A novel model of the initial state of charge estimation for LiFePO4 batteries

Abstract The State-of-Charge (SOC) is an important performance parameter and evaluation index in rechargeable battery energy storage systems. Here, a novel smart estimation method based on coulomb counting is proposed in order to enhance estimation accuracy. Firstly, an enhanced model for the initial SOC (SOC 0 ) estimation based on dynamic multi-parameter method is investigated, because SOC 0 plays a key role in calculating real SOC in-time. All the design limits, such as voltage, temperature, are used as its constraints. And more importantly, the relaxation effect also is considered. The SOC 0 with the main parameters satisfies Gauss function. Secondly, the quantitative relations of the energy efficiencies are measured and analyzed under the moderate discharging situation. The results show a negative quadratic correlation between energy efficiency and rate, and exhibit a reduction in energy efficiency as rate increases. Lastly, a test with several consecutive hybrid pulse power characteristic test profiles is carried. The experimental results indicate that the correction of SOC 0 can efficiently limit the error below 4%, and also exhibit that considering on the effect of energy efficiency can further reduce its estimation error.

[1]  Byoungwoo Kang,et al.  Battery materials for ultrafast charging and discharging , 2009, Nature.

[2]  Karen E. Thomas,et al.  Measurement of the Entropy of Reaction as a Function of State of Charge in Doped and Undoped Lithium Manganese Oxide , 2001 .

[3]  Gregory L. Plett,et al.  Extended Kalman filtering for battery management systems of LiPB-based HEV battery packs: Part 2. Modeling and identification , 2004 .

[4]  Joongpyo Shim,et al.  Effect of electrode density on cycle performance and irreversible capacity loss for natural graphite anode in lithium-ion batteries , 2003 .

[5]  K. Onda,et al.  Experimental Study on Heat Generation Behavior of Small Lithium-Ion Secondary Batteries , 2003 .

[6]  Allen J. Bard,et al.  Electrochemical Methods: Fundamentals and Applications , 1980 .

[7]  Yaoyu Li,et al.  Optimal Energy Management of Wind-Battery Hybrid Power System With Two-Scale Dynamic Programming , 2013, IEEE Transactions on Sustainable Energy.

[8]  Hongwen He,et al.  Online model-based estimation of state-of-charge and open-circuit voltage of lithium-ion batteries in electric vehicles , 2012 .

[9]  Mao-Sung Wu,et al.  Electrochemical Investigations on Advanced Lithium-Ion Batteries by Three-Electrode Measurements , 2005 .

[10]  Hongwen He,et al.  Online estimation of model parameters and state-of-charge of LiFePO4 batteries in electric vehicles , 2012 .

[11]  Song Wenji,et al.  A critical review on state of charge of batteries , 2013 .

[12]  Jiahao Li,et al.  A comparative study of state of charge estimation algorithms for LiFePO4 batteries used in electric vehicles , 2013 .

[13]  Changqing Du,et al.  A novel way to calculate energy efficiency for rechargeable batteries , 2012 .