Sulphate attack and ettringite formation in the lime and cement stabilized marine clays

Swelling and shrinkage behaviour of marine clays impose foundation problems that may sometimes results in excessive settlements. Improving the behaviour of soft clays using lime or cement is not new. Recent studies reported the occurrence of high swelling and pavement failures in lime and cement stabilized clays containing sulphates. The above phenomena resulted in the formation of swelling minerals such as ettringite and thaumasite. In this paper, the earlier reported case histories of sulphate attack in lime and cement stabilized clays have been reviewed, and a list of precautionary measures to be adopted for controlling the ettringite formation have been suggested. An attempt has been made to investigate the application of deep lime mixing technique in sulphate enriched marine clays. Physico-chemical and engineering properties of the lime treated clays containing ettringite have been examined. Test results indicate that lime and cement stabilization techniques should be cautiously approached in sulphate enriched clays.

[1]  S. Wild,et al.  Effects of partial substitution of lime with ground granulated blast furnace slag (GGBS) on the strength properties of lime-stabilised sulphate-bearing clay soils , 1998 .

[2]  Caner Zanbak,et al.  Geochemical and Engineering Aspects of Anhydrite/Gypsum Phase Transitions , 1986 .

[3]  D. Roy,et al.  C4A3S hydration, ettringite formation, and its expansion mechanism: II. Microstructural observation of expansion , 1982 .

[4]  P. Sherwood,et al.  SOIL STABILIZATION WITH CEMENT AND LIME , 1993 .

[5]  P. K. Mehta Effect of Lime on Hydration of Pastes Containing Gypsum and Calcium Aluminates or Calcium Sulfoaluminate , 1973 .

[6]  G. Rajasekaran,et al.  REACTION PRODUCTS FORMED IN LIME-STABILIZED MARINE CLAYS , 1996 .

[7]  Wayne A Dunlap,et al.  United States Air Force Soil Stabilization Index System - A Validation , 1975 .

[8]  A. Neville Properties of Concrete , 1968 .

[9]  S. Wild,et al.  Effects of monovalent and divalent metal sulphates on consistency and compaction of lime-stabilised kaolinite , 1999 .

[10]  N. Bolan,et al.  Effect of liming and phosphate additions on sulphate leaching in soils , 1988 .

[11]  G H McClellan,et al.  IMPROVED CHARACTERISTICS IN SULFATE SOILS TREATED WITH BARIUM COMPOUNDS BEFORE LIME STABILIZATION , 1991 .

[12]  J. Bijen,et al.  Blast furnace slag cement for durable marine structures , 1996 .

[13]  C. Smith,et al.  Effect of surface applications of lime, gypsum and phosphogypsum on the alleviating of surface and subsurface acidity in a soil under pasture , 1994 .

[14]  S. Nagataki,et al.  Expansive admixtures (mainly ettringite) , 1998 .

[15]  T W Lambe,et al.  RECENT SOIL-LIME RESEARCH AT THE MASSACHUSETTS INSTITUTE OF TECHNOLOGY , 1960 .

[16]  S. Wild,et al.  Suppression of swelling associated with ettringite formation in lime stabilized sulphate bearing clay soils by partial substitution of lime with ground granulated blastfurnace slag (GGBS) , 1999 .

[17]  D. Roy,et al.  Early activation and properties of slag cement , 1990 .

[18]  Masashi Kamon,et al.  Combining Industrial Wastes with Lime for Soil Stabilization , 1991 .

[19]  Michael Gasser,et al.  Mechanism of Sulfate Expansion in Hydrated Portland Cement , 1988 .

[20]  内川 浩,et al.  Influence of Character of Blending Component on the Diffusion of Na and Cl ions in Hardened Blended Cement Paste , 1987 .

[21]  P. K. Mehta Mechanism of sulfate attack on portland cement concrete — Another look , 1983 .

[22]  Raymond N. Yong,et al.  Soil Properties and Behaviour , 1975 .

