Hawaii Energy and Environmental Technologies (HEET) Initiative

Abstract : This report covers efforts by the Hawaii Natural Energy Institute of the University of Hawaii under the ONR-funded HEET Initiative that addresses critical technology needs for exploration/utilization of seabed methane hydrates and development/testing of advanced fuel cells and fuel cell systems. Methane hydrates work included: hydrate thermochemistry and kinetics; environmental impacts of methane release from seafloor hydrates; hydrate engineering applications; and international collaborative RD work on understanding the S02 contamination mechanism and S02 contamination recovery; preliminary testing of Protonex H2/air stacks under pure oxygen in support of NUWC; and fuel contamination efforts via a Modelica model which worked with previous experimental results of CO poisoning. Fuel processing and purification work included testing of a reverse-vortex-flow non-thermal plasma reactor to study methane reforming. Further work was also carried out with novel fuel cell concepts including biocarbons and bio-fuel cells.

[1]  Hiroshi Sato,et al.  Thermodynamic and Raman spectroscopic studies on H2+tetrahydrofuran+water and H2+ tetra-n-butyl ammonium bromide+water mixtures containing gas hydrates , 2006 .

[2]  C. Posten,et al.  Comparison of the energetic efficiencies of hydrogen and oxychemicals formation in Klebsiella pneumoniae and Clostridium butyricum during anaerobic growth on glycerol. , 1995, Journal of biotechnology.

[3]  L. Fouts Analysis of Biodiesel Blend Samples Collected in the United States in 2008 , 2010 .

[4]  Y. Ting,et al.  Characterization of corrosive bacterial consortia isolated from petroleum-product-transporting pipelines , 2009, Applied Microbiology and Biotechnology.

[5]  Scott Q. Turn,et al.  Experimental Investigation of Hydrogen Production from Glycerin Reforming , 2007 .

[6]  Radu Burlica,et al.  Formation of reactive species in gliding arc discharges with liquid water , 2006 .

[7]  M. Liu,et al.  Synthesis of Metabolites of Polycyclic Aromatic Hydrocarbons , 2010 .

[8]  Jhuma Sadhukhan,et al.  Process intensification aspects for steam methane reforming: An overview , 2009 .

[9]  Christopher Yang,et al.  Determining the lowest-cost hydrogen delivery mode , 2007 .

[10]  Iulian Rusu,et al.  On a possible mechanism of the methane steam reforming in a gliding arc reactor , 2003 .

[11]  C. Angell,et al.  Heat capacity of water at extremes of supercooling and superheating. Technical report , 1981 .

[12]  K. Glasgow,et al.  Los Angeles, California , 2003 .

[13]  R. Metkemeijer,et al.  Experimental study on gasoline reforming assisted by nonthermal arc discharge , 2008 .

[14]  T. Lewins,et al.  Fit for purpose , 2000 .

[15]  K. Henriksen,et al.  Characterization of Methanotrophic Bacterial Populations in Soils Showing Atmospheric Methane Uptake , 1999, Applied and Environmental Microbiology.

[16]  P. Atanassov,et al.  Conductive macroporous composite chitosan-carbon nanotube scaffolds. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[17]  A. Fridman,et al.  Gliding arc in tornado using a reverse vortex flow , 2005 .

[18]  A. Czernichowski GlidArc Assisted Preparation of the Synthesis Gas from Natural and Waste Hydrocarbons Gases , 2001 .

[19]  John M. Cimbala,et al.  Fluid Mechanics: Fundamentals and Applications , 2004 .

[20]  Qing X. Li,et al.  Chapter 21 – Proteomics in Pesticide Toxicology , 2010 .

[21]  N. Palaniswamy,et al.  Biodegradation and corrosion behavior of manganese oxidizer Bacillus cereus ACE4 in diesel transporting pipeline , 2007 .

[22]  Jan Sunner,et al.  Biocorrosion: towards understanding interactions between biofilms and metals. , 2004, Current opinion in biotechnology.

[23]  Thierry Paulmier,et al.  Use of non-thermal plasma for hydrocarbon reforming , 2005 .

[24]  Ramon Gonzalez,et al.  Anaerobic fermentation of glycerol by Escherichia coli: a new platform for metabolic engineering. , 2006, Biotechnology and bioengineering.

[25]  B. Liaw,et al.  Three Dimensional Chitosan Carbon Nanotube Composite Material for Biofuel Cell Application , 2008 .

[26]  F. Richard,et al.  Physical study of a gliding arc discharge , 1996 .

[27]  Manfred Baldauf,et al.  Plasma catalytic hybrid processes: gas discharge initiation and plasma activation of catalytic processes , 2004 .

[28]  Qing X. Li,et al.  Metabolomics in Pesticide Toxicology , 2010 .

[29]  A. Fridman,et al.  Gliding arc gas discharge , 1999 .

[30]  Eric W. Lemmon,et al.  Method for Estimating the Dielectric Constant of Natural Gas Mixtures , 2005 .

