Enhancing the performance of a high-pressure cogeneration boiler with waste hydrogen-rich fuel

Abstract The cogeneration boiler has been applied extensively for simultaneously supplying electrical power and high-pressure steam. In this study, the performance of a high-pressure cogeneration boiler (max 280 tons/h boiler capacity) that burnt fuel oil (FO) and natural gas (NG) in a full-scale petrochemical plant was enhanced by partially replacing the NG with a waste hydrogen-rich refinery gas (RG), a byproduct from catalytic reforming and catalytic cracking operations. The addition of RG does not influence the boiler efficiency; it results in saving the energy consumption and significantly decreasing the greenhouse gas emission. If the inlet FO/NG/RG volumetric flow rate ratio is maintained at 50:33:17, adding RG will save 14,500,000 m 3 /year of NG and reduce 12,900 tons/year of CO 2 emission. Therefore, the use of RG to partially replace NG has practical benefits for reducing energy consumption and greenhouse gas emission.

[1]  S. C. Hill,et al.  Modeling of nitrogen oxides formation and destruction in combustion systems , 2000 .

[2]  Nesrin Ozalp,et al.  Calibrated models of on-site power and steam production in US manufacturing industries , 2006 .

[3]  Cheng-Hsien Tsai,et al.  Improvements in the performance of a medium-pressure-boiler through the adjustment of inlet fuels in a refinery plant , 2007 .

[4]  Vladimir I. Kuprianov Applications of a cost-based method of excess air optimization for the improvement of thermal efficiency and environmental performance of steam boilers , 2005 .

[5]  Pedro J. Coelho,et al.  Heavy fuel oil combustion in a cylindrical laboratory furnace: measurements and modeling , 2005 .

[6]  Gianni Bidini,et al.  Implementation of a cogenerative district heating : Optimization of a simulation model for the thermal power demand , 2006 .

[7]  János M. Beér,et al.  Combustion technology developments in power generation in response to environmental challenges , 2000 .

[8]  J. M. Sala,et al.  Investigation on the Design and Optimization of a Low NOx−CO Emission Burner Both Experimentally and through Computational Fluid Dynamics (CFD) Simulations , 2007 .

[9]  Petr Stehlik,et al.  Low NOx burners--prediction of emissions concentration based on design, measurements and modelling. , 2002, Waste management.

[10]  Ming-Tong Tsay,et al.  Application of evolutionary programming to optimal operational strategy cogeneration system under time-of-use rates , 2000 .

[11]  Leif Gustavsson,et al.  External costs and taxes in heat supply systems , 2003 .

[12]  E. Conde Lázaro,et al.  Analysis of cogeneration in the present energy framework , 2006 .

[13]  Yuksel Kaplan,et al.  Investigations of hydrogen and hydrogen–hydrocarbon composite fuel combustion and NOx emission characteristics in a model combustor , 2005 .

[14]  Wlodzimierz Blasiak,et al.  Mathematical modelling of NO emissions from high-temperature air combustion with nitrous oxide mechanism , 2005 .

[15]  Optimization of combustion by fuel testing in a NOx reduction test facility , 1997 .

[16]  Mustafa Ilbas,et al.  The effect of thermal radiation and radiation models on hydrogen–hydrocarbon combustion modelling , 2005 .

[17]  Ahsan Choudhuri,et al.  Characteristics of hydrogen–hydrocarbon composite fuel turbulent jet flames , 2003 .

[18]  L. Reh,et al.  Experimental investigation of the prevaporized premixed (vpl) combustion process for liquid fuel lean combustion , 2002 .

[19]  K. Clemitshaw,et al.  Ozone and other secondary photochemical pollutants: chemical processes governing their formation in the planetary boundary layer , 2000 .

[20]  S. Gollahalli,et al.  Combustion characteristics of hydrogen–hydrocarbon hybrid fuels , 2000 .

[21]  Chung-Jen Tseng,et al.  Effects of hydrogen addition on methane combustion in a porous medium burner , 2002 .

[22]  J. De Ruyck,et al.  NO formation rates for hydrogen combustion in stirred reactors , 2001 .

[23]  S. Aggarwal,et al.  Fuel effects on NOx emissions in partially premixed flames , 2004 .

[24]  Ö. Gülder,et al.  The effect of hydrogen addition on flammability limit and NOx emission in ultra-lean counterflow CH4/air premixed flames , 2005 .

[25]  Robert W. Schefer,et al.  Hydrogen enrichment for improved lean flame stability , 2003 .

[26]  S. Aggarwal,et al.  NOx emissions in n-heptane/air partially premixed flames , 2003 .