulletin.
[49] JOSEPH P. Brown,et al. Thiations with sulphur in dimethylformamide , 1974 .
[50] B. McCarry,et al. Acetylenic bond participation in biogenetic-like olefinic cyclizations. II. Synthesis of dl-progesterone. , 1971, Journal of the American Chemical Society.
[51] H. Fujimoto,et al. Synthesis of the Skeleton of Dammarane-Type Triterpene , 1970 .
[52] Y. Iitaka,et al. Structure of ceroplasteric acid and ceroplastol I. Sesterterpenes from an insect wax , 1968 .
[53] O. Tanaka,et al. Stereochemistry of the side chain of dammarane type triterpenes , 1968 .
[54] M. Nagai,et al. Stereochemistry of protopanaxadiol: Acid catalysed epimerization of C-20 hydroxyl of betulafolienetriol, protopanaxadiol, and their derivatives , 1967 .
[55] O. Tanaka,et al. On genuine sapogenin of ginseng , 1963 .
[56] O. Tanaka,et al. The structure of panaxadiol a sapogenin of ginseng , 1962 .
[57] J. Wolinsky,et al. The Synthesis of 1-Acetyl-4-Isopropenyl-1-Cyclopentene , 1960 .