Quantification of slag heap volumes and masses through the use of induced polarization: application to the Castel-Minier site

Abstract When used for archaeological purposes, geophysical methods are often useful for the exploration, detection and mapping of archaeological remains. In the case of ancient metallurgical activities, slag accumulations form precious mineral records of these activities. Evaluating the volume of slag produced in such locations is an important issue, since it enables an estimate of the amount of metal produced in the smeltery. Unfortunately, slags themselves cannot be easily detected by DC electrical methods. Although they can be easily detected using magnetic techniques, these methods do not allow for an estimate of the quantity of slag, because magnetic fields do not conserve magnetic flux. In the present study we show that the Induced Polarization method (IP) is suited to the quantification of buried slags, provided the slag response has been suitably calibrated prior to the field measurements. The ability to quantify the quantity of slag is based on the quasi-linear relationship between the main IP parameter, i.e., the chargeability, and the slag concentration. This approach provides a new, non-invasive tool for the estimation of the volume of buried slag in palaeometallurgical sites. In this paper, an application of this technique for the site of Castel-Minier, Ariege, France, is presented.

[1]  F. G. Shin,et al.  Pulse response functions of dielectric susceptibility , 1991, Journal of Materials Science.

[2]  D. Parasnis,et al.  Principles of Applied Geophysics , 1962 .

[3]  M. Dabas,et al.  Recent developments in shallow‐depth electrical and electrostatic prospecting using mobile arrays , 1998 .

[4]  F. G. Shin,et al.  On the connection between the spectral shape function for dielectric susceptibility and a non-linear differential equation , 1988 .

[5]  Andreas Weller,et al.  A new approach to fitting induced-polarization spectra , 2008 .

[6]  Nicolas Florsch,et al.  CR1Dinv: A Matlab program to invert 1D spectral induced polarization data for the Cole-Cole model including electromagnetic effects , 2009, Comput. Geosci..

[7]  A. Revil,et al.  Effects of Drying on the Low-Frequency Electrical Properties of Tournemire Argillites , 2007 .

[8]  C. Dias,et al.  Developments In A Model To Describe Low-Frequency Electrical Polarization Of Rocks - (Iii): Applications , 1999 .

[9]  H. Frank Morrison,et al.  ELECTROMAGNETIC COUPLING IN FREQUENCY AND TIME-DOMAIN INDUCED-POLARIZATION SURVEYS OVER A MULTILAYERED EARTH , 1973 .

[10]  I. Scollar Archaeological Prospecting and Remote Sensing , 1990 .

[11]  Michel Dabas,et al.  Magnetic susceptibility and viscosity of soils in a weak time varying field , 1992 .

[12]  H. Seigel Mathematical formulation and type curves for induced polarization , 1959 .

[13]  M. Schmutz,et al.  Non-invasive monitoring of water content and textural changes in clay-rocks using spectral induced polarization: A laboratory investigation , 2009 .

[14]  Stanley H. Ward,et al.  Mineral discrimination and removal of inductive coupling with multifrequency IP , 1978 .

[15]  Nicolas Florsch,et al.  Determination of permeability from spectral induced polarization in granular media , 2010 .

[16]  C. Schlumberger,et al.  Étude sur la prospection électrique du sous-sol , 1920 .

[17]  Gerald W. Hohmann Electromagnetic Coupling Between Grounded Wires At The Surface Of A Two-layer Earth , 1973 .

[18]  J. Chambers,et al.  Inversion of 2D spectral induced polarization imaging data , 2006 .

[19]  J. Fabre,et al.  Évaluation du volume des ferriers romains du domaine des Forges (Les Martys, Aude), de la masse de scories qu'ils renferment et de la production de fer correspondante , 1998 .

[20]  Chris Gaffney,et al.  Magnetometry for Archaeologists , 2008 .

[21]  S. Leroy Circulation au moyen âge des matériaux ferreux issus des Pyrénées ariégeoises et de la Lombardie. : Apport du couplage des analyses en éléments traces et multivariées , 2010 .

[22]  C. Doussan,et al.  Non‐invasive monitoring of water infiltration in a silty clay loam soil using Spectral Induced Polarization , 2008 .

[23]  A. Aspinall,et al.  Induced polarization as a technique for archaeological sur-veying , 1968 .

[24]  A. Aspinall,et al.  An induced polarization instrument for the detection of near-surface features , 1970 .

[25]  Cornelius Meyer,et al.  Archaeological questions and geophysical solutions: ground‐penetrating radar and induced polarization investigations in Munigua, Spain , 2007 .

[26]  Catherine Verna,et al.  Premières analyses métallographiques des produits sidérurgiques trouvés sur le site médiéval de Castel-Minier (Aulus-les-Bains, 09) , 2006 .

[27]  K. Cole,et al.  Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics , 1941 .

[28]  François Baumgartner,et al.  CR1Dmod: A Matlab program to model 1D complex resistivity effects in electrical and electromagnetic surveys , 2006, Comput. Geosci..

[29]  R. Hilfer Analytical representations for relaxation functions of glasses , 2002 .

[30]  Yanzhong Luo,et al.  Theory and Application of Spectral Induced Polarization , 1998 .

[31]  Karsten Lambers,et al.  Layers of perception : proceedings of the 35th International conference on Computer Applications and Quantitative Methods in Archaeology (CAA), Berlin, Germany, April 2 - 6, 2007 , 2008 .

[32]  Nicolas Florsch,et al.  Bayesian inference of the Cole–Cole parameters from time‐ and frequency‐domain induced polarization , 2007 .

[33]  A. Tarasov,et al.  Relationships between induced polarization relaxation time and hydraulic properties of sandstone , 2010 .

[34]  Raymond M. Fuoss,et al.  Electrical Properties of Solids. VIII. Dipole Moments in Polyvinyl Chloride-Diphenyl Systems* , 1941 .

[35]  James R. Wait,et al.  On electromagnetic coupling “removal” from induced polarization surveys , 1986 .

[36]  Carsten Rücker,et al.  Electrical resistivity tomography methods for archaeological prospection , 2008 .

[37]  M. Nabighian,et al.  The early history of the induced polarization method , 2007 .

[38]  J. Schön,et al.  Physical Properties of Rocks: Fundamentals and Principles of Petrophysics , 1996 .