[31]  D. R. Cohn,et al.  Plasma catalytic reforming of methane , 1999 .

[32]  Bor Yann Liaw,et al.  In Situ Characterization Techniques for Design and Evaluation of Micro-and Nano-Enzyme-Catalyzed Power Sources , 2008 .

[33]  Scott Calabrese Barton,et al.  Enzymatic Biofuel Cells , 2007, ECS Meeting Abstracts.

[34]  N. Palaniswamy,et al.  Role of Serratia marcescens ACE2 on diesel degradation and its influence on corrosion , 2007, Journal of Industrial Microbiology & Biotechnology.

[35]  E. Chodurek,et al.  The relationship between microbial metabolic activity and biocorrosion of carbon steel. , 1997, Research in microbiology.

[36]  Satoshi Okabe,et al.  Microbial community structures and in situ sulfate-reducing and sulfur-oxidizing activities in biofilms developed on mortar specimens in a corroded sewer system , 2018 .

[37]  Y. Chun,et al.  Hydrogen-Rich Gas Production from Biogas Reforming Using Plasmatron† , 2008 .

[38]  M. G. Sobacchi Experimental assessment of a combined plasma/catalytic system for hydrogen production via partial oxidation of hydrocarbon fuels , 2002 .

[39]  Marchesi,et al.  Methanogen and bacterial diversity and distribution in deep gas hydrate sediments from the Cascadia Margin as revealed by 16S rRNA molecular analysis. , 2001, FEMS microbiology ecology.

[40]  M. Cha,et al.  Optimization scheme of a rotating gliding arc reactor for partial oxidation of methane , 2007 .

[41]  Hiroyuki Oyama,et al.  Phase diagram, latent heat, and specific heat of TBAB semiclathrate hydrate crystals , 2005 .

[42]  F. Mueller-Langer,et al.  Techno-economic assessment of hydrogen production processes for the hydrogen economy for the short and medium term , 2007 .

[43]  S. Minteer,et al.  Characterization of flow-through microbial fuel cells , 2010 .

[44]  B. Liaw,et al.  Design and characterization of redox enzyme electrodes: new perspectives on established techniques with application to an extremeophilic hydrogenase , 2005 .

[45]  S. Minteer,et al.  Fluorescence characterization of chemical microenvironments in hydrophobically modified chitosan , 2009 .

[46]  S. Chavadej,et al.  Partial oxidation of methane with air for synthesis gas production in a multistage gliding arc discharge system , 2007 .

[47]  B. Liaw,et al.  Harnessing electric power from monosaccharides—a carbohydrate–air alkaline fuel cell mediated by redox dyes , 2009 .

[48]  B. Liaw,et al.  Sustainable current generation from the ammonia–polypyrrole interaction , 2008 .

[49]  D. Capone,et al.  Degassing of Pore Water Methane during Sediment Incubations , 1985, Applied and environmental microbiology.

[50]  B. Liaw,et al.  Design of chitosan gel pore structure: towards enzyme catalyzed flow-through electrodes , 2008 .

[51]  A. Zeng,et al.  High concentration and productivity of 1,3-propanediol from continuous fermentation of glycerol by Klebsiella pneumoniae , 1997 .

[52]  Yu Zhu Applied Materials & Interfaces , 2012 .

[53]  M. Cooney Kinetic measurements for enzyme immobilization. , 2011, Methods in molecular biology.

[54]  Guillaume Petitpas,et al.  A comparative study of non-thermal plasma assisted reforming technologies , 2007 .

[55]  A. Bories,et al.  Relationship between the physiology of Enterobacter agglomerans CNCM 1210 grown anaerobically on glycerol and the culture conditions. , 1997, Research in microbiology.

[56]  Carolyn A. Koh,et al.  Clathrate hydrates of natural gases , 1990 .

[57]  A. Fridman,et al.  Gliding arc discharges as a source of intermediate plasma for methane partial oxidation , 2005, IEEE Transactions on Plasma Science.

[58]  A. B. Ustimenko,et al.  Hydrogen production by coal plasma gasification for fuel cell technology , 2007 .

[59]  W. Wagner,et al.  The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use , 2002 .

[60]  Yash Paul Handa,et al.  Compositions, enthalpies of dissociation, and heat capacities in the range 85 to 270 K for clathrate hydrates of methane, ethane, and propane, and enthalpy of dissociation of isobutane hydrate, as determined by a heat-flow calorimeter , 1986 .

[61]  Akira Mizuno,et al.  Hydrogen production by reforming of iso-octane using spray-pulsed injection and effect of non-thermal plasma , 2004 .

[62]  Alexei V. Saveliev,et al.  Thermal and nonthermal regimes of gliding arc discharge in air flow , 2000 .

[63]  S. Turn,et al.  An experimental investigation of reverse vortex flow plasma reforming of methane , 2012 .

[64]  Robert I. Krieger,et al.  Hayes' handbook of pesticide toxicology , 2010 .

[65]  J. Golob,et al.  Microorganisms in Diesel and in Biodiesel Fuels , 2007 .