Conformational isomers in (2RS,3SR,6SR)-3-ethyl-2,6-diphenyl-1-phenylacetyl-4-piperidone determined from synchrotron data at 120 K
暂无分享,去创建一个
In the title compound, C27H27NO2, the conformations of the two independent molecules differ in the shape of the piperidone rings, the orientation of the N-acyl substituents and the axial/equatorial disposition of the ethyl and phenyl groups. The molecules are linked into complex chains by four independent C—H⋯O hydrogen bonds.
[1] M. N. Ponnuswamy,et al. CRYSTAL STRUCTURE AND CONFORMATION OF TWO SIMILAR PIPERIDONES , 2003 .
[2] Raymond E. Davis,et al. Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals , 1995 .
[3] D. Cremer,et al. General definition of ring puckering coordinates , 1975 .