Analysis of the emissions of volatile organic compounds from the compression ignition engine fueled by diesel-biodiesel blend and diesel oil using gas chromatography

Abstract This paper describes the procedures of the analysis of pollutant gases, as volatile organic compounds (benzene, toluene, ethylbenzene, o -xylene, m -xylene and p -xylene) emitted by engines, using high-resolution gas chromatography (HRGC). In a broad sense, CI engine burning diesel was compared with B10 and a drastic reduction was observed in the emissions of the aromatic compounds by using B10. Especially for benzene, the reduction of concentrations occurs on the level of about 19.5%. Although a concentration value below 1 μg ml −1 has been obtained, this reduction is extremely significant since benzene is a carcinogenic compound.

[1]  Breda Kegl,et al.  Effects of biodiesel on emissions of a bus diesel engine. , 2008, Bioresource technology.

[2]  S. J. Marley,et al.  Fuel properties and emissions of soybean oil esters as diesel fuel , 1996 .

[3]  P. Vasconcellos,et al.  Low molecular weight carboxylic acids in an urban atmosphere: Winter measurements in São Paulo City, Brazil , 1999 .

[4]  Sergio Machado Corrêa,et al.  Aromatic hydrocarbons emissions in diesel and biodiesel exhaust , 2006 .

[5]  R. Ferrari,et al.  Biodiesel de soja: taxa de conversão em ésteres etílicos, caracterização físico-química e consumo em gerador de energia , 2005 .

[6]  Hifjur Raheman,et al.  Performance of diesel engine with biodiesel at varying compression ratio and ignition timing , 2008 .

[7]  C. G. Herrera Esteres metílicos de ácidos grasos como carburantes. Implicaciones económicas, ecológicas y energéticas , 1995 .

[8]  J. V. Gerpen,et al.  The effect of biodiesel oxidation on engine performance and emissions , 2001 .

[9]  Rushang M. Joshi,et al.  FLOW PROPERTIES OF BIODIESEL FUEL BLENDS AT LOW TEMPERATURES , 2007 .

[10]  Juan J. Hernández,et al.  Speciation of the semivolatile hydrocarbon engine emissions from sunflower biodiesel , 2008 .

[11]  J. H. Van Gerpen,et al.  The effect of timing and oxidation on emissions from biodiesel-fueled engines. , 2001 .

[12]  Willard W. Pulkrabek,et al.  Engineering Fundamentals of the Internal Combustion Engine , 1997 .

[13]  Relation between aerosol sources and meteorological parameters for inhalable atmospheric particles in Sao Paulo City, Brazil , 1994 .

[14]  R. Velraj,et al.  Performance and exhaust emission characteristics of a CI engine fueled with Pongamia pinnata methyl ester (PPME) and its blends with diesel , 2008 .

[15]  Paulo Hilário Nascimento Saldiva,et al.  [Air pollution and emergency room visits due to pneumonia and influenza in São Paulo, Brazil]. , 2002, Revista de saude publica.

[16]  Adnan Parlak,et al.  Performance characteristics of a low heat rejection diesel engine operating with biodiesel , 2008 .

[17]  Milford A. Hanna,et al.  Alternative diesel fuels from vegetable oils , 1994 .

[18]  Md. Nurun Nabi,et al.  Improvement of engine emissions with conventional diesel fuel and diesel-biodiesel blends. , 2006, Bioresource technology.