论文信息 - Characterisation of two different mixed-valence states in a strongly interacting dimolybdenum complex

Characterisation of two different mixed-valence states in a strongly interacting dimolybdenum complex

The pyrazine-bridged bimetallic complex [{Mo(NO)[HB(dmpz) 3 ]Br} 2 (µ-pz)] z [HB(dmpz) 3 = tris(3,5-dimethylpyrazolyl)borate] exists within a five-membered electron-transfer chain where z = -2, -1, 0, +1 and +2; the mixed-valence species with z = -1 is delocalised on the EPR and IR spectroscopic timescales whereas that with z = +1 is valence-trapped.

M. Ward | J. McCleverty | Andrzej Wlodarczyk | J. Maher | G. A. Doyle

[1] M. Ward,et al. Effects of Systematic Variation in Bridging Ligand Structure on the Electrochemical and Magnetic Properties of a Series of Dinuclear Molybdenum Complexes. , 1996, Inorganic chemistry.

[2] W. Kaim,et al. Electronic Structure of the 16 Valence Electron Fragments M(CO)3(PR3)2 (M = Mo, W; R = iPr, Cy) in Their Complexes with H2, THF, and Three .pi.-Conjugated Dinucleating Ligands: Electrochemistry and Spectroscopy of Different Oxidation States , 1995 .

[3] K. Kalyanasundaram,et al. Inter-chromophore electronic interactions in ligand-bridged polynuclear complexes: a comparative study of various bridging ligands , 1994 .

[4] M. Sponsler,et al. Mixed-Valence Diiron Complexes with Butadienediyl Bridges , 1994 .

[5] J. Gladysz,et al. New families of coordinated carbon: oxidative coupling of an ethynyl complex to isolable and crystallographically characterized MC.tplbond.CC.tplbond.CM and +M:C:C:C:C:M+ assemblies , 1993 .

[6] U. Mueller-Westerhoff,et al. THE SYNTHESIS OF DITHIOLENE DYES WITH STRONG NEAR-IR ABSORPTION , 1991 .

[7] Henry Taube,et al. Binuclear complexes of ruthenium ammines , 1973 .