Innovation of Embedding Eggshell to Enhance Physical-Mechanical-Thermal Properties in Fired Clay Bricks via Extrusion Process

Eggshell functioned as a bio-filler and sintering aid added into earthenware clay compounds to make fire clay bricks via extrusion process. The main composition of eggshell is calcium carbonate (CaCO 3 ) while the main composition of earthenware is aluminosilcate (Al 2 O 3 .2SiO 2 .2H 2 O) and other oxide compounds. Calcium carbonate in eggshell can react to chemical substances in earthenware clay compound to form calcium alumnosilicate or anorthite and wollastonite or calcium silicate phase formation of the fired clay bricks. Adding 20%wt eggshell powder into clay bricks and fired at 1000°C for 5 hrs., affects to the physical-mechanical-thermal properties, i.e. high compressive strength and hardness, good thermal expansion coefficient, good true density, and low water absorption. In general, the theoretical compressive strength, hardness, and water absorption of desired refractory are more than 7.0 MPa, 6.0 HV, and less than 25%wt, respectively. Therefore, the obtained fired clay bricks added eggshell powder and fired at 1000°C for 5 hrs., are potential for use as bricks for construction and thermal insulation.

[1]  Sujeeva Setunge,et al.  Possible use of biosolids in fired-clay bricks , 2015 .

[2]  D. Oliveira,et al.  A literature review on adding value to solid residues: egg shells. , 2013 .

[3]  Osman Şimşek,et al.  Porous clay bricks manufactured with rice husks , 2013 .

[4]  Rahul V. Ralegaonkar,et al.  Development of sustainable construction material using industrial and agricultural solid waste: A review of waste-create bricks , 2011 .

[5]  F. Kristály,et al.  Correlations between Combustion Type Additives and Expansion after Extrusion of Clay Bricks , 2010 .

[6]  Z. Ahmad,et al.  Effect of the change of firing temperature on microstructure and physical properties of clay bricks from Beruas (Malaysia) , 2010 .

[7]  Fernando Rocha,et al.  Mineralogical transformations of calcareous rich clays with firing: A comparative study between calcite and dolomite rich clays from Algarve, Portugal , 2009 .

[8]  Jiang Chang,et al.  Preparation and the phase transformation behavior of amorphous mesoporous calcium silicate , 2008 .

[9]  F. S. Murakami,et al.  Physicochemical study of CaCO3 from egg shells , 2007 .

[10]  J. Yang,et al.  Characterization and adsorption properties of eggshells and eggshell membrane. , 2006, Bioresource technology.

[11]  Ming Li,et al.  Preparation and in vitro bioactivities of calcium silicate nanophase materials , 2005 .

[12]  J. García‐Ruiz,et al.  Iconography : Avian eggshell mineralization: biochemical and functional characterization of matrix proteins , 2004 .

[13]  M. Jordán,et al.  Firing transformations of Tertiary clays used in the manufacturing of ceramic tile bodies , 2001 .

[14]  Giuseppe Cultrone,et al.  Carbonate and silicate phase reactions during ceramic firing , 2001 .

[15]  J. Weems Chemistry of Clays , 1904 .