Portable Thermoelectric Power Generator Based on a Microfabricated Silicon Combustor with Low Resistance to Flow

A portable-scale thermoelectric power generator is designed, fabricated, and tested. The basis of the system is a mesoscale silicon reactor for the combustion of butane over an alumina-supported platinum catalyst. The system is integrated with commercial bismuth telluride thermoelectric modules to produce 5.8 W of electrical power with a chemical-to-electrical conversion efficiency of 2.5% (based on LHV). The energy and power densities of the demonstrated system are 321 W h kg–1 and 17 W kg–1, respectively. The pressure drop through the system is 130 Pa for the highest flow rate used, resulting in a parasitic power requirement for air-pressurization of ∼0.1 W. The demonstration represents an order-of-magnitude improvement in portable-scale electrical power from thermoelectrics and hydrocarbon fuels, and a notable increase in the conversion efficiency compared with previous studies.

[1]  D. Rowe CRC Handbook of Thermoelectrics , 1995 .

[2]  M. Schmidt Wafer-to-wafer bonding for microstructure formation , 1998, Proc. IEEE.

[3]  Xin Zhang,et al.  A six-wafer combustion system for a silicon micro gas turbine engine , 2000, Journal of Microelectromechanical Systems.

[4]  F. Kapteijn,et al.  Zeolite coated structures for the acylation of aromatics , 2001 .

[5]  R. Venkatasubramanian,et al.  Thin-film thermoelectric devices with high room-temperature figures of merit , 2001, Nature.

[6]  R. Yetter,et al.  Development of a microreactor as a thermal source for microelectromechanical systems power generation , 2002 .

[7]  Evan O. Jones,et al.  Microfuel processor for use in a miniature power supply , 2002 .

[8]  Klavs F. Jensen,et al.  A microfabricated suspended-tube chemical reactor for thermally efficient fuel processing , 2003 .

[9]  Erdogan Gulari,et al.  A scalable silicon microreactor for preferential CO oxidation: performance comparison with a tubular packed-bed microreactor , 2004 .

[10]  Yong Wang,et al.  Review of developments in portable hydrogen production using microreactor technology. , 2004, Chemical reviews.

[11]  N. Kasagi,et al.  Development of Micro Catalytic Combustor with Pt/Al2O3 Thin Films , 2004 .

[12]  Dionisios G. Vlachos,et al.  Hydrogen assisted self-ignition of propane/air mixtures in catalytic microburners , 2005 .

[13]  Masayoshi Esashi,et al.  Micro-ejector to supply fuel-air mixture to a micro-combustor , 2005 .

[14]  M. Esashi,et al.  A micro-fuel processor with trench-refilled thick silicon dioxide for thermal isolation fabricated by water-immersion contact photolithography , 2005 .

[15]  M. Esashi,et al.  High-energy density miniature thermoelectric generator using catalytic combustion , 2006, Journal of Microelectromechanical Systems.

[16]  S. Woo,et al.  Performance of microchannel reactor combined with combustor for methanol steam reforming , 2006 .

[17]  N. Kasagi,et al.  Development of a micro catalytic combustor using high-precision ceramic tape casting , 2006 .

[18]  D. G. Norton,et al.  Catalytic microcombustors with integrated thermoelectric elements for portable power production , 2006 .

[19]  Robert F. Richards,et al.  Demonstration of an external combustion micro-heat engine , 2007 .

[20]  V. Hessel,et al.  Low temperature catalytic combustion of propane over Pt-based catalyst with inverse opal microstructure in a microchannel reactor. , 2007, Chemical communications.

[21]  Yei-Chin Chao,et al.  Effects of catalytic walls on hydrogen/air combustion inside a micro-tube , 2007 .

[22]  Dionisios G. Vlachos,et al.  Portable power production from methanol in an integrated thermoeletric/microreactor system , 2008 .

[23]  O. Kwon,et al.  Silicon-based miniaturized reformer with methanol catalytic burner , 2008 .

[24]  D. Vlachos,et al.  Stability and performance of catalytic microreactors: Simulations of propane catalytic combustion on Pt , 2008 .

[25]  Alexander Mitsos,et al.  Designing Man-Portable Power Generation Systems for Varying Power Demand , 2008 .

[26]  Yang Wang,et al.  Combustion of hydrogen–air in catalytic micro-combustors made of different material , 2009 .

[27]  Siti Kartom Kamarudin,et al.  Overview on the application of direct methanol fuel cell (DMFC) for portable electronic devices , 2009 .

[28]  Takenobu Kajikawa,et al.  Approach to the Practical Use of Thermoelectric Power Generation , 2009 .

[29]  B. Zhong,et al.  Hydrogen-assisted catalytic ignition characteristics of different fuels , 2010 .

[30]  Steven G. Johnson,et al.  Design and global optimization of high-efficiency thermophotovoltaic systems. , 2010, Optics express.

[31]  N. Kaisare,et al.  Simulation of hydrogen and hydrogen-assisted propane ignition in Pt catalyzed microchannel , 2010 .

[32]  Benjamin A. Wilhite,et al.  Autothermal hydrogen generation from methanol in a ceramic microchannel network , 2010 .