Time series analysis of water quality data from Lake Ontario: implications for the measurement of water quality in large and small lakes

SUMMARY 1. The normal strategy of monitoring water quality is to sample such parameters as chlorophyll no more than weekly. A preferable strategy is to first define the natural periodicities in the water body and then to set up a sampling scheme that takes into account the natural scales of variance in physical, chemical and biological parameters. Failure to do so leads to aliased and biased estimates of means and variances and an inability to interpret the underlying physical and biological mechanisms. 2. The natural scales of variance vary with basin size. In lakes, physical and biological processes overlap at scales of from 1 to 15 days. Time series analysis of daily data from Lake Ontario and other lakes showed how the means and variances of the data sets were determined by the physical and biological processes in the water columns and displayed the fundamental lags in the systems. Even in small lakes and reservoirs, advective processes were of great importance. Advection became the dominant process in Lake Ontario. Time lags and advection made simple correlations of physical and biological parameters meaningless. 3. Decimation of the daily data sets revealed the statistical dangers of less frequent sampling. The desirable frequency of sampling was shown to be a function of the physics of the mixed layer, the turnover times of the nutrient pools, and the biological activity. Data from the three lakes graphically demonstrated the inadequacy of normal sampling frequencies.

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