Boundary effects on a spin-model: microemulsions in a confined geometry

Widom (1986) formulated a lattice model of microemulsions in terms of a spin-1/2 Ising system with nearest-neighbour ferromagnetic interaction and further-neighbour antiferromagnetic interactions. Through Monte Carlo simulation of the Widom model on a simple cubic lattice of size Lx*Ly*Lz the authors have investigated the surface effects on the structure by imposing physically-motivated boundary conditions. In an interesting range of the interaction parameters they have observed novel structures in the narrow-gap geometry.

[1]  Evans,et al.  Classical, microscopic, liquid Poisson oscillator. , 1991, Physical review letters.

[2]  D. Stauffer,et al.  Monte Carlo simulation of the three-dimensional dilute Widom model of microemulsions , 1991 .

[3]  R. Evans REVIEW ARTICLE: Fluids adsorbed in narrow pores: phase equilibria and structure , 1990 .

[4]  Dawson,et al.  Low-temperature analysis of three-phase coexistence. , 1990, Physical review. A, Atomic, molecular, and optical physics.

[5]  Dawson,et al.  Fluctuation-induced transitions in an isotropic spatially frustrated lattice model. , 1990, Physical review. A, Atomic, molecular, and optical physics.

[6]  K. Dawson,et al.  Accounting for fluctuations in a lattice model of microemulsions , 1990 .

[7]  M. Velgakis Site-diluted two-dimensional Ising models with competing interactions , 1989 .

[8]  B. Widom Correlation and scattering functions in a lattice model of oil–water–amphiphile solutions , 1989 .

[9]  B. Widom,et al.  Phase diagram of a lattice microemulsion model , 1988 .

[10]  D. Stauffer,et al.  Monte Carlo simulations of spin-1/2 micelle and microemulsion models , 1988 .

[11]  Dawson Interfaces between phases in a lattice model of microemulsions. , 1987, Physical review. A, General physics.

[12]  B. Widom,et al.  Lattice model of microemulsions , 1986 .

[13]  R. L. Reed,et al.  Immiscible Microemulsion Flooding , 1977 .

[14]  R. L. Reed,et al.  Physsicochemical Aspects of Microemulsion Flooding , 1974 .

[15]  H. Neumann,et al.  Petroleum emulsions, micro-emulsions, and micellar solutions , 1988 .