Conversion of Carbon Dioxide to Methanol Using Solar Energy - A Brief Review

This article presents a meticulous and comprehensive review of literature reported on conversion of carbon dioxide, a green house gas into methanol or to any other value added chemical following various routes including catalytic, thermal, biological, electrochemical and photoelectrochemical (PEC). More emphasis is given on conversion of carbon dioxide to methanol using solar energy (i.e., artificial photosynthesis) as this process can tackle the human generated two pressing problems, i.e., “global warming” and “energy crisis” today world is facing. It also covers information on various materials required for designing and development of reliable PEC cells for conversion of carbon dioxide to more value added chemicals including methanol. Finally, it also provides the scope for the future research on this topic with adequate literature support.

[1]  Reed J. Jensen,et al.  Direct Solar Reduction of CO2 to Fuel: First Prototype Results , 2002 .

[2]  G V Subba Rao,et al.  Semiconductor based photoelectrochemical cells for solar energy conversion—An overview , 1982 .

[3]  M. P. Nair,et al.  TiO2-SiO2 based photoanodes in photoelectrochemical cells—performance and evaluation studies , 1989 .

[4]  K. Ogura,et al.  CO2 electrochemical reduction via adsorbed halide anions , 2011 .

[5]  M. Thring.  World Energy Outlook , 1977 .

[6]  F. Glenn Fielding,et al.  New approaches , 1964, DAC.

[7]  Charles C. Sorrell,et al.  Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects , 2002 .

[8]  Aie.  World Energy Outlook 2001 , 2001 .

[9]  Andrew B. Bocarsly,et al.  Selective solar-driven reduction of CO2 to methanol using a catalyzed p-GaP based photoelectrochemical cell. , 2008, Journal of the American Chemical Society.

[10]  K. Kalyanasundaram,et al.  Artificial photosynthesis: Efficient dye-sensitized photoelectrochemical cells for direct conversion of visible light to electricity , 1994 .

[11]  H. Eyring,et al.  Electrode reduction kinetics of carbon dioxide in aqueous solution , 1972 .

[12]  D. Darensbourg,et al.  Chemistry of carbon dioxide relevant to its utilization: a personal perspective. , 2010, Inorganic chemistry.

[13]  M. Halmann,et al.  Photoelectrochemical reduction of aqueous carbon dioxide on p-type gallium phosphide in liquid junction solar cells , 1978, Nature.

[14]  Emily Barton Cole,et al.  Using a one-electron shuttle for the multielectron reduction of CO2 to methanol: kinetic, mechanistic, and structural insights. , 2010, Journal of the American Chemical Society.

[15]  Norman Hackerman,et al.  The Electroreduction of Carbon Dioxide and Formic Acid on Tin and Indium Electrodes , 1983 .

[16]  Akhlesh Gupta,et al.  Photoelectrochemical behaviour of polypyrrole coated cadmium telluride , 1992 .

[17]  Paul Kögerler,et al.  An all-inorganic, stable, and highly active tetraruthenium homogeneous catalyst for water oxidation. , 2008, Angewandte Chemie.

[18]  D. Tryk,et al.  New approaches in CO2 reduction , 1998 .

[19]  Akira Fujishima,et al.  Electrochemical reduction of carbon dioxide at ruthenium dioxide deposited on boron-doped diamond , 2003 .

[20]  Paul M Zimmerman,et al.  Simultaneous two-hydrogen transfer as a mechanism for efficient CO(2) reduction. , 2010, Inorganic chemistry.

[21]  A. Fujishima,et al.  Photoelectrochemical hydrogen production , 1979 .

[22]  Myoung-Jae Choi,et al.  Research Activities on the Utilization of Carbon Dioxide in Korea , 2008 .

[23]  Zhongyi Jiang,et al.  Efficient Conversion of CO2 to Methanol Catalyzed by Three Dehydrogenases Co-encapsulated in an Alginate−Silica (ALG−SiO2) Hybrid Gel , 2006 .

[24]  Andrew B. Bocarsly,et al.  A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential , 1994 .

[25]  H. Herzog.  THE COST OF CARBON CAPTURE , 2000 .

