Modeling trace gas budgets in the troposphere: 2. CH4 and CO

A two-dimensional photochemical model of the atmosphere has been used to calculate regional and global budgets for CH4 and CO in the troposphere. The modeled distributions of these trace gases are compared to relevant observations and show good agreement when the zonal average nature of the model results is taken into account. The chemical and dynamical components of the budgets are investigated and used to explain the seasonal distribution of CH4 and CO in the model. The seasonal variation is governed mainly by the seasonal variation in emissions and transport between the hemispheres. Destruction by OH is also important at certain times of the year.

[1]  J. Pyle,et al.  Studies of the ozone budget using a zonal mean circulation model and linearized photochemistry , 1977 .

[2]  J. Fishman,et al.  The significance of biomass burning as a source of carbon monoxide and ozone in the southern hemisphere tropics: A satellite analysis , 1990 .

[3]  W. Seiler,et al.  The vertical distribution of stable trace gases at mid‐latitudes , 1981 .

[4]  H. A. Wallio,et al.  The distribution of middle tropospheric carbon monoxide during early October 1984 , 1990 .

[5]  M. Khalil,et al.  Sources, sinks, and seasonal cycles of atmospheric methane , 1983 .

[6]  W. Seiler,et al.  Trends of tropospheric CO, N2O and CH4 as observed at cape point, South Africa , 1990 .

[7]  Paul J. Crutzen,et al.  A two‐dimensional photochemical model of the atmosphere: 2. The tropospheric budgets of the anthropogenic chlorocarbons CO, CH4, CH3Cl and the effect of various NO x sources on tropospheric ozone , 1983 .

[8]  E. Bigg,et al.  Tropospheric transport of trace substances in the southern hemisphere , 1990 .

[9]  P. Crutzen,et al.  Scale problems in global tropospheric chemistry modeling: Comparison of results obtained with a three-dimensional model, adopting longitudinally uniform and varying emissions of NOX and NMHC , 1993 .

[10]  D. Cunnold,et al.  Atmospheric methane: A global three‐dimensional model study , 1991 .

[11]  D. Tanner,et al.  Ion-assisted tropospheric OH measurements , 1991 .

[12]  A. J. Crawford,et al.  The global distribution of methane in the troposphere , 1987 .

[13]  W. Seiler,et al.  Trace gas measurements at the monitoring station cape point, South Africa, between 1978 and 1988 , 1990 .

[14]  S. Wofsy,et al.  Tropospheric chemistry: A global perspective , 1981 .

[15]  J. Lerner,et al.  Three‐dimensional model synthesis of the global methane cycle , 1991 .

[16]  L. P. Steele,et al.  Carbon dioxide and methane in the Arctic atmosphere , 1989 .

[17]  C. M. Stevens,et al.  The isotopic composition of atmospheric carbon monoxide , 1972 .

[18]  John A. Pyle,et al.  Modeling trace gas budgets in the troposphere: 1. Ozone and odd nitrogen , 1993 .

[19]  Paul J. Crutzen,et al.  Methane's sinks and sources , 1991, Nature.

[20]  P. Fraser,et al.  Global average concentration and trend for hydroxyl radicals deduced from ALE/GAGE trichloroethane (methyl chloroform) data for 1978–1990 , 1992 .

[21]  J. A. Pyle,et al.  A two‐dimensional mean circulation model for the atmosphere below 80km , 1975 .

[22]  D. Cahoon,et al.  Carbon monoxide over the Amazon Basin during the 1985 dry season , 1988 .

[23]  J. Fishman,et al.  Identification of Widespread Pollution in the Southern Hemisphere Deduced from Satellite Analyses , 1991, Science.

[24]  A. Ravishankara,et al.  Kinetics of the OH Reaction with Methyl Chloroform and Its Atmospheric Implications , 1992, Science.

[25]  B. Heikes,et al.  Chemical mechanisms of acid generation in the troposphere , 1985, Nature.

[26]  Ghanshyam L. Vaghjiani,et al.  New measurement of the rate coefficient for the reaction of OH with methane , 1991, Nature.

[27]  W. Seiler,et al.  The seasonality of CO abundance in the Southern Hemisphere , 1984 .

[28]  P. Fraser,et al.  Methane, carbon monoxide and methylchloroform in the southern hemisphere , 1986 .

[29]  L. O. Wade,et al.  Carbon monoxide over the Amazon Basin during the wet season. , 1990 .

[30]  A. Hough Development of a two-dimensional global tropospheric model: Model chemistry , 1991 .