AMB2018-04: Benchmark Physical Property Measurements for Powder Bed Fusion Additive Manufacturing of Polyamide 12

Laser sintering (LS) of polyamide 12 (PA12) is increasingly being adopted for industrial production of end-use parts, yet the complexity of this process coupled with the lack of organized, rigorous, publicly available process-structure-physical property datasets exposes manufacturers and customers to risks of unacceptably poor part quality and high costs. Although an extensive scientific literature has been developed to address some of these concerns, results are distributed among numerous reports based on different machines, materials, process parameters, and users. In this study, a single commercially important LS PA12 feedstock has been processed along four build dimensions of a modern production LS machine, characterized by a wide range of physical techniques, and compared to the same material formed by conventional melt processing. Results are discussed in the context of the literature, offering novel insights including distributions of particle size and shape, localization of semicrystalline phase changes due to LS processing, effect of chemical aging on melt viscosity, porosity orientation relative to LS build axes, and microstructural effects on tensile properties and failure mechanisms. The resulting datasets will be made publicly available to modelers and practitioners for the purpose of improving certifiability and repeatability of end-use parts manufactured by LS.

[1]  Neil Hopkinson,et al.  Shear viscosity measurements on Polyamide‐12 polymers for laser sintering , 2013 .

[2]  Michael Schmidt,et al.  A Round Robin study for Selective Laser Sintering of polyamide 12: Microstructural origin of the mechanical properties , 2017 .

[3]  G. Peters,et al.  Quantification of isothermal crystallization of polyamide 12: Modelling of crystallization kinetics and phase composition , 2018, Polymer.

[4]  Study in performance and morphology of polyamide 12 produced by selective laser sintering technology , 2018, Rapid Prototyping Journal.

[5]  Richard P. Wool,et al.  Polymer welding relations investigated by a lap shear joint method , 1988 .

[6]  Yong Huang,et al.  Additive Manufacturing: Current State, Future Potential, Gaps and Needs, and Recommendations , 2015 .

[7]  J. Kruth,et al.  CT-based quality control of Laser Sintering of Polymers , 2016 .

[8]  J. Kruth,et al.  Effect of PA12 powder reuse on coalescence behaviour and microstructure of SLS parts , 2017 .

[9]  Bmc Bouke Wullms Additive manufacturing in the spare parts supply chain , 2016 .

[10]  Neil Hopkinson,et al.  Rapid manufacturing : an industrial revolution for the digital age , 2006 .

[11]  Garrett Craft,et al.  Impact of extended sintering times on mechanical properties in PA-12 parts produced by powderbed fusion processes , 2018, Additive Manufacturing.

[12]  J. Bullard,et al.  Contact function, uniform-thickness shell volume, and convexity measure for 3D star-shaped random particles , 2013 .

[13]  C. Körner,et al.  Modeling of Laser Beam Absorption in a Polymer Powder Bed , 2018, Polymers.

[14]  D. Drummer,et al.  Aging effects of polyamide 12 in selective laser sintering: Molecular weight distribution and thermal properties , 2019, Additive Manufacturing.

[15]  R. Hague,et al.  Laser sintering of polyamides and other polymers , 2012 .

[16]  C. Bunn,et al.  The crystal structure of polycaproamide: Nylon 6 , 1955 .

[17]  Neil Hopkinson,et al.  Degree of particle melt in Nylon‐12 selective laser‐sintered parts , 2009 .

[18]  David W. Fowler,et al.  Some properties of irregular 3-D particles , 2006 .

[19]  C. Yan,et al.  Ultra-toughened nylon 12 nanocomposites reinforced with IF-WS2 , 2014, Nanotechnology.

[20]  A. Becker Characterization and prediction of SLS processability of polymer powders with respect to powder flow and part warpage , 2016 .

[21]  H. Schuttenberg,et al.  A new method for gel permeation chromatography of polyamides , 1980 .

[22]  Brad Fox,et al.  Rapid Manufacture in the Aeronautical Industry , 2006 .

[23]  J. Kruth,et al.  Characterization of polyamide powders for determination of laser sintering processability , 2016 .

[24]  Z. Denchev,et al.  Crystalline structure of polyamide 12 as revealed by solid-state 13C NMR and synchrotron WAXS and SAXS , 2005 .

[25]  Brett Lyons,et al.  Additive Manufacturing in Aerospace; Examples and Research Outlook , 2014 .

[26]  S. Rüsenberg,et al.  Mechanical and Physical Properties – A Way to assess quality of Laser Sintered Parts , 2011 .

[28]  M. Schmid Laser Sintering with Plastics , 2018 .

[29]  N. Hopkinson,et al.  An investigation on the suitability of micro-computed tomography as a non-destructive technique to assess the morphology of laser sintered nylon 12 parts , 2014 .

[30]  Richard R Neptune,et al.  Manufacture of energy storage and return prosthetic feet using selective laser sintering. , 2010, Journal of biomechanical engineering.

[31]  L. Brown,et al.  The structure of the gamma form of polycaproamide (Nylon 6) , 1965 .

[32]  N. Hiramatsu,et al.  Study of Transformations among α, γ and γ' Forms in Nylon 12 by X-Ray and DSC , 1983 .

[33]  Richard H. Crawford,et al.  Manufacture of Passive Dynamic Ankle–Foot Orthoses Using Selective Laser Sintering , 2008, IEEE Transactions on Biomedical Engineering.

[34]  S. Leen,et al.  Helium permeability of polymer materials as liners for composite overwrapped pressure vessels , 2016 .