[26]  Iman Noshadi,et al.  A Review of Methanol Production from Methane Oxidation via Non-Thermal Plasma Reactor , 2010 .

[27]  J. Bockris,et al.  Stable photoelectrochemical cells for the splitting of water , 1977, Nature.

[28]  G. Olah,et al.  Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons. , 2009, The Journal of organic chemistry.

[29]  R. Pan,et al.  Solar energy conversion by chloroplast photoelectrochemical cells , 1981, Nature.

[30]  M. Gupta,et al.  CO 2 Capture Technologies and Opportunities in Canada “ , 2003 .

[31]  Janusz Nowotny,et al.  Materials for photoelectrochemical energy conversion , 2007 .

[32]  J. W. Dijkstra,et al.  Novel Concepts for CO2 Capture with SOFC , 2003 .

[33]  Christopher W. Jones,et al.  Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable of capturing CO2 reversibly. , 2008, Journal of the American Chemical Society.

[34]  E. Lindeberg,et al.  Underground storage of CO2 in aquifers and oil reservoirs , 1995 .

[35]  B. V. D. Zwaana,et al.  The learning potential of photovoltaics : implications for energy policy , 2004 .

[36]  Stefan Bachu,et al.  Sequestration of CO2 in geological media: criteria and approach for site selection in response to climate change , 2000 .

[37]  F. Jiao,et al.  Nanostructured cobalt oxide clusters in mesoporous silica as efficient oxygen-evolving catalysts. , 2009, Angewandte Chemie.

[38]  S. Licht.  A description of energy conversion in photoelectrochemical solar cells , 1987, Nature.

[39]  Catherine A Peters,et al.  Safe storage of CO2 in deep saline aquifers. , 2002, Environmental science & technology.

[40]  A. Fujishima,et al.  Electrochemical Photolysis of Water at a Semiconductor Electrode , 1972, Nature.

[41]  D. Haneman.  Surfaces for photoelectrochemical cells , 1979 .

[42]  George A. Olah,et al.  Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons. , 2009 .

[43]  Michael Grätzel,et al.  Photoelectrochemical cells , 2001, Nature.

[44]  Guntis Moritis.  EOR continues to unlock oil resources , 2004 .

[45]  Juan Carlos Abanades,et al.  Enhancement of CaO for CO2 capture in an FBC environment , 2003 .

[46]  Qiushi Yin,et al.  A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals , 2010, Science.

[47]  Michael Grätzel,et al.  Influence of plasmonic Au nanoparticles on the photoactivity of Fe₂O₃ electrodes for water splitting. , 2011, Nano letters.

[48]  Akira Fujishima,et al.  Formation of Hydrogen Gas with an Electrochemical Photo-cell , 1975 .

[49]  J. Gale,et al.  USING COAL SEAMS FOR CO2 SEQUESTRATION , 2006 .

[50]  F. van Bergen,et al.  Worldwide selection of early opportunities for CO2-enhanced oil recovery and CO2-enhanced coal bed methane production , 2004 .

[51]  Stephen K. Ritter,et al.  WHAT CAN WE DO WITH CO , 2007 .

[52]  S. Bachu,et al.  Sequestration of CO2 in geological media in response to climate change: capacity of deep saline aquifers to sequester CO2 in solution , 2003 .

[53]  Stephen Dye,et al.  Rapid freshening of the deep North Atlantic Ocean over the past four decades , 2002, Nature.

[54]  R. K. Pandey,et al.  Solar energy conversion by photoelectrochemical cells using chemical-bath-deposited CdS films , 1980 .

[55]  A. Maldonado,et al.  Physical properties of ZnO:F obtained from a fresh and aged solution of zinc acetate and zinc acetylacetonate , 2006 .

[56]  Jie Song,et al.  Polyoxometalates in the Design of Effective and Tunable Water Oxidation Catalysts , 2011 .

[57]  Willie Soon,et al.  Environmental Effects of Increased Atmospheric Carbon Dioxide , 1999 .

[58]  Y. Nakato,et al.  Solar to chemical conversion using metal nanoparticle modified microcrystalline silicon thin film photoelectrode , 2007 .