Production of drinking water from saline water by direct contact membrane distillation (DCMD)

Abstract Nine types of commercially available membranes were used for a DCMD system to investigate the effect of membrane difference on permeation flux and conductivity. Some characteristics such as liquid entry pressure (LEP), contact angle (CA), gas permeability were checked to understand the membranes more comprehensively. Three different depth membrane modules were set up to study the heat and mass transfer process in a DCMD system. The effect of different operation parameters were studied including flow mode, flow rate, temperature, and NaCl concentration. The permeation conductivity values were under 8 μS/cm for all the experimental conditions. With real seawater, the permeate flux dropped from 23.76 L/m 2  h to 14.36 L/m 2  h over one month at the following conditions: hot side inlet temperature of 60 °C, cold side inlet temperature of 20 °C, and hot and cold side flow rate of 0.6 L/min for PTFE pore size 0.22 μm membranes. After cleaning, the membrane successfully reused in the DCMD system. A mathematical model was built to simulate the mass and heat transfer process, and the experimental results agree with the theoretical calculations.

[1]  R. Thiruvenkatachari,et al.  Separation of Water and Nitric Acid with Porous Hydrophobic Membrane by Air Gap Membrane Distillation (AGMD) , 2006 .

[2]  Giulio C. Sarti,et al.  Separation efficiency in vacuum membrane distillation , 1992 .

[3]  Noam Lior,et al.  Membrane-distillation desalination: Status and potential , 2005 .

[4]  Roland Wimmerstedt,et al.  The application of membrane technology in the pulp and paper industry , 1985 .

[5]  L. Martinez-diez,et al.  Desalination of brines by membrane distillation , 2001 .

[6]  M. C. García-Payo,et al.  Separation of binary mixtures by thermostatic sweeping gas membrane distillation: II. Experimental results with aqueous formic acid solutions , 2002 .

[7]  Roland Wimmerstedt,et al.  Membrane distillation - a theoretical study of evaporation through microporous membranes , 1985 .

[8]  M. C. García-Payo,et al.  Separation of binary mixtures by thermostatic sweeping gas membrane distillation: I. Theory and simulations , 2002 .

[9]  Sang Eon Park,et al.  Isotopic water separation using AGMD and VEMD , 2004 .

[10]  C. W. Leung,et al.  Theoretical and experimental studies on air gap membrane distillation , 1998 .

[11]  Giulio C. Sarti,et al.  Extraction of organic components from aqueous streams by vacuum membrane distillation , 1993 .

[12]  Antoni W. Morawski,et al.  Ethanol production in membrane distillation bioreactor , 2000 .

[13]  Antoni W. Morawski,et al.  Membrane distillation of NaCl solution containing natural organic matter , 2001 .

[14]  Jan H. Hanemaaijer Memstill® — low cost membrane distillation technology for seawater desalination , 2004 .

[15]  Fawzi Banat,et al.  Membrane distillation for dilute ethanol: Separation from aqueous streams , 1999 .

[16]  G. Wytze Meindersma,et al.  Modelling temperature and salt concentration distribution in membrane distillation feed channel , 2003 .

[17]  K.S.M.S. Raghavarao,et al.  Membrane distillation for the concentration of raw cane-sugar syrup and membrane clarified sugarcane juice☆ , 2002 .

[18]  Ratana Jiraratananon,et al.  Direct contact membrane distillation: effect of mass transfer on heat transfer , 2001 .

[19]  K. Bani-Melhem,et al.  Sensitivity Analysis of Air Gap Membrane Distillation , 2003 .

[20]  M. Gryta,et al.  Study on the concentration of acids by membrane distillation , 1995 .

[21]  M. Maalej,et al.  Experimental study of air gap and direct contact membrane distillation configurations: application to geothermal and seawater desalination , 2004 .