Comparative study of regulated and unregulated gaseous emissions during NEDC in a light-duty diesel engine fuelled with Fischer Tropsch and biodiesel fuels

In this study, regulated and unregulated gaseous emissions and fuel consumption with five different fuels were tested in a 4-cylinder, light-duty diesel EURO IV typically used for the automotive vehicles in Europe. Three different biodiesel fuels obtained from soybean oil, rapeseed oil and palm oil, a Fischer Tropsch fuel and an ultra low sulphur diesel were studied. The test used was the New European Driving Cycle (NEDC), this allowed tests to be carried out on an engine warmed up beforehand to avoid the effect of cold starts and several tests a day. Regulated emissions of NOX, CO, HC and CO2 were measured for each fuel. Unburned Hydrocarbon Speciation and formaldehyde were also measured in order to determine the maximum incremental reactivity (MIR) of the gaseous emissions. Pollutants were measured without the diesel oxidation catalyst (DOC) to gather data about raw emissions. When biodiesel was used, increases in regulated and unregulated emissions were observed and also significant increases in engine fuel consumption. The use of Fischer Tropsch fuel, however, caused lower regulated and unregulated emissions and fuel consumption than diesel.

[1]  R. Derwent,et al.  Photochemical ozone creation potentials for a large number of reactive hydrocarbons under European conditions , 1996 .

[2]  Célia Regina Pesquero,et al.  Emission of polycyclic aromatic hydrocarbons from light-duty diesel vehicles exhaust , 2004 .

[3]  D. Montalvo,et al.  The Effect of Oxygenated Fuels on Emissions from a Modern Heavy-Duty Diesel Engine , 1993 .

[4]  Tie Li,et al.  Characteristics of Unregulated Toxic Emissions from Ultra-High EGR Low Temperature Diesel Combustion and Effects of Exhaust Catalysts , 2007 .

[5]  Claudio Bertoli,et al.  Evaluation of Combustion Behavior and Pollutants Emission of Advanced Fuel Formulations by Single Cylinder Engine Experiments , 1998 .

[6]  Georgios Karavalakis,et al.  Regulated and unregulated emissions of a light duty vehicle operated on diesel/palm-based methyl ester blends over NEDC and a non-legislated driving cycle , 2009 .

[7]  Sergio Machado Corrêa,et al.  Carbonyl emissions in diesel and biodiesel exhaust. , 2008 .

[8]  Hsi-Hsien Yang,et al.  Effects of the biodiesel blend fuel on aldehyde emissions from diesel engine exhaust , 2008 .

[9]  Zuohua Huang,et al.  Experimental investigation on regulated and unregulated emissions of a diesel engine fueled with ultra-low sulfur diesel fuel blended with biodiesel from waste cooking oil. , 2009, The Science of the total environment.

[10]  J. Arregle,et al.  Procedure for engine transient cycle emissions testing in real time , 2006 .

[11]  Juan J. Hernández,et al.  Speciation of the semivolatile hydrocarbon engine emissions from sunflower biodiesel , 2008 .

[12]  T J Wallington,et al.  Automotive fuels and internal combustion engines: a chemical perspective. , 2006, Chemical Society reviews.

[13]  Octavio Armas,et al.  Effect of biodiesel fuels on diesel engine emissions , 2008 .

[14]  Jin Kusaka,et al.  Experimental study on unregulated emission characteristics of turbocharged DI diesel engine with common rail fuel injection system , 2003 .

[15]  Bernardo Tormos,et al.  Comparative analysis of a DI diesel engine fuelled with biodiesel blends during the European MVEG-A cycle: Performance and emissions (II) , 2009 .

[16]  Manfred Baerns,et al.  Basic principles in applied catalysis , 2004 .

[17]  B. Buchholz,et al.  A Numerical Investigation into the Anomalous Slight NOx Increase when Burning Biodiesel: A New (Old) Theory , 2007 .

[18]  Juhun Song,et al.  Effect of Oxygenated Fuel on Combustion and Emissions in a Light-Duty Turbo Diesel Engine , 2002 .

[19]  E. Zervas Regulated and non-regulated pollutants emitted from two aliphatic and a commercial diesel fuel , 2008 .

[20]  M. Duncan,et al.  Carcinogenic Hydrocarbons and Human Cells in Culture , 1971, Nature.

[21]  E. Zervas,et al.  Emission of alcohols and carbonyl compounds from a spark ignition engine. Influence of fuel and air/fuel equivalence ratio. , 2002, Environmental science & technology.

[22]  Bernardo Tormos,et al.  Hydrocarbon emissions speciation in diesel and biodiesel exhausts , 2009 .