Bottom-up approach to engineer a molybdenum-doped covalent-organic framework catalyst for selective oxidation reaction

We synthesized a readily accessible molybdenum-doped covalent-organic framework catalyst (Mo-COF) linked by a hydrazine linkage via a facile two-step bottom-up approach. This Mo-COF catalyst, as an open nanochannel-reactor, exhibited promising catalytic activity for the selective oxidation reaction.

[1]  M. Bagherzadeh,et al.  Immobilization of dioxomolybdenum(VI) complex bearing salicylidene 2-picoloyl hydrazone on chloropropyl functionalized SBA-15: A highly active, selective and reusable catalyst in olefin epoxidation , 2014 .

[2]  Abdolreza Rezaeifard,et al.  Economical Oxygenation of Olefins and Sulfides Catalyzed by New Molybdenum(VI) Tridentate Schiff Base Complexes: Synthesis and Crystal Structure , 2012 .

[3]  G. Fortunato,et al.  Molybdenum-Pterin Chemistry. 3. Use of X-ray Photoelectron Spectroscopy To Assign Oxidation States in Metal Complexes of Noninnocent Ligands , 1999 .

[4]  Banglin Chen,et al.  Highly efficient C-H oxidative activation by a porous Mn(III) -porphyrin metal-organic framework under mild conditions. , 2013, Chemistry.

[5]  C. G. Young,et al.  New insights into the Berg-Holm oxomolybdoenzyme model , 1999 .

[6]  S. Deng,et al.  Selective CO2 capture in an imine linked porphyrin porous polymer , 2013 .

[7]  Liuyi Li,et al.  Urea-based porous organic frameworks: effective supports for catalysis in neat water. , 2014, Chemistry.

[8]  Yanyan Zhang,et al.  Aerobic selective oxidation of benzyl alcohols to benzaldehyde catalyzed by bidentate Schiff base dioxomolybdenum(VI) complex immobilized on CPS microspheres , 2012 .

[9]  R. Banerjee,et al.  Construction of crystalline 2D covalent organic frameworks with remarkable chemical (acid/base) stability via a combined reversible and irreversible route. , 2012, Journal of the American Chemical Society.

[10]  Yuan Zhang,et al.  Construction of covalent organic framework for catalysis: Pd/COF-LZU1 in Suzuki-Miyaura coupling reaction. , 2011, Journal of the American Chemical Society.

[11]  A. Valente,et al.  Dioxomolybdenum(VI) Epoxidation Catalyst Supported on Mesoporous Silica Containing Phosphane Oxide Groups , 2010 .

[12]  S. Tangestaninejad,et al.  MoO2(acac)2 supported on multi-wall carbon nanotubes: Highly efficient and reusable catalysts for alkene epoxidation with tert-BuOOH , 2012 .

[13]  Weijie Zhang,et al.  Selective oxidation over a metalloporphyrinic metal–organic framework catalyst and insights into the mechanism of bicarbonate ion as co-catalyst , 2014 .

[14]  Zehui Zhang,et al.  Aerobic oxidation of biomass derived 5-hydroxymethylfurfural into 5-hydroxymethyl-2-furancarboxylic acid catalyzed by a montmorillonite K-10 clay immobilized molybdenum acetylacetonate complex , 2014 .

[15]  R. Banerjee,et al.  Mechanochemical synthesis of chemically stable isoreticular covalent organic frameworks. , 2013, Journal of the American Chemical Society.

[16]  Michael O'Keeffe,et al.  Porous, Crystalline, Covalent Organic Frameworks , 2005, Science.

[17]  Wei Wang,et al.  Covalent organic frameworks (COFs): from design to applications. , 2013, Chemical Society reviews.

[18]  W. Wang,et al.  Covalent organic frameworks. , 2012, Chemical Society reviews.

[19]  J. Ziółkowski,et al.  Molybdenum complex-catalysed epoxidation of unsaturated fatty acids by organic hydroperoxides , 2003 .

[20]  Xiong Chen,et al.  Towards covalent organic frameworks with predesignable and aligned open docking sites. , 2014, Chemical communications.

[21]  A. Adesina,et al.  Improved alkene selectivity in carbon monoxide hydrogenation over silica supported cobalt-molybdenum catalyst , 1994 .

[22]  M. Maurya.  Catalytic Applications of Polymer-Supported Molybdenum Complexes in Organic Transformations , 2012 .

[23]  J. Simpson,et al.  Synthesis, crystal structure and catalytic activity of a new Mo Schiff base complex with Mo histidine immobilized on Al-MCM-41 for oxidation of sulfides , 2014 .

[24]  Robert Huber,et al.  Crystal Structure of the Xanthine Oxidase-Related Aldehyde Oxido-Reductase from D. gigas , 1995, Science.