Photocatalytic properties of Fe-doped ZnO electrospun nanofibers

Abstract Undoped and Fe-doped Zinc Oxide (ZnO) nanofibers were prepared by electrospinning method to investigate the effect of transition metal ion doping on the photocatalytic performance of ZnO. A variety of techniques were employed to characterize various properties of the fabricated nanofibers. It was realized that the crystallization of ZnO fibers was significantly improved by optimizing the sintering conditions. The results revealed that Fe-doping greatly improved the photocatalytic activity of ZnO owing to modified nanofibers morphology and the reduced optical bandgap. The ZnO nanofibers showed the optimum photocatalytic activity for 1.5% Fe-doping percentage which was attributed to the presence of maximum dopant ions in the ZnO matrix. The enhanced photocatalytic performance of ZnO could increase its scope of industrial and commercial applications.

[1]  Tom Regier,et al.  Band Gap Tuning in ZnO Through Ni Doping via Spray Pyrolysis , 2013 .

[2]  L. Schmidt‐Mende,et al.  ZnO - nanostructures, defects, and devices , 2007 .

[3]  R. Marschall Photocatalysis: Semiconductor Composites: Strategies for Enhancing Charge Carrier Separation to Improve Photocatalytic Activity (Adv. Funct. Mater. 17/2014) , 2014 .

[4]  Byeong-Kyu Lee,et al.  Great improvement on tetracycline removal using ZnO rod-activated carbon fiber composite prepared with a facile microwave method. , 2017, Journal of hazardous materials.

[5]  A. P. Rambu,et al.  Structure and gas sensing properties of nanocrystalline Fe-doped ZnO films prepared by spin coating method , 2013, Journal of Materials Science.

[6]  Muhammad Safdar,et al.  Visible light driven type II heterostructures and their enhanced photocatalysis properties: a review. , 2013, Nanoscale.

[7]  G. Shao,et al.  Mn-doped TiO2 nanopowders with remarkable visible light photocatalytic activity , 2011 .

[8]  G. Somorjai,et al.  Nanoscale advances in catalysis and energy applications. , 2010, Nano letters.

[9]  Y. Qi,et al.  A self-assembly mechanism for sol–gel derived ZnO thin films , 2007 .

[10]  Y. Long,et al.  Fabrication of p-type ZnO nanofibers by electrospinning for field-effect and rectifying devices , 2014 .

[11]  Hamberg,et al.  Band-gap tailoring of ZnO by means of heavy Al doping. , 1988, Physical review. B, Condensed matter.

[12]  Yan Zhang,et al.  Concave trisoctahedral Ag3PO4 microcrystals with high-index facets and enhanced photocatalytic properties. , 2013, Chemical communications.

[13]  Bo-Hye Kim,et al.  Zinc oxide/activated carbon nanofiber composites for high-performance supercapacitor electrodes , 2015 .

[14]  Zhong Lin Wang,et al.  One-dimensional ZnO nanostructures: Solution growth and functional properties , 2011 .

[15]  Ka-Fu Yung,et al.  Surfactant-Free microwave-assisted synthesis of Fe-doped ZnO nanostars as photocatalyst for degradation of tropaeolin o in water under visible light , 2015 .

[16]  I. Ferguson,et al.  Investigating process-structure relations of ZnO nanofiber via electrospinning method , 2017 .

[17]  Ji-Won Jung,et al.  Electrospun materials for solar energy conversion: innovations and trends , 2016 .

[18]  Li Liu,et al.  Carbon fibers/ZnO nanowires hybrid nanogenerator based on an insulating interface barrier , 2017 .

[19]  R. Marschall,et al.  Semiconductor Composites: Strategies for Enhancing Charge Carrier Separation to Improve Photocatalytic Activity , 2014 .

[20]  S. Muthusamy,et al.  ZnO/Ag heterostructures embedded in Fe3O4 nanoparticles for magnetically recoverable photocatalysis , 2016 .

[21]  Zeynep Aytac,et al.  Grain boundary engineering in electrospun ZnO nanostructures as promising photocatalysts , 2016 .

[22]  Huicong Liu,et al.  Growth of ZnO nanowires on fibers for one-dimensional flexible quantum dot-sensitized solar cells , 2012, Nanotechnology.

[23]  K. Ariga,et al.  Photocatalytic degradation of 2,4,6-trichlorophenol using lanthanum doped ZnO in aqueous suspension , 2007 .

[24]  E. Bacaksız,et al.  Structure and optical properties of Zn1−xFexO thin films prepared by ultrasonic spray pyrolysis , 2007 .

[25]  H. Raval,et al.  Nanotechnology in water treatment: an emerging trend , 2010 .

[26]  Ke Deng,et al.  Facet-mediated photodegradation of organic dye over hematite architectures by visible light. , 2012, Angewandte Chemie.

[27]  S. Manorama,et al.  Facile Synthesis of Face Oriented ZnO Crystals: Tunable Polar Facets and Shape Induced Enhanced Photocatalytic Performance , 2013 .

[28]  P. Amornpitoksuk,et al.  Effects of optical band gap energy, band tail energy and particle shape on photocatalytic activities of different ZnO nanostructures prepared by a hydrothermal method , 2016 .

[29]  N. Umezawa,et al.  Facet engineered Ag3PO4 for efficient water photooxidation , 2013 .

[30]  Tierui Zhang,et al.  Site-specific nucleation and growth kinetics in hierarchical nanosyntheses of branched ZnO crystallites. , 2006, Journal of the American Chemical Society.

[31]  L. Lauhon,et al.  A synergistic assembly of nanoscale lamellar photoconductor hybrids. , 2009, Nature materials.

[32]  C. Yoo,et al.  Status of adsorptive removal of dye from textile industry effluent , 2012 .

[33]  Shuxin Ouyang,et al.  Nano‐photocatalytic Materials: Possibilities and Challenges , 2012, Advanced materials.

[34]  Xianzhi Fu,et al.  Various Facet Tunable ZnO Crystals by a Scalable Solvothermal Synthesis and Their Facet-Dependent Photocatalytic Activities , 2014 .

[35]  J. Iqbal,et al.  Synthesis and Physical Properties of Mn Doped ZnO Dilute Magnetic Semiconductor Nanostructures , 2011 .

[36]  Guoyue Xu,et al.  Effect of sintering atmosphere on the electrical and optical properties of (ZnO)1−x(MnO2)x NTCR ceramics , 2009 .

[37]  Sunita Mishra,et al.  Synthesis and Sensing Characterization of ZnO Nanofibers Prepared by Electrospinning , 2015 .

[38]  G. Pan,et al.  Ti/ZnO–Fe2O3 composite: Synthesis, characterization and application as a highly efficient photoelectrocatalyst for methanol from CO2 reduction , 2016 .

[39]  A. Pourjavadi,et al.  Role of CdO addition on the growth and photocatalytic activity of electrospun ZnO nanofibers: UV vs. visible light , 2014 .

[40]  Jiaguo Yu,et al.  Origin of tunable photocatalytic selectivity of well-defined α-Fe(2)O(3) nanocrystals. , 2014, Small.

[41]  P. P. Sahay,et al.  Experimental Investigation of Spray-Deposited Fe-Doped ZnO Nanoparticle Thin Films: Structural, Microstructural, and Optical Properties , 2013, Journal of Thermal Spray Technology.

[42]  Lina Han,et al.  Influence of annealing temperature on the photoelectric gas sensing of Fe-doped ZnO under visible light irradiation , 2013 .

[43]  Anderson Janotti,et al.  Fundamentals of zinc oxide as a semiconductor , 2009 .