[35]  C. Emmelmann,et al.  Properties of copper modified polyamide 12-powders and their potential for the use as laser direct structurable electronic circuit carriers , 2018, Additive Manufacturing.

[36]  Carolyn Conner Seepersad,et al.  A designer's guide for dimensioning and tolerancing SLS parts , 2012 .

[37]  Neil Hopkinson,et al.  Effect of the degree of particle melt on mechanical properties in selective laser-sintered Nylon-12 parts , 2008 .

[38]  P. Puyvelde,et al.  Assessing polymer powder flow for the application of laser sintering , 2015 .

[39]  D. Bourell,et al.  Performance Limitations in Polymer Laser Sintering , 2014 .

[40]  Albert J. Shih,et al.  Additive manufacturing of custom orthoses and prostheses-A review , 2016 .

[41]  Yann Marco,et al.  Modelling the influence of temperature and relative humidity on the time-dependent mechanical behaviour of a short glass fibre reinforced polyamide , 2013 .

[42]  Wim Dewulf,et al.  Using X-ray computed tomography to improve the porosity level of polyamide-12 laser sintered parts , 2016 .

[43]  Q. Nguyen,et al.  FOR SPACE APPLICATIONS , 2000 .

[44]  J. Usher,et al.  Weibull growth modeling of laser‐sintered nylon 12 , 2013 .

[45]  W. H. Jeu,et al.  Crystalline Structure and Morphology in Nylon-12: A Small- and Wide-Angle X-ray Scattering Study , 2003 .

[46]  D. Drummer,et al.  Crystallization Kinetics of Polyamide 12 during Selective Laser Sintering , 2018, Polymers.

[47]  S. Hoshino,et al.  Crystal structure of nylon 12 , 1973 .

[48]  J. Kruth,et al.  Benchmarking of different SLS/SLM processes as Rapid Manufacturing techniques , 2005 .

[49]  K. Migler,et al.  Weld formation during material extrusion additive manufacturing. , 2017, Soft matter.

[50]  Richard R Neptune,et al.  Selective laser sintered versus carbon fiber passive-dynamic ankle-foot orthoses: a comparison of patient walking performance. , 2014, Journal of biomechanical engineering.

[51]  T. Niino,et al.  Effect of Powder Compaction in Plastic Laser Sintering Fabrication , 2009 .

[52]  Neil Hopkinson,et al.  Effect of section thickness and build orientation on tensile properties and material characteristics of laser sintered nylon‐12 parts , 2011 .

[53]  C. Ramesh Crystalline Transitions in Nylon 12 , 1999 .

[54]  H. A. Willis,et al.  The application of Fourier transform Raman spectroscopy to the identification and characterization of polyamides—I. Single number nylons , 1990 .

[55]  Charlie C. L. Wang,et al.  The status, challenges, and future of additive manufacturing in engineering , 2015, Comput. Aided Des..

[56]  David W. Fowler,et al.  Shape and size of microfine aggregates: X-ray microcomputed tomography vs. laser diffraction , 2007 .

[57]  S. Tamari,et al.  Optimum design of the constant-volume gas pycnometer for determining the volume of solid particles , 2004 .

[58]  J. Scala,et al.  The effect of furan molecular units on the glass transition and thermal degradation temperatures of polyamides , 2017 .

[59]  Manfred Schmid,et al.  Influence of the origin of polyamide 12 powder on the laser sintering process and laser sintered parts , 2017 .

[60]  James L White,et al.  Crystal structure, morphology, orientation, and mechanical properties of biaxially oriented polyamide 6 films , 2002 .

[61]  A. Bandyopadhyay,et al.  Additive manufacturing: scientific and technological challenges, market uptake and opportunities , 2017 .

[62]  S. M. Aharoni,et al.  n-Nylons: Their Synthesis, Structure, and Properties , 1997 .

[63]  Neil Hopkinson Production Economics of Rapid Manufacture , 2006 .

[64]  Stephen Oluwashola Akande,et al.  Assessment of tests for use in process and quality control systems for selective laser sintering of polyamide powders , 2016 .

[65]  John Wooten Aeronautical Case Studies Using Rapid Manufacture , 2006 .

[66]  N. Kasai,et al.  The γ → α partial transformation in nylon 12 by drawing , 1981 .

[67]  D. Drummer,et al.  Thermographic investigation of laser-induced temperature fields in selective laser beam melting of polymers , 2019, Optics & Laser Technology.

[68]  Chee Kai Chua,et al.  Polymeric composites for powder-based additive manufacturing: Materials and applications , 2019, Progress in Polymer Science.

[69]  J. Usher,et al.  The effect of process conditions on mechanical properties of laser‐sintered nylon , 2011 .

[70]  O. Lame,et al.  Microstructural origin of physical and mechanical properties of polyamide 12 processed by laser sintering , 2012 .

[71]  Neil Hopkinson,et al.  Effects of processing on microstructure and properties of SLS Nylon 12 , 2006 .

[72]  Konrad Wegener,et al.  Materials perspective of polymers for additive manufacturing with selective laser sintering , 2014 .

[73]  N. Kasai,et al.  Effect of casting conditions on polymorphism of nylon‐12 , 1980 .

[74]  M. J. Hill,et al.  Chain-folded lamellar crystals of aliphatic polyamides. Investigation of nylons 4 8, 4 10, 4 12, 6 10, 6 12, 6 18 and 8 12 , 1997 .

[75]  Joseph L. Lenhart,et al.  DMA testing of epoxy resins: The importance of dimensions , 2015 .