论文信息 - CRYSTAL STRUCTURE OF TRIPHENYLTIN 4 - METHOXYBENZOATE

CRYSTAL STRUCTURE OF TRIPHENYLTIN 4 - METHOXYBENZOATE

Figure 1. Molecular structure of [Ph3Sn02CC6H40CH3-4]. Selected bond distances and angles: Sn(l)-0(1) 2.053(2), Sn(l)-0(2) 2.793(3), Sn(l)-C(21) 2.114(3), Sn(l)-C(31) 2.113(3), Sn(l)-C(41) 2.128(3), C (1)0(1) 1.308(4), C( 1 )-0(2) 1.226(4), C(l)-C(51) 1.477(4) ; C(41)-Sn(l)-C(21) 109.66(12), C(41)-Sn(l)C(31) 106.49(12), C(21 )-Sn( 1 )-C(31) 122.00(12), 0 ( 1 )-Sn( 1 )-C(21) 109.40(10), 0(1)-Sn(l)-C(41) 97.18(10), 0(l)-C(l)-0(2) 120.8(3), C(l)-0(1)-Sn(l) 110.31(19), 0(l)-Sn(l)-0(2) 51.31(20) H-atoms omitted for clarity.

C. Cahill | G. Eng | Xueqing Song

[1] Louis J. Farrugia,et al. WinGX suite for small-molecule single-crystal crystallography , 1999 .

[2] J. Vollano,et al. Pentacoordinated molecules. 65. Discrete, dimeric, and polymeric structures of triphenyltin esters of chlorobenzoic acids , 1986 .

[3] J. Vollano,et al. Pentacoordinated molecules. 55. Intramolecularly formed pentacoordinated structures of triphenyltin esters of salicylic acid, o-anisic acid, and p-methylthiobenzoic acid , 1984 .

[4] J. Vollano,et al. Pentacoordinated molecules. 54. Pentacoordinated structures of triphenyltin esters of anthranilic acid, o-(dimethylamino)benzoic acid, and p-aminobenzoic acid formed by intramolecular carboxylate group coordination , 1984 .

[5] Edward R. T. Tiekink,et al. Structural chemistry of organotin carboxylates: a review of the crystallographic literature , 1991 .