Au/Fe/Au multilayer transducers for magneto-optic surface plasmon resonance sensing

In this paper, we analyze the magnetoplasmonic MP features and sensing capabilities of Au/Fe/Au trilayer structures, as transducers of the magneto-optic surface plasmon resonance MOSPR biosensor. This biosensor, which can surpass the sensitivity of the standard SPR sensor, is based on a MP modulation technique generated by the simultaneous stimulation of the surface plasmon polaritons SPP and the transversal magneto-optical Kerr effect TMOKE. We study the magneto-optical activity of the trilayers as a function of the thickness and position of the Fe layer. We first demonstrate that this kind of structure allows modulating the SPP through an external magnetic field and moreover, induce a strong enhancement of the TMOKE effect. The modulation of the SPP is linearly proportional to the thickness of Fe layer and inversely proportional to the distance between the Fe layer and the external dielectric medium. Finally, we experimentally confirm a twofold increase in the MOSPR sensitivity with respect to the intensity-interrogated SPR biosensor in bulk refractive-index changes, keeping a similar chemical resistance and stability, unprecedented in other MP transducers, and biofunctionalization protocols. © 2010 American Institute of Physics. doi:10.1063/1.3475711

[1]  L M Lechuga,et al.  Highly sensitive detection of biomolecules with the magneto-optic surface-plasmon-resonance sensor. , 2006, Optics letters.

[2]  J. Homola Surface plasmon resonance sensors for detection of chemical and biological species. , 2008, Chemical reviews.

[3]  B. Liedberg,et al.  Biosensing with surface plasmon resonance--how it all started. , 1995, Biosensors & bioelectronics.

[4]  L M Lechuga,et al.  Multi-analyte SPR immunoassays for environmental biosensing of pesticides , 2007, Analytical and bioanalytical chemistry.

[5]  Sergiy Patskovsky,et al.  Phase and amplitude sensitivities in surface plasmon resonance bio and chemical sensing. , 2009, Optics express.

[6]  J. Homola Surface plasmon resonance based sensors , 2006 .

[7]  Liann-Be Chang,et al.  High-sensitivity sensor based on surface plasmon resonance and heterodyne interferometry , 2003 .

[8]  A V Kabashin,et al.  Mechanical modulation method for ultrasensitive phase measurements in photonics biosensing. , 2008, Optics express.

[9]  L M Lechuga,et al.  Label-free detection of DNA mutations by SPR: application to the early detection of inherited breast cancer , 2009, Analytical and bioanalytical chemistry.

[10]  P. Prasad,et al.  Phase-sensitive time-modulated surface plasmon resonance polarimetry for wide dynamic range biosensing. , 2007, Optics express.

[11]  R. F. Wallis,et al.  Enhancement of the transverse Kerr magneto-optic effect by surface magnetoplasma waves , 1977 .

[12]  Laura M Lechuga,et al.  Identification of the optimal spectral region for plasmonic and nanoplasmonic sensing. , 2010, ACS nano.

[13]  J. Homola,et al.  Surface plasmon resonance (SPR) sensors: approaching their limits? , 2009, Optics express.

[14]  Jacques Peretti,et al.  Surface-enhanced magneto-optics in metallic multilayer films , 2001 .

[15]  N. Miura,et al.  Recent advancements in surface plasmon resonance immunosensors for detection of small molecules of biomedical, food and environmental interest , 2007 .

[16]  J. R. Sambles,et al.  Differential ellipsometric surface plasmon resonance sensors with liquid crystal polarization modulators , 2004 .

[17]  R. Clarke,et al.  Surface-magnetoplasmon nonreciprocity effects in noble-metal/ferromagnetic heterostructures , 2007 .

[18]  L M Lechuga,et al.  Determination of human growth hormone in human serum samples by surface plasmon resonance immunoassay. , 2009, Talanta.

[19]  H. Raether Surface Plasmons on Smooth and Rough Surfaces and on Gratings , 1988 .

[20]  D. Lynch,et al.  Optical properties of metals. , 1981, Applied optics.

[21]  L. Lechuga,et al.  Magnetooptic effects in surface-plasmon-polaritons slab waveguides , 2006, Journal of Lightwave Technology.

[22]  Marlière,et al.  Magneto-optical Effects Enhanced by Surface Plasmons in Metallic Multilayer Films. , 1994, Physical review letters.

[23]  Youngpak Lee,et al.  Magneto-optical and optical properties of Fe-rich Au-Fe alloy films near the fcc-bcc structural transformation region , 2003 .