论文信息 - First- and second-sphere co-ordination of a lanthanum cation by acalix[4]arene tetraamide in the partial-cone conformation

First- and second-sphere co-ordination of a lanthanum cation by acalix[4]arene tetraamide in the partial-cone conformation

5,11,17,23-Tetra-tert -butyl-25,26,27,28-tetrakis(diethylcarbamoylmethoxy)calix[4]arene (L) has been synthesized in the partial-cone conformation for the first time. Reaction with lanthanum picrate (2,4,6-trinitrophenolate) gives a 1∶1 complex which has been structurally characterised: [LaL(pic) 3 (H 2 O) 2 ]·3H 2 O·MeCN (triclinic, space group P, Z = 2, R = 0.087 for 10 150 independent reflections above background). The metal–calixarene interactions involve two amide oxygen atoms in the first co-ordination sphere and three oxygen atoms (two ether and one amide) in the second. The remainder of the first co-ordination sphere of the nine-co-ordinate lanthanum cation consists of two water oxygen atoms and oxygen atoms of the three picrate anions.

P. Beer | M. Drew | M. Ogden

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