Nitrogen and Phosphorus Recovery from Human Urine by Struvite Precipitation and Air Stripping in Vietnam

A “No Mix” sanitation system was installed in a dormitory at the University of CanTho in South Vietnam, with the objective of recycling nutrients from source separated wastewater streams. This paper presents the “Yellow Water” treatment plant and its efficiency in recovering phosphorus and nitrogen from human urine. The pilot plant achieved phosphorus removal efficiencies of 98% with both diluted and undiluted urine. Phosphorus was recovered in the form of struvite, a solid mineral fertilizer with heavy metal concentrations being below the German Fertilizer Regulation's threshold limits. About 110 g of struvite could be generated after one treatment cycle, during which 50 L of urine were processed. Nitrogen removal by air stripping showed best results when circulating the urine for 3 h through the stripping column at a high flow rate (80 L/h). With these settings, more than 90% of the nitrogen could be removed from the urine, and virtually 100% of this nitrogen could be recovered in the form of liquid ammonium sulfate. In the future, treatment costs could be further reduced by making use of the solar energy that is available during daytime in South Vietnam.

[1]  Max Maurer,et al.  Struvite precipitation from urine - Influencing factors on particle size. , 2010, Water research.

[2]  A. Sarkar Hydration/dehydration characteristics of struvite and dittmarite pertaining to magnesium ammonium phosphate cement systems , 1991 .

[3]  Max Maurer,et al.  The behaviour of pharmaceuticals and heavy metals during struvite precipitation in urine. , 2007, Water research.

[4]  W. Römer Vergleichende Untersuchungen zur Pflanzenverfügbarkeit von Phosphat aus verschiedenen P‐Recycling‐Produkten im Keimpflanzenversuch , 2006 .

[5]  E. Tilley,et al.  EFFECTS OF STORAGE ON PHOSPHORUS RECOVERY FROM URINE , 2008, Environmental technology.

[6]  Max Maurer,et al.  Struvite precipitation thermodynamics in source-separated urine. , 2007, Water research.

[7]  Willi Gujer,et al.  Estimating the precipitation potential in urine-collecting systems. , 2003, Water research.

[8]  M C M van Loosdrecht,et al.  Phosphate and potassium recovery from source separated urine through struvite precipitation. , 2007, Water research.

[9]  D Mavinic,et al.  RECOVERY OF STRUVITE FROM STORED HUMAN URINE , 2008, Environmental technology.

[10]  Ilhan Talinli,et al.  Recovery of Ammonia from Human Urine by Stripping and Absorption , 2007 .

[11]  Jessica G. Davis,et al.  Effectiveness of Recovered Magnesium Phosphates as Fertilizers in Neutral and Slightly Alkaline Soils , 2009 .

[12]  J Wilsenach,et al.  Impact of separate urine collection on wastewater treatment systems. , 2003, Water science and technology : a journal of the International Association on Water Pollution Research.

[13]  H. Gulyas,et al.  Production of value added products from separately collected urine. , 2002, Water science and technology : a journal of the International Association on Water Pollution Research.

[14]  B. Lind,et al.  Nutrient recovery from human urine by struvite crystallization with ammonia adsorption on zeolite and wollastonite. , 2000 .

[15]  G. Saracco,et al.  High temperature ammonia stripping and recovery from process liquid wastes , 1994 .

[16]  Eva Nilsson,et al.  Recovery of N and P from human urine by freezing, struvite precipitation and adsorption to zeolite and active carbon. , 2007, Bioresource technology.

[17]  G. L. Bridger,et al.  Micronutrient Sources, Metal Ammonium Phosphates as Fertilizers , 1962 .

[18]  Willi Gujer,et al.  Urea hydrolysis and precipitation dynamics in a urine-collecting system. , 2003, Water research.

[19]  A. Mersmann,et al.  Air stripping – a method for treatment of wastewater , 1995 .

[20]  Tove A. Larsen,et al.  Biologically induced precipitation in urine-collecting systems , 2003 .

[21]  César Plaza,et al.  Greenhouse evaluation of struvite and sludges from municipal wastewater treatment works as phosphorus sources for plants. , 2007, Journal of agricultural and food chemistry.

[22]  C. Plaza,et al.  Lettuce Response to Phosphorus Fertilization with Struvite Recovered from Municipal Wastewater , 2009 .

[23]  Natasha Gilbert,et al.  Environment: The disappearing nutrient , 2009, Nature.

[24]  Kwang Victor Lo,et al.  Removal of nitrogen from swine manure wastewaters by ammonia stripping , 1995 .

[25]  A. E. Johnston,et al.  Effectiveness of different precipitated phosphates as phosphorus sources for plants , 2003 .

[26]  J. Clemens,et al.  A tool to evaluate the fertiliser value and the environmental impact of substrates from wastewater treatment. , 2007, Water science and technology : a journal of the International Association on Water Pollution Research.

[27]  August Bonmatí,et al.  Air stripping of ammonia from pig slurry: characterisation and feasibility as a pre- or post-treatment to mesophilic anaerobic digestion. , 2003, Waste Management.

[28]  D S Mavinic,et al.  Thermal decomposition of struvite and its phase transition. , 2008, Chemosphere.