[23]  J. A. Little,et al.  Effect of temperature on lime-soil stabilization , 1992 .

[24]  S. Wild,et al.  Sulphate Expansion of Lime-Stabilized Kaolinite: II. Reaction Products and Expansion , 1993, Clay Minerals.

[25]  R. F. Sorsbie,et al.  Geology for Engineers , 1911, Nature.

[26]  E. Kishar,et al.  Studies on the stability of the calcium sulfoaluminate hydrates. Part 1: Effect of temperature on the stability of ettringite in pure water , 1985 .

[27]  R. Yong,et al.  Particle Interaction and Rheology of Illite-Iron Oxide Complexes , 1991 .

[28]  J. Speight The chemistry and physics of coking , 1998 .

[29]  Serge Leroueil,et al.  Liquid limits and fall cones , 1996 .

[30]  R. H. Rogue,et al.  Hydration of Portland Cement Compounds , 1934 .

[31]  G. Holm,et al.  Improving lime column strength with gypsum , 1983 .

[32]  O. Al-Amoudi,et al.  Expansive characteristics of gypsiferous/anhydritic soil formations , 1998 .

[33]  Edgardo F. Irassar,et al.  ETTRINGITE FORMATION IN LOW C3A PORTLAND CEMENT EXPOSED TO SODIUM SULFATE SOLUTION , 1997 .

[34]  Raymond S. Rollings,et al.  SULFATE ATTACK ON CEMENT-STABILIZED SAND , 2000 .

[35]  R. Yong,et al.  Biochemical Alteration and Heave of Black Shale; Detailed Observations and Interpretations , 1973 .

[36]  G. Rajasekaran,et al.  Lime Stabilization Technique for the Improvement of Marine Clay. , 1997 .

[37]  G. Rajasekaran,et al.  Microfabric, chemical and mineralogical study of indian marine clays , 1998 .

[38]  P. Fookes Middle East—Inherent Ground Problems , 1978, Quarterly Journal of Engineering Geology.

[39]  H. Taylor,et al.  Microstructural and microanalytical studies of sulfate attack. V. Comparison of different slag blends , 1996 .

[40]  S. Wild,et al.  Sulphate Expansion of Lime-Stabilized Kaolinite: I. Physical Characteristics , 1993, Clay Minerals.

[41]  R. B. Robinson,et al.  Effects of Ground Granulated Blast Furnace Slag (GGBS) on the Strength and Swelling Properties of Lime-Stabilized Kaolinite in the Presence of Sulphates , 1996, Clay Minerals.

[42]  A. B. Hawkins,et al.  Sulphate analysis on black mudstones , 1987 .

[43]  G. Rajasekaran,et al.  PARTICLE SIZE ANALYSIS OF LIME-TREATED MARINE CLAYS , 1998 .

[44]  J. Bensted Thaumasite — background and nature in deterioration of cements, mortars and concretes , 1999 .

[45]  Raymond S. Rollings,et al.  Geotechnical Materials in Construction , 1995 .

[46]  James K. Mitchell,et al.  Practical problems from surprising soil behavior , 1986 .

[47]  R. Grim,et al.  REACTION OF HYDRATED LIME WITH PURE CLAY MINERALS IN SOIL STABILIZATION , 1960 .

[48]  A. B. Hawkins,et al.  Cause and significance of heave at Llandough Hospital, Cardiff—a case history of ground floor heave due to gypsum growth , 1987, Quarterly Journal of Engineering Geology.

[49]  D. Hunter Lime-Induced Heave in Sulfate-Bearing Clay Soils , 1988 .

[50]  P. K. Mehta Mechanism of expansion associated with ettringite formation , 1973 .

[51]  Jamal M. Khatib,et al.  Factors influencing strength development of concrete containing silica fume , 1995 .

[52]  Marshall R Thompson,et al.  Lime Reactivity of Illinois Soils , 1966 .