An excimer-laser-based nanosecond thermal diffusion technique for ultra-shallow pn junction fabrication

Abstract In this paper we review the development of nanosecond thermal diffusion (NTD), a new doping technology which utilizes excimer-laser-induced heating to incorporate and diffuse impurities in silicon wafers. With thermal anneals less than 200 ns in duration, the new laser-based method permits simple, low-temperature fabrication of the ultrashallow p-n junctions necessary for deep-submicrometer MOS and bipolar transistors. In a multifaceted research effort, we are building advanced equipment, developing accurate simulation tools, and designing effective process flows to demonstrate the viability of the NTD technique for manufacturing applications. To date we have fabricated p+-n and n+-p diodes with 300 A junction depth, submicrometer PMOS transistors, and narrow-base regions in bipolar devices. Included in our results are: ultra-shallow diodes with ideality factors of 1.01–1.10 over seven decades of current, reverse leakage currents less than 10 nA/cm2 at 5 V reverse bias, and breakdown voltages in excess of 100 V, MOS devices that demonstrate excellent short channel behavior and no threshold voltage shift at submicrometer gate lengths, and bipolar transistors that incorporate base widths which range from 700 A to 1200 A and exhibit current gains between 50 and 200.

[1]  Eric Fogarassy,et al.  A thermal description of the melting of c- and a-silicon under pulsed excimer lasers , 1989 .

[2]  Laser‐induced melting of predeposited impurity doping technique used to fabricate shallow junctions , 1987 .

[3]  High-performance polysilicon contacted shallow junctions formed by stacked-amorphous-silicon films , 1992, IEEE Electron Device Letters.

[4]  Fred A. Stevie,et al.  Enhanced tail diffusion of ion implanted boron in silicon , 1987 .

[5]  K. Ng,et al.  The impact of intrinsic series resistance on MOSFET scaling , 1986, IEEE Transactions on Electron Devices.

[6]  Kunihiro Suzuki,et al.  Optimum base doping profile for minimum base transit time , 1991 .

[7]  Dim-Lee Kwong,et al.  Silicided shallow junction formation by ion implantation of impurity ions into silicide layers and subsequent drive‐in , 1987 .

[8]  Richard M. Osgood,et al.  Electrical properties of laser chemically doped silicon , 1981 .

[9]  A. Slaoui,et al.  Photoabsorption of BCl3 Gas under pulsed ArF excimer laser irradiation , 1990 .

[10]  Ki-Bum Kim,et al.  Epitaxial GexSi1−x/Si (100) structures produced by pulsed laser mixing of evaporated Ge on Si (100) substrates , 1988 .

[11]  S. Matsumoto,et al.  Precise control of sheet resistance in boron doping of silicon by excimer laser irradiation , 1991, IEEE Electron Device Letters.

[12]  F. Foulon,et al.  Excimer laser induced doping of phosphorus into silicon , 1990 .

[13]  J. Wortman,et al.  Material and electrical properties of ultra-shallow p/sup +/-n junctions formed by low-energy ion implantation and rapid thermal annealing , 1991 .

[14]  M. Law,et al.  Low-temperature annealing of arsenic/phosphorus junctions , 1991 .

[15]  Richard M. Osgood,et al.  Efficient Si solar cells by laser photochemical doping , 1981 .

[16]  Richard B. Fair,et al.  Damage removal/dopant diffusion tradeoffs in ultra-shallow implanted p/sup +/-n junctions , 1990 .

[17]  Ettore Landi,et al.  Numerical simulation of the gas immersion laser doping (GILD) process in silicon , 1988, IEEE Trans. Comput. Aided Des. Integr. Circuits Syst..

[18]  R. F. Wood,et al.  p‐n junction formation in boron‐deposited silicon by laser‐induced diffusion , 1978 .

[19]  Akira Usami,et al.  Shallow-junction formation on silicon by rapid thermal diffusion of impurities from a spin-on source , 1992 .

[20]  P. Carey,et al.  Low-temperature fabrication of p/sup +/-n diodes with 300-AA junction depth , 1992, IEEE Electron Device Letters.

[21]  Friedrich G. Bachmann Excimer Laser Drill for Multilayer Printed Circuit Boards , 1989 .

[22]  R.D. Gardner,et al.  A new approach to optimizing the base profile for high-speed bipolar transistors , 1990, IEEE Electron Device Letters.

[23]  J.L. de Jong,et al.  Thin base formation by double diffused polysilicon technology , 1988, Proceedings of the 1988 Bipolar Circuits and Technology Meeting,.

[24]  Hiroshi Iwai,et al.  Impurity diffusion behavior of bipolar transistor under low-temperature furnace annealing and high-temperature RTA and its optimization for 0.5- mu m Bi-CMOS process , 1992 .

[25]  T. Sigmon,et al.  Thin-base bipolar transistor fabrication using gas immersion laser doping , 1989, IEEE Electron Device Letters.

[26]  R. Fair,et al.  Very shallow p+‐n junction formation by low‐energy BF+2 ion implantation into crystalline and germanium preamorphized silicon , 1988 .

[27]  Fabrication of patterned Gex/Si1−x/Si layers by pulsed laser induced epitaxy , 1991 .

[28]  R. Hodgson,et al.  Time dependence of the reflectivity of Si at 633 and 488 nm during pulsed laser annealing , 1980 .

[29]  J. Narayan,et al.  UV laser incorporation of dopants into silicon: Comparison of two processes , 1985 .

[30]  Structural and Electrical Properties of Gas immersion Laser Doped Layers in Crystalline Silicon , 1983 .

[31]  M. Kase,et al.  Eliminating channeling tail by lower dose preimplantation , 1990 .

[32]  R. Press,et al.  Solar cells made by laser‐induced diffusion directly from phosphine gas , 1981 .