Synthesis of metalloporphyrin-based porous organic polymers and their functionalization for conversion of CO2 into cyclic carbonates: recent advances, opportunities and challenges

This review summarized the recent advances made in the task-specific design and synthesis of metalloporphyrin-based porous organic polymers (POPs) and their functionalization for conversion of CO2 into cyclic carbonates.

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[26]  Huibiao Liu,et al.  Tetrapyrrole macrocycle based conjugated two-dimensional mesoporous polymers and covalent organic frameworks: From synthesis to material applications , 2017, Coordination Chemistry Reviews.

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[29]  Qihua Yang,et al.  Cationic Zn-Porphyrin Immobilized in Mesoporous Silicas as Bifunctional Catalyst for CO2 Cycloaddition Reaction under Cocatalyst Free Conditions , 2018 .

[30]  Jun Luo,et al.  Atomically Dispersed Iron–Nitrogen Active Sites within Porphyrinic Triazine-Based Frameworks for Oxygen Reduction Reaction in Both Alkaline and Acidic Media , 2018 .

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[32]  Qihua Yang,et al.  Cationic Zn-Porphyrin Polymer Coated onto CNTs as a Cooperative Catalyst for the Synthesis of Cyclic Carbonates. , 2018, ACS applied materials & interfaces.

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[37]  Bao-hang Han,et al.  Fluorinated Porous Conjugated Polyporphyrins through Direct C-H Arylation Polycondensation: Preparation, Porosity, and Use as Heterogeneous Catalysts for Baeyer-Villiger Oxidation. , 2017, Chemistry.

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[41]  Li Yan,et al.  State-of-the-Art Multifunctional Heterogeneous POP Catalyst for Cooperative Transformation of CO2 to Cyclic Carbonates , 2017 .

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[43]  Hongbing Ji,et al.  State‐of‐the‐Art Aluminum Porphyrin‐based Heterogeneous Catalysts for the Chemical Fixation of CO2 into Cyclic Carbonates at Ambient Conditions , 2017 .

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[49]  P. Yang,et al.  Covalent organic frameworks comprising cobalt porphyrins for catalytic CO2 reduction in water , 2015, Science.

[50]  P. Feng,et al.  Heterometal‐Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts , 2015, Advanced materials.

[51]  Pingle Liu,et al.  Cycloaddition Reaction of Propylene Oxide and Carbon Dioxide Over NaX Zeolite Supported Metalloporphyrin Catalysts , 2014, Catalysis Letters.

[52]  Shengqian Ma,et al.  Covalent Heme Framework as a Highly Active Heterogeneous Biomimetic Oxidation Catalyst , 2014 .

[53]  Chuande Wu,et al.  Porous metal-organic frameworks for heterogeneous biomimetic catalysis. , 2014, Accounts of chemical research.

[54]  Hong Xia,et al.  A porphyrin-linked conjugated microporous polymer with selective carbon dioxide adsorption and heterogeneous organocatalytic performances , 2014 .

[55]  Dawei Feng,et al.  Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination. , 2013, Journal of the American Chemical Society.

[56]  S. Nguyen,et al.  Enhanced catalytic activity through the tuning of micropore environment and supercritical CO2 processing: Al(porphyrin)-based porous organic polymers for the degradation of a nerve agent simulant. , 2013, Journal of the American Chemical Society.

[57]  Wei-Qiao Deng,et al.  Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer , 2013, Nature Communications.

[58]  H. Kim,et al.  Microporous organic networks bearing metal-salen species for mild CO2 fixation to cyclic carbonates , 2013 .

[59]  Luping Yu,et al.  Nanoporous Porphyrin Polymers for Gas Storage and Separation , 2012 .

[60]  Zhaoqi Guo,et al.  Highly Efficient Activation of Molecular Oxygen with Nanoporous Metalloporphyrin Frameworks in Heterogeneous Systems , 2011, Advanced materials.

[61]  Lei Jiang,et al.  Functional biointerface materials inspired from nature. , 2011, Chemical Society reviews.

[62]  Huanwang Jing,et al.  Synthesis of cyclic carbonate from epoxide and CO2 catalyzed by magnetic nanoparticle-supported porphyrin , 2011 .

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