Direct printing of reduced graphene oxide on planar or highly curved surfaces with high resolutions using electrohydrodynamics.

Electrohydrodynamic inkjet printing of reduced graphene oxide (RGO) is de-monstrated to form complex geometric devices with high resolution (line width ≈ 5 mm). Both planar and highly curved surfaces (radius of curvature ≈ 60 mm) can be used as substrates. Demonstrations of counterfeit coin recognition using RGO patterns and all-printed RGO transistors suggest substantial promise for applications in security and electronics.

[1]  R. Ruoff,et al.  All-organic vapor sensor using inkjet-printed reduced graphene oxide. , 2010, Angewandte Chemie.

[2]  Yongsheng Chen,et al.  Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors , 2011 .

[3]  Wolfgang Kowalsky,et al.  Large Area Electronics Using Printing Methods , 2005, Proceedings of the IEEE.

[4]  SUPARNA DUTTASINHA,et al.  Graphene: Status and Prospects , 2009, Science.

[5]  Jeffrey Bokor,et al.  Ultra-high-resolution monolithic thermal bubble inkjet print head , 2007 .

[6]  C. Berger,et al.  Epitaxial graphene , 2007, 0704.0285.

[7]  Junyong Kang,et al.  Oxidation resistance of graphene-coated Cu and Cu/Ni alloy. , 2011, ACS nano.

[8]  M. Hersam,et al.  Inkjet Printing of High Conductivity, Flexible Graphene Patterns. , 2013, The journal of physical chemistry letters.

[9]  V. Subramanian,et al.  Inkjet-printed line morphologies and temperature control of the coffee ring effect. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[10]  Y. Jung,et al.  Uniform graphene quantum dots patterned from self-assembled silica nanodots. , 2012, Nano letters.

[11]  Jong-Hyun Ahn,et al.  Extremely efficient flexible organic light-emitting diodes with modified graphene anode , 2012, Nature Photonics.

[12]  Zhenan Bao,et al.  Thin Film Deposition, Patterning, and Printing in Organic Thin Film Transistors , 2004 .

[13]  John A Rogers,et al.  Nanoscale, electrified liquid jets for high-resolution printing of charge. , 2010, Nano letters.

[14]  S. Magdassi,et al.  Conductive nanomaterials for printed electronics. , 2014, Small.

[15]  Hong-Bo Sun,et al.  Direct imprinting of microcircuits on graphene oxides film by femtosecond laser reduction , 2010 .

[16]  J. Coleman,et al.  High-yield production of graphene by liquid-phase exfoliation of graphite. , 2008, Nature nanotechnology.

[17]  Hong Kyoon Choi,et al.  Scaling laws for jet pulsations associated with high-resolution electrohydrodynamic printing , 2008 .

[18]  C. Granqvist Transparent conductors as solar energy materials: A panoramic review , 2007 .

[19]  M. in het Panhuis,et al.  Inkjet printing of transparent, electrically conducting single-walled carbon-nanotube composites. , 2007, Small.

[20]  A. Ferrari,et al.  Inkjet-printed graphene electronics. , 2011, ACS nano.

[21]  John A Rogers,et al.  High-resolution electrohydrodynamic jet printing. , 2007, Nature materials.

[22]  M. L. Curri,et al.  Inkjet-printed multicolor arrays of highly luminescent nanocrystal-based nanocomposites. , 2009, Small.

[23]  G. Privitera,et al.  Solution‐phase exfoliation of graphite for ultrafast photonics , 2010 .

[24]  Colin Nuckolls,et al.  Jet-printed electrodes and semiconducting oligomers for elaboration of organic thin-film transistors , 2006 .

[25]  Qiyuan He,et al.  Graphene-based materials: synthesis, characterization, properties, and applications. , 2011, Small.

[26]  John A Rogers,et al.  Ultrathin silicon solar microcells for semitransparent, mechanically flexible and microconcentrator module designs. , 2008, Nature materials.

[27]  Chang Liu,et al.  A review of carbon nanotube- and graphene-based flexible thin-film transistors. , 2013, Small.

[28]  J. Jang,et al.  Micropatterning of Graphene Sheets by Inkjet Printing and Its Wideband Dipole‐Antenna Application , 2011, Advanced materials.

[29]  Kwang S. Kim,et al.  Large-scale pattern growth of graphene films for stretchable transparent electrodes , 2009, Nature.

[30]  Charles M. Lieber,et al.  Synthesis of monolithic graphene-graphite integrated electronics. , 2012, Nature materials.

[31]  Yongsheng Chen,et al.  An overview of the applications of graphene-based materials in supercapacitors. , 2012, Small.

[32]  C. Dimitrakopoulos,et al.  100-GHz Transistors from Wafer-Scale Epitaxial Graphene , 2010, Science.

[33]  M. El‐Kady,et al.  Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage , 2013, Nature Communications.

[34]  Klaus Müllen,et al.  Patterned Graphene Electrodes from Solution‐Processed Graphite Oxide Films for Organic Field‐Effect Transistors , 2009 .

[35]  Yong‐Lai Zhang,et al.  Bandgap Tailoring and Synchronous Microdevices Patterning of Graphene Oxides , 2012 .

[36]  Li Shi,et al.  Two-Dimensional Phonon Transport in Supported Graphene , 2010, Science.

[37]  Lei Zhang,et al.  Inkjet Printing High‐Resolution, Large‐Area Graphene Patterns by Coffee‐Ring Lithography , 2012, Advanced materials.

[38]  Andreas Sandström,et al.  Printed Electronics: Inkjet Printed Bilayer Light‐Emitting Electrochemical Cells for Display and Lighting Applications (Small 20/2014) , 2014 .

[39]  Kian Ping Loh,et al.  High mobility, printable, and solution-processed graphene electronics. , 2010, Nano letters.

[40]  J. Kysar,et al.  Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene , 2008, Science.

[41]  Michael G. Spencer,et al.  Thickness Estimation of Epitaxial Graphene on SiC Using Attenuation of Substrate Raman Intensity , 2009 .

[42]  Yong‐Lai Zhang,et al.  Photoreduction of Graphene Oxides: Methods, Properties, and Applications , 2014 .

[43]  H W Li,et al.  Dewetting of conducting polymer inkjet droplets on patterned surfaces , 2004, Nature materials.

[44]  Andreas Sandström,et al.  Inkjet printed bilayer light-emitting electrochemical cells for display and lighting applications. , 2014, Small.

[45]  S. Bauer,et al.  Organic Nonvolatile Memory Transistors for Flexible Sensor Arrays , 2009, Science.

[46]  John A Rogers,et al.  Micro- and nanopatterning techniques for organic electronic and optoelectronic systems. , 2007, Chemical reviews.

[47]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.