Polysaccharide-based hydrogels derived from cellulose: the architecture change from nanofibers to hydrogels for a putative dual function in dye wastewater treatment.

Improving the electrochemical capacitance performance of biomass-derived carbon electrode active materials for supercapacitor applications has recently attracted considerable attention. In the study, we develop hybrid electrode materials from rice husk-derived porous carbon(C) and β-Ni(OH)2 using a facile two-step solid-state reaction strategy. The prepared C/Ni(OH)2 composite materials were characterized by SEM (EDS), XPS, and XRD to acquire the physical and chemical information, which was used to demonstrate the successful preparation of C/Ni(OH)2 composite materials. The TGA measurement results confirmed that the thermal stability of C/Ni(OH)2 was changed owning to the presence of Ni(OH)2. As expected, C/Ni(OH)2 electrode materials possess higher specific capacitance (~ 952 F/g at the current density of 1.0 A/g) than that of pure biomass-based carbon materials under three-electrode system. This facile preparation method, which was used to fabricate electrode active materials, can extend to the value-added utility of other waste biomass materials for high-performance supercapacitors for energy storage applications.

[1]  I. Kelnar,et al.  Carboxymethyl cellulose-hydrogel embedded with modified magnetite nanoparticles and porous carbon: Effective environmental adsorbent. , 2020, Carbohydrate polymers.

[2]  T. Jiao,et al.  Facile preparation of self-assembled chitosan-based composite hydrogels with enhanced adsorption performances , 2020 .

[3]  Jie Cai,et al.  Preparation of Lipid-soluble Bilberry Anthocyanins through Acylation with Cinnamic Acids and Its Antioxidation Activities. , 2020, Journal of agricultural and food chemistry.

[4]  Yinzhen Wang,et al.  Fabrication of ZIF-8@TiO2 micron composite via hydrothermal method with enhanced absorption and photocatalytic activities in tetracycline degradation , 2020 .

[5]  D. Prasetyoko,et al.  Review on recent advances of carbon based adsorbent for methylene blue removal from waste water , 2020, Materials Today Chemistry.

[6]  Yinqiu Wu,et al.  Facile preparation of polyacrylamide/chitosan/Fe3O4 composite hydrogels for effective removal of methylene blue from aqueous solution. , 2020, Carbohydrate polymers.

[7]  A. Kouzani,et al.  Dynamic plant-derived polysaccharide-based hydrogels. , 2020, Carbohydrate polymers.

[8]  A. Silverman,et al.  Photocatalytic hydrogels for removal of organic contaminants from aqueous solution in continuous flow reactors , 2020 .

[9]  A. Kruse,et al.  Towards the Properties of Different Biomass-Derived Proteins via Various Extraction Methods , 2020, Molecules.

[10]  Jie Cai,et al.  Citric acid-incorporated cellulose nanofibrous mats as food materials-based biosorbent for removal of hexavalent chromium from aqueous solutions. , 2020, International journal of biological macromolecules.

[11]  Yuanfeng Pan,et al.  Redox-responsive carboxymethyl cellulose hydrogel for adsorption and controlled release of dye , 2020 .

[12]  Richa,et al.  Synthesis of a novel gellan-pullulan nanogel and its application in adsorption of cationic dye from aqueous medium. , 2020, Carbohydrate polymers.

[13]  Xuejun Wang,et al.  Electrospun cellulose acetate/P(DMDAAC‐AM) nanofibrous membranes for dye adsorption , 2020, Journal of Applied Polymer Science.

[14]  Inamuddin,et al.  Nano-engineered Adsorbent for the Removal of Dyes from Water: A Review , 2020 .

[15]  Z. Alothman,et al.  Photodegradation of toxic dye using Gum Arabic-crosslinked-poly(acrylamide)/Ni(OH)2/FeOOH nanocomposites hydrogel , 2019 .

[16]  Z. N. Garba,et al.  Microcrystalline cellulose (MCC) based materials as emerging adsorbents for the removal of dyes and heavy metals - A review. , 2019, The Science of the total environment.

[17]  Xiaoliang Qi,et al.  Honeycomb-like hydrogel adsorbents derived from salecan polysaccharide for wastewater treatment , 2019, Cellulose.

[18]  Haijiang Wang,et al.  Facile synthesis of a triptycene‐based porous organic polymer with a high efficiency and recyclable adsorption for organic dyes , 2019, Journal of Applied Polymer Science.

[19]  E. Srasra,et al.  Adsorption of organic dyes by HDPy+-modified clay: Effect of molecular structure on the adsorption , 2019, Journal of Molecular Structure.

[20]  M. Ghaedi,et al.  Visible light-induced photo-degradation of methylene blue by n–p heterojunction CeO2/CuS composite based on ribbon-like CeO2 nanofibers via electrospinning , 2019, Polyhedron.

[21]  M. Ranjbar-Mohammadi,et al.  Low cost hydrogels based on gum Tragacanth and TiO2 nanoparticles: characterization and RBFNN modelling of methylene blue dye removal. , 2019, International journal of biological macromolecules.

[22]  Xiu-li Wang,et al.  A Bifunctional Alginate-Based Composite Hydrogel with Synergistic Pollutant Adsorption and Photocatalytic Degradation Performance , 2019, Industrial & Engineering Chemistry Research.

