Effect of carbon nanotubes on mechanical and electrical properties of polyimide/carbon nanotubes nanocomposites

Abstract Multi-walled carbon nanotubes (MWNTs) reinforced polyimide nanocomposites were synthesized by in situ polymerization using 4,4′-oxydianilline, MWNTs, and pyromellitic dianhydride followed by casting, evaporation and thermal imidization. A homogeneous dispersion of chemically modified MWNTs was achieved in polyimide matrix as evidenced by scanning electron microscopy and atomic force microscopy. The incorporation of the modified MWNTs enhanced the mechanical properties of the polyimide due to the presence of strong interfacial interaction between the polymer matrix and the nanotubes in polymer composites. The resultant polyimide/MWNTs nanocomposites were electrically conductive with significant conductivity enhancement at 3 wt% MWNTs, which is favorable for many practical uses.

[1]  J. Iroh,et al.  Synthesis and Characterization of Polyimide/Silica Hybrid Composites , 1999 .

[2]  S. Armes,et al.  Multihydroxy Polymer-Functionalized Carbon Nanotubes: Synthesis, Derivatization, and Metal Loading , 2005 .

[3]  R. Andrews,et al.  Carbon nanotube polymer composites , 2004 .

[4]  Yiu-Wing Mai,et al.  Dispersion and alignment of carbon nanotubes in polymer matrix: A review , 2005 .

[5]  Lawrence F. Allard,et al.  Functionalization of Carbon Nanotubes with Polystyrene , 2002 .

[6]  R. Hoch,et al.  High power electrochemical capacitors based on carbon nanotube electrodes , 1997 .

[7]  J. Nagy,et al.  Preparation and Characterization of Carbon Nanotube/Polyacrylonitrile Composites , 2002 .

[8]  K. Watson,et al.  Dispersion of single wall carbon nanotubes by in situ polymerization under sonication , 2002 .

[9]  R. Smalley,et al.  Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping , 2001 .

[10]  C. Dekker,et al.  Logic Circuits with Carbon Nanotube Transistors , 2001, Science.

[11]  Richard H. Friend,et al.  Composites of Carbon Nanotubes and Conjugated Polymers for Photovoltaic Devices , 1999 .

[12]  P. Ajayan,et al.  Capillarity-induced filling of carbon nanotubes , 1993, Nature.

[13]  A. Rinzler,et al.  Carbon nanotube actuators , 1999, Science.

[14]  D. E. Hill,et al.  Polyimide-functionalized carbon nanotubes: Synthesis and dispersion in nanocomposite films , 2004 .

[15]  Volkov,et al.  Supercurrents through single-walled carbon nanotubes , 1999, Science.

[16]  M. Dresselhaus,et al.  Physical properties of carbon nanotubes , 1998 .

[17]  E. Siochi,et al.  Electrical properties of single wall carbon nanotube reinforced polyimide composites , 2003 .

[18]  Hsu-Chiang Kuan,et al.  Synthesis, thermal, mechanical and rheological properties of multiwall carbon nanotube/waterborne polyurethane nanocomposite , 2005 .

[19]  E. Bekyarova,et al.  Incorporation of highly dispersed single-walled carbon nanotubes in a polyimide matrix , 2006 .

[20]  H. Choi,et al.  Carbon Nanotube-Adsorbed Polystyrene and Poly(methyl methacrylate) Microspheres , 2005 .

[21]  T. Ebbesen,et al.  Exceptionally high Young's modulus observed for individual carbon nanotubes , 1996, Nature.

[22]  Andrea E O'Rear,et al.  SWNT-Filled Thermoplastic and Elastomeric Composites Prepared by Miniemulsion Polymerization , 2002 .

[23]  James R Heath,et al.  Starched carbon nanotubes. , 2002, Angewandte Chemie.

[24]  D. Yan,et al.  Controlled functionalization of multiwalled carbon nanotubes by in situ atom transfer radical polymerization. , 2004, Journal of the American Chemical Society.

[25]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[26]  N. Sahoo,et al.  Effect of Functionalized Carbon Nanotubes on Molecular Interaction and Properties of Polyurethane Composites , 2006 .

[27]  Joselito M. Razal,et al.  Super-tough carbon-nanotube fibres , 2003, Nature.

[28]  Ya‐Ping Sun,et al.  Space durable polymer/carbon nanotube films for electrostatic charge mitigation ☆ , 2004 .

[29]  Gilbert C Walker,et al.  Noncovalent engineering of carbon nanotube surfaces by rigid, functional conjugated polymers. , 2002, Journal of the American Chemical Society.

[30]  Zhi‐Kang Xu,et al.  Preparation and properties of the polyimide/multi-walled carbon nanotubes (MWNTs) nanocomposites , 2006 .

[31]  N. Goo,et al.  Electroactive Shape‐Memory Polyurethane Composites Incorporating Carbon Nanotubes , 2005 .

[32]  Bin Zhao,et al.  Continuous spinning of a single-walled carbon nanotube-nylon composite fiber. , 2005, Journal of the American Chemical Society.