Size, structure and dynamics of “large” bubbles in a two-dimensional slurry bubble column

Abstract This paper reports preliminary results of a study on the hydrodynamics of a two-dimensional slurry bubble column. Experiments have been carried out with air/paraffin oil slurries with solids concentrations of 0, 28.3 and 38.6 vol% of porous silica particles (mean diameter of 38 μm). Bubble sizes, bubble coalescence and bubble break-up rates were determined by video image analysis. Increasing slurry concentration increases the size and size distribution of the “large” bubbles, defined here as having diameters larger than 10 mm. Increasing slurry concentration reduces the total gas holdup to a significant extent; this reduction is to be largely attributed to the destruction of the “small” bubble population, which have bubble diameters smaller than 10 mm. Video imaging experiments lead to new insights into the mass transfer mechanisms from “large” bubbles. These “large” bubbles are continually coalescing and breaking up. The coalescence and breakup rates were determined by a frame-by-frame analysis of the video recordings and found to be at least 4 s −1 . A population model for mass transfer has been set up and used to establish that frequent bubble-bubble interactions could lead to an order of magnitude increase in the mass transfer rates for the large bubble class.

[1]  K. Muroyama,et al.  PROPERTIES OF BUBBLE SWARM IN A SLURRY BUBBLE COLUMN , 1987 .

[2]  Robert W. Field,et al.  Bubble Column Reactors , 1991 .

[3]  S. C. Saxena,et al.  Bubble column reactors and Fischer-Tropsch synthesis , 1995 .

[4]  K. Koide,et al.  GAS HOLDUP AND VOLUMETRIC LIQUID-PHASE MASS TRANSFER COEFFICIENT IN SOLID-SUSPENDED BUBBLE COLUMNS , 1984 .

[5]  Wolf-Dieter Deckwer,et al.  Hydrodynamic Properties of the Fischer-Tropsch Slurry Process , 1980 .

[6]  R. Krishna,et al.  Influence of Particles Concentration on the Hydrodynamics of Bubble-Column Slurry Reactors , 1995 .

[7]  A. Schumpe,et al.  Gas/liquid mass transfer in a slurry bubble column , 1987 .

[8]  J. Fox Fischer-Tropsch reactor selection , 1990 .

[9]  K. Lunde,et al.  A Method for the Detailed Study of Bubble Motion and Deformation , 1995 .

[10]  John R. Grace,et al.  Effect of bubble interaction on interphase mass transfer in gas fluidized beds , 1981 .

[11]  B. G. Kelkar,et al.  Hydrodynamics and axial mixing in a three-phase bubble column. Effects of slurry properties , 1984 .

[12]  B. G. Kelkar,et al.  Hydrodynamics and axial mixing in a three-phase bubble column , 1982 .

[13]  Rajamani Krishna,et al.  A unified approach to the scale-up of gas—solid fluidized bed and gas—liquid bubble column reactors , 1994 .

[14]  C. W. Stewart Bubble interaction in low-viscosity liquids , 1996 .

[15]  Andrew K. C. Wong,et al.  A new method for gray-level picture thresholding using the entropy of the histogram , 1985, Comput. Vis. Graph. Image Process..

[16]  S. T. Sie,et al.  Selection, design and scale up of the Fischer-Tropsch reactor , 1997 .

[17]  B. Jager,et al.  Advances in low temperature Fischer-Tropsch synthesis , 1995 .

[18]  Snehal A. Patel,et al.  HYDRODYNAMIC STUDIES IN FISCHER-TROPSCH DERIVED WAXES IN A BUBBLE COLUMN , 1987 .

[19]  R. Krishna,et al.  Hydrodynamics and mass transfer in bubble columns in operating in the churn-turbulent regime , 1981 .

[20]  A. Schumpe,et al.  Improved tools for bubble column reactor design and scale-up☆ , 1993 .

[21]  Katsuhiko Muroyama,et al.  MEASUREMENT OF BEHAVIOR OF GAS BUBBLES AND GAS HOLDUP IN A SLURRY BUBBLE COLUMN BY A DUAL ELECTRORESISTIVITY PROBE METHOD , 1986 .