[23]  E. Amante,et al.  Investigation of cell wall polysaccharides from flour made with waste peel from unripe banana (Musa sapientum) biomass. , 2019, Journal of the science of food and agriculture.

[24]  Haibin Sun,et al.  Electrospinning preparation and dye adsorption capacity of TiO2@Carbon flexible fiber , 2019, Ceramics International.

[25]  Amit Kumar,et al.  Fabrication and characterization of novel Fe0@Guar gum-crosslinked-soya lecithin nanocomposite hydrogel for photocatalytic degradation of methyl violet dye , 2019, Separation and Purification Technology.

[26]  Shugen Liu,et al.  Treatment of hydroxyquinone-containing wastewater using precipitation method with barium salt , 2019, Water Science and Engineering.

[27]  B. Pei,et al.  Construction of ordered structure in polysaccharide hydrogel: A review. , 2019, Carbohydrate polymers.

[28]  Yuxiang Jia,et al.  Synthesis of a novel isatin and ethylenediamine modified resin and effective adsorption behavior towards Orange G , 2019, RSC advances.

[29]  Z. Zuhra,et al.  Synthesis of γ-alumina (Al2O3) nanoparticles and their potential for use as an adsorbent in the removal of methylene blue dye from industrial wastewater , 2018, Nanoscale advances.

[30]  Xiaoyu Chen,et al.  Alginate Composite Hydrogel Bead with Multilayer Flake Structure for Dye Adsorptions , 2019, Journal of Renewable Materials.

[31]  Xiaoze Shi,et al.  Large-scale converting waste coffee grounds into functional carbon materials as high-efficient adsorbent for organic dyes. , 2019, Bioresource technology.

[32]  A. Mohammadi,et al.  Synthesis and Characterization of γ-CD-Modified TiO2 Nanoparticles and Its Adsorption Performance for Different Types of Organic Dyes , 2018, Journal of Chemical & Engineering Data.

[33]  Zuotai Zhang,et al.  MOF-Derived Porous ZnO Nanocages/rGO/Carbon Sponge-Based Photocatalytic Microreactor for Efficient Degradation of Water Pollutants and Hydrogen Evolution , 2018, ACS Sustainable Chemistry & Engineering.

[34]  B. Shahmoradi,et al.  Porous synthetic hectorite clay-alginate composite beads for effective adsorption of methylene blue dye from aqueous solution. , 2018, International journal of biological macromolecules.

[35]  B. Ding,et al.  Nanofiber-Based Hydrogels: Controllable Synthesis and Multifunctional Applications. , 2018, Macromolecular rapid communications.

[36]  Geun Chul Park,et al.  Enhanced Photocatalytic Activity of Porous Single Crystal TiO 2 /CNT Composites by Annealing Process , 2018 .

[37]  F. H. Rodrigues,et al.  Cellulose nanowhiskers improve the methylene blue adsorption capacity of chitosan-g-poly(acrylic acid) hydrogel. , 2018, Carbohydrate polymers.

[38]  F. Ali,et al.  Removal of Acid Yellow 17 Dye by Fenton Oxidation Process , 2018 .

[39]  T. Tripathy,et al.  Poly(N,N-dimethylacrylamide-co-acrylamide) Grafted Hydroxyethyl Cellulose Hydrogel: A Useful Congo Red Dye Remover , 2018, Journal of Polymers and the Environment.

[40]  S. Ray,et al.  Competitive Removal of Cu(II) and Cd(II) from Water Using a Biocomposite Hydrogel. , 2017, Journal of Physical Chemistry B.

[41]  C. Das,et al.  Removal of Pb (II) and Cu (II) ions from wastewater using composite electrospun cellulose acetate/titanium oxide (TiO2) adsorbent , 2017 .

[42]  Shuang Liu,et al.  Electrospun composite nanofiber mats of Cellulose@Organically modified montmorillonite for heavy metal ion removal: Design, characterization, evaluation of absorption performance , 2017 .

[43]  Tong Lin,et al.  High-performance supercapacitor electrode from cellulose-derived, inter-bonded carbon nanofibers , 2016 .

[44]  Juming Yao,et al.  Synthetic control of three-dimensional porous cellulose-based bioadsorbents: correlation between structural feature and metal ion removal capability , 2016, Cellulose.

[45]  V. Ranade,et al.  Green Approach to Dye Wastewater Treatment Using Biocoagulants , 2016 .

[46]  M. Irani,et al.  Chitosan nanofibers functionalized by TiO2 nanoparticles for the removal of heavy metal ions , 2016 .

[47]  Tong Lin,et al.  High-Performance Supercapacitor Electrode Materials from Cellulose-Derived Carbon Nanofibers. , 2015, ACS applied materials & interfaces.

[48]  Qian Ma,et al.  Robust electrospinning cellulose acetate@TiO2 ultrafine fibers for dyeing water treatment by photocatalytic reactions , 2015 .

[49]  Naveed Ahmad,et al.  Synthesis and characterization of thermo- and pH-responsive bacterial cellulose/acrylic acid hydrogels for drug delivery , 2012 .