Heavily tellurium doped n-type InGaAs grown by MOCVD on 300 mm Si wafers

Abstract Tellurium has several remarkable properties that make it an attractive n-type dopant in III–V semiconductors, namely high incorporation and activation efficiency resulting in high achievable doping levels in combination with a low diffusion coefficient. However, it suffers from a strong memory effect related to its surfactant behavior that inhibits sharp junction interface formation. We report Te-doped In 0.53 Ga 0.47 As with an electron density of 8×10 19  cm −3 . The layers were grown by MOCVD on 300 mm Si wafers and were characterized by SIMS, XRD, Hall effect, and sheet resistivity mapping. The high active electron density and the excellent uniformity over the wafer surface make this process promising for selective regrowth of highly doped source and drain in VLSI.

[1]  G. B. Stringfellow Organometallic Vapor-Phase Epitaxy: Theory and Practice , 1989 .

[2]  M. Panish,et al.  Sn incorporation into InP grown by molecular beam epitaxy: A secondary‐ion mass spectrometry study , 1990 .

[3]  L $_{\mathrm {g}} = 80$ -nm Trigate Quantum-Well In0.53Ga0.47As Metal–Oxide–Semiconductor Field-Effect Transistors With Al2O3/HfO2 Gate-Stack , 2015, IEEE Electron Device Letters.

[4]  L. Lou,et al.  Hall effect and resistivity in liquid‐phase‐epitaxial layers of HgCdTe , 1984 .

[5]  H. Tsuchiya,et al.  Role of Carrier Transport in Source and Drain Electrodes of High-Mobility MOSFETs , 2010, IEEE Electron Device Letters.

[6]  R. D. Dupuis,et al.  Heavily‐doped n‐type InP and InGaAs grown by metalorganic chemical vapor deposition using tetraethyltin , 1990 .

[7]  Carlos Algora,et al.  Analysis of tellurium as n-type dopant in GaInP: Doping, diffusion, memory effect and surfactant properties , 2007 .

[8]  H. Lüth,et al.  Te doping of GaAs using diethyl‐tellurium , 1994 .

[9]  G. B. Stringfellow,et al.  Influence of tellurium doping on step bunching of GaAs(001) vicinal surfaces grown by organometallic vapor phase epitaxy , 1998 .

[10]  Mark J. W. Rodwell,et al.  High doping effects on in-situ Ohmic contacts to n-InAs , 2010, 2010 22nd International Conference on Indium Phosphide and Related Materials (IPRM).

[11]  V. Aimez,et al.  Inhibition of Te surfactant effect on surface morphology of heavily Te-doped GaAs , 2013 .

[12]  A. Paranjpe,et al.  Tellurium doping of InGaP for tunnel junction applications in triple junction solar cells , 2011 .

[13]  Y. Yeo,et al.  Toward Conformal Damage-Free Doping With Abrupt Ultrashallow Junction: Formation of Si Monolayers and Laser Anneal as a Novel Doping Technique for InGaAs nMOSFETs , 2014, IEEE Transactions on Electron Devices.

[14]  John E. Ayers,et al.  The measurement of threading dislocation densities in semiconductor crystals by X-ray diffraction , 1994 .

[15]  M. Rodwell,et al.  Co-doping of InxGa1−xAs with silicon and tellurium for improved ultra-low contact resistance , 2013 .

[16]  A. Hikavyy,et al.  Advancing CMOS beyond the Si roadmap with Ge and III/V devices , 2011, 2011 International Electron Devices Meeting.

[17]  I. Rey‐Stolle,et al.  Te doping of GaAs using metalorganic vapor phase epitaxy: Volatile versus nonvolatile behavior , 2008 .

[18]  M. J. Manfra,et al.  20–80nm Channel length InGaAs gate-all-around nanowire MOSFETs with EOT=1.2nm and lowest SS=63mV/dec , 2012, 2012 International Electron Devices Meeting.

[19]  J. Alamo Nanometre-scale electronics with III–V compound semiconductors , 2011, Nature.

[20]  P. Y. Hung,et al.  Ultra low contact resistivity (< 1×10−8 Ω-cm2) to In0.53Ga0.47As fin sidewall (110)/(100) surfaces: Realized with a VLSI processed III–V fin TLM structure fabricated with III–V on Si substrates , 2014, 2014 IEEE International Electron Devices Meeting.

[21]  Mark J. W. Rodwell,et al.  InP Bipolar ICs: Scaling Roadmaps, Frequency Limits, Manufacturable Technologies , 2008, Proceedings of the IEEE.

[22]  James W. Mayer,et al.  Electronic Materials Science: For Integrated Circuits in Si and GaAS , 1989 .

[23]  G. Dewey,et al.  Electrostatics improvement in 3-D tri-gate over ultra-thin body planar InGaAs quantum well field effect transistors with high-K gate dielectric and scaled gate-to-drain/gate-to-source separation , 2011, 2011 International Electron Devices Meeting.

[24]  K. Lau,et al.  Material and Device Characteristics of Metamorphic ${\rm In}_{0.53}{\rm Ga}_{0.47}{\rm As}$ MOSHEMTs Grown on GaAs and Si Substrates by MOCVD , 2013, IEEE Transactions on Electron Devices.

[25]  G. Dewey,et al.  III–V field effect transistors for future ultra-low power applications , 2012, 2012 Symposium on VLSI Technology (VLSIT).