Filtration characteristics of polysulfone membrane filters

Abstract Polysulfone (PSF) membrane filters are employed as thermoplastic material in fabricating membranes for use in water ultrafiltration systems and gas separation. However, PSF membrane filters have seldom been used in aerosol filtration. Therefore, this work clarifies the effects of PSF membrane filters on aerosol penetration. Three concentrations of casting solutions (10%, 15%, and 20%) were used to form membranes with the variously sized pores and porosities. The PSL monodisperse aerosols were applied as the challenged aerosols. The aerosol penetration was measured using a condensation particle counter. The effects of various factors, including particle size ( 0.038 – 0.81 μ m ), flow rate (5.2, 10.4, and 15.6 l / min ) and relative humidity (RH 30% and RH 70%) on the aerosol collection characteristics were evaluated. The experimental results implied that 10%, 15%, and 20% PSF membrane filters have different porosities and pressure drops across them were about 4.51, 5.81, and 7.31 kPa . The data obtained herein reveal that the aerosol penetrations of the 0.3 μ m PSL aerosol through the 10%, 15%, and 20% PSF membrane filters were around 7.5%, 3.8%, and 0.9%, respectively. The size of the most penetrating aerosol through the PSF membrane was approximately 0.05 μ m . These results demonstrate that the aerosol penetration through PSF membrane filters declines as the concentration of the casting solution increases, because the pore size inside the PSF membrane filter decreases as the concentration of the casting solution rises. Moreover, aerosol penetration through the PSF membrane filters increases obviously with the flow rate when aerosol is less smaller than 0.21 μ m . When aerosol is greater than 0.3 μ m , variations of penetration through the PSF membrane filters become smaller at different flow rates. The relative humidity does not affect the aerosol penetration through the PSF membrane filters. The 20% PSF membrane filter has a quality factor larger than the 10% and 15% PSF membrane filter over the entire range of aerosol sizes studies.

[1]  G. Belfort,et al.  Photochemical modification of poly(ether sulfone) and sulfonated poly(sulfone) nanofiltration membranes for control of fouling by natural organic matter , 2000 .

[2]  B. Brunekreef,et al.  Interlaboratory comparison of PM10 and black smoke measurements in the peace study , 1997 .

[3]  K. W. Lee,et al.  Efficiency of membrane and nuclepore filters for submicrometer aerosols , 1976 .

[4]  R. Flocchini,et al.  Elemental composition of springtime aerosol in Chillán, Chile , 2004 .

[5]  J. Seinfeld,et al.  Sampling methods used for the collection of particle-phase organic and elemental carbon during ACE-Asia , 2003 .

[6]  M. Smutek,et al.  Impaction of particles on the surface of membrane filters , 1974 .

[7]  R. Sherrell,et al.  Determination of trace elements in filtered suspended marine particulate material by sector field HR-ICP-MS , 2001 .

[8]  Tadashi Shirai,et al.  Chemical Characterization of Particles in Winter-Night Smog in Tokyo , 2002 .

[9]  M. Manton Brownian diffusion of aerosols to the face of a nuclepore filter , 1979 .

[10]  J. Lodge,et al.  Aerosol filtration by means of nuclepore filters : Structural and filtration properties. , 1969 .

[11]  Bert Brunekreef,et al.  Wintertime PM10 and black smoke concentrations across Europe: results from the PEACE study. , 1997 .

[12]  Charles S. McCammon,et al.  Air Sampling Instruments for Evaluation of Atmospheric Contaminants , 1995 .

[13]  G. Summers,et al.  Dipyridyl functionalized polysulfones for membrane production , 2003 .

[14]  G. Belfort,et al.  Photoinduced grafting of ultrafiltration membranes: comparison of poly(ether sulfone) and poly(sulfone) , 2001 .

[15]  M. Manton The impaction of aerosols on a nuclepore filter , 1978 .

[16]  G. Robertson,et al.  Modified polysulfones. IV. Synthesis and characterization of polymers with silicon substituents for a comparative study of gas-transport properties † , 2001 .

[17]  Susanne V. Hering,et al.  Air Sampling Instruments for Evaluation of Atmospheric Contaminants , 1989 .

[18]  P. Koutrakis,et al.  Experimental Investigation of Pressure Drop with Particle Loading in Nuclepore Filters , 1999 .

[19]  M. Fujii,et al.  Time course shift in particle penetration characteristics through capillary pore membrane filters , 2004 .

[20]  Amit Chakma,et al.  Preparation of hollow fiber poly(ether block amide)/polysulfone composite membranes for separation of carbon dioxide from nitrogen , 2004 .

[21]  J. Gentry,et al.  Effect of pore and particle size distribution on efficiencies of membrane filters , 1973 .

[22]  D. Boulaud,et al.  Experimental study on the collection efficiency of membrane filters , 1996 .

[23]  Bao-Ku Zhu,et al.  A study on formation of regular honeycomb pattern in polysulfone film , 2005 .

[24]  David Y. H. Pui,et al.  CHARACTERISTICS OF AIR SAMPLING FILTER MEDIA. , 1983 .

[25]  M. Guiver,et al.  Modified polysulphone membranes: 1. Pervaporation of water/alcohol mixtures through modified polysulphone membranes having methyl ester moiety , 1992 .

[26]  J. Lodge,et al.  Aerosol filtration by means of Nuclepore filters: aerosol sampling and measurement , 1969 .