The effect of polarization frequency and temperature on polarization rule of tourmaline

ABSTRACT In order to understand the effect of polarization frequency and temperature on polarization rule of tourmaline, the ferroelectric hysteresis loops of three kinds of tourmaline samples are measured in different polarization conditions. It is demonstrated that the spontaneous polarization along c-axis of tourmaline is larger than that perpendicular to c-axis. Furthermore, the polarization frequency and temperature have great influences on the ferroelectric hysteresis loop of tourmaline, inferring that the polarization forms of tourmaline may be composed of turning-direction polarization of electric dipole and thermionic relaxation polarization.

[1]  W. Heinrich,et al.  Tetrahedral boron in natural and synthetic HP/UHP tourmaline: Evidence from Raman spectroscopy, EMPA, and single-crystal XRD , 2016 .

[2]  W. Heinrich,et al.  Influence of the X-site composition on tourmaline’s crystal structure: investigation of synthetic K-dravite, dravite, oxy-uvite, and magnesio-foitite using SREF and Raman spectroscopy , 2016, Physics and Chemistry of Minerals.

[3]  L. Liao,et al.  Correlation between intrinsic dipole moment and pyroelectric coefficient of Fe-Mg tourmaline , 2014, International Journal of Minerals, Metallurgy, and Materials.

[4]  Liao Libing,et al.  Influence of Temperature, The Content and Valence of Fe in Tourmaline on Their Polyhedron Distortion , 2013 .

[5]  M. Fang,et al.  Characterization of dielectric performance of tourmaline single crystals from Yunnan, China , 2012 .

[6]  J. Schreuer,et al.  Correlation between dielectric properties and chemical composition of the tourmaline single crystals , 2011 .

[7]  B. Dutrow,et al.  Nomenclature of the tourmaline-supergroup minerals , 2011 .

[8]  F. Bosi Octahedrally coordinated vacancies in tourmaline: a theoretical approach , 2010, Mineralogical Magazine.

[9]  IN Tourmaline STRUCTURAL MECHANISMS FOR LIGHT . ELEMENT VARIATIONS IN TOURMALINE , 2006 .

[10]  梁金生,et al.  Observation of spontaneous polarization of tourmaline , 2005 .

[11]  L. Reznitskii,et al.  Crystal chemistry of the dravite-chromdravite series , 2004 .

[12]  Ji Zhijiang,et al.  Observation of spontaneous polarization of tourmaline , 2003 .

[13]  John M. Hughes,et al.  POLYHEDRON DISTORTIONS IN TOURMALINE , 2002 .

[14]  A. Pieczka Modelling of some structural parameters of tourmalines on the basis of their chemical composition. I. Ordered structure model , 2000 .

[15]  G. Lin,et al.  Synthesis of Aryl α,α‐Difluoroalkyl Ketones as Potent Inhibitors of Cholesterol Esterase , 1994 .

[16]  Terutaro Nakamura,et al.  Tourmaline group crystals reaction with water , 1992 .

[17]  S. Mishra,et al.  Dielectric properties of tourmaline under different conditions , 1989 .

[18]  A. Pavlovic,et al.  Thermal expansion of tourmaline single crystals from 80 to 300 K. , 1988, Physical review. B, Condensed matter.

[19]  K. Rao,et al.  Dielectric Properties of Tourmaline , 1985, February 16.

[20]  David M. Kovenock,et al.  The theoretical approach , 1973 .

[21]  R. Barton Refinement of the crystal structure of buergerite and the absolute orientation of tourmalines , 1969 .