Reactivity of coal gasification with steam and CO2

A description of the main parameters affecting char gasification, as well as an evaluation of the kinetic models used for describing the char gasification reaction, are presented. By reviewing literature on char gasification reactivity it is shown that of all the parameters involved in char gasification, the thermal history of the char, the pore structure and the coal chemical composition are those which present the most different results. The examination of reactive models indicates that their use depends mainly on their purpose in use.

[1]  L. Shufen,et al.  Kinetic studies of a lignite char pressurized gasification with CO2, H2 and steam , 1994 .

[2]  D. D. Perlmutter,et al.  A random pore model for fluid‐solid reactions: I. Isothermal, kinetic control , 1980 .

[3]  K. Raghunathan,et al.  Unification of coal gasification data and its applications , 1989 .

[4]  J. Moulijn,et al.  Nature, activity and stability of active sites during alkali metal carbonate-catalysed gasification reactions of coal char , 1983 .

[5]  J. J. Pis,et al.  Influence of coal oxidation upon char gasification reactivity , 1995 .

[6]  R. L. Taylor,et al.  An update on the carbon-oxygen reaction , 1991 .

[7]  Y. Yang,et al.  Gasification reactivity of some Western Canadian coals , 1994 .

[8]  Kouichi Miura,et al.  Factors affecting the reactivity of coal chars during gasification, and indices representing reactivity , 1989 .

[9]  F. Shadman,et al.  Variation of rate during potassium-catalysed CO2 gasification of coal char , 1984 .

[10]  S. D. Kim,et al.  Catalytic activity of alkali and transition metal salt mixtures for steam-char gasification , 1995 .

[11]  George R. Gavals A Random Capillary Model with Application to Char Gasification at Chemically Controlled Rates , 1980 .

[12]  S. D. Kim,et al.  Catalytic activity of alkali and iron salt mixtures for steam-char gasification , 1993 .

[13]  D. D. Perlmutter,et al.  The effect of pore structure on the char-steam reaction , 1989 .

[14]  T. Kojima,et al.  Prediction of CO2 gasification rate of char in fluidized bed gasifier , 1986 .

[15]  R. T. Yang,et al.  The active surface species in alkali-catalyzed carbon gasification : phenolate (C-O-M) groups vs clusters (particles) , 1993 .

[16]  M. D. Souza-Santos Comprehensive modelling and simulation of fluidized bed boilers and gasifiers , 1989 .

[17]  J. Moulijn,et al.  Towards a unified theory of reactions of carbon with oxygen-containing molecules , 1995 .

[18]  A. Rehmat,et al.  Gasification kinetics of Western Kentucky bituminous coal char , 1989 .

[19]  T. Liliedahl,et al.  Modelling of char-gas reaction kinetics , 1997 .

[20]  Toshimitsu Suzuki,et al.  CO2 Gasification of Iron-Loaded Carbons: Activation of the Iron Catalyst with CO , 1995 .

[21]  K. Hashimoto,et al.  Correlation of gasification rates of various coals measured by a rapid heating method in a steam atmosphere at relatively low temperatures , 1986 .

[22]  Y. Sakata,et al.  Effects of coal carbonization conditions on rate of steam gasification of char , 1987 .

[23]  R. Hurt,et al.  The role of microporous surface area in the gasification of chars from a sub-bituminous coal , 